Learning Resources

Solved Problem - Example CD13-2: Effect of Variance

    If the variance is changed for the asymmetric RTD in Example 13-1, how is the conversion affected?  
       
       
   

Solution

Below are three similar RTDs, with the same mean residence time but with different variances. The variances are listed below. Note: E1.1(t) is the same as curve (1) in Example CDE13-2.1.
 
       
    image 13eq62.giffor the original RTD E1.1(t) is 0.157.
image 13eq62.giffor the second RTD E1.2(t) is 0.302.

image 13eq62.giffor the third RTD E1.3(t) is 0.0834.
 
       
   

A comparison of the RTDs is shown in Figure CDE13-2.1.



Figure CDE13-2.1.
E(t) for different variations




The only equations that need to be changed in the POLYMATH examples above are those for the E(t) curves. They are changed to:

 
       
   

image 13eq64.gif

 
       
    The conversions are given below.  
       
    image 13eq63.gif  
       
    Comparing the conversion and variance of the RTD curves, one can deduce that as the variance increases, the conversion decreases. This result can be explained by analyzing the RTD. With the higher variance curves, more reactants are able to leave the reactor at an earlier time, not allowing the reaction time to occur, thus decreasing the conversion.