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The Lombardo reaction is used to convert ketones and aldehydes into alkenes using reagents generated from zinc,
dibromomethane, and TiCl4 that react under low temperatures. It is this combination of reagents that make up the
Lombardo reagent. The reaction was discovered in 1982 by Luciano Lombard as a modification of the TakaiNozaki
Methylenation reaction. One of the many benefits of the Lombardo reagent is its ability to selectively form products.
Lombardo Reagents:
General Scheme:
General Mechanism: