4th Edition, 1st Printing Typos
Note: Please refer to the further typos printing pages for additional changes
Preface
Page xxvii, Footnote
__________________
*The name 'FEMLAB' was changed to "Comsol Multiphysics" on July 1, 2005.
Page xxxii, last five lines should read
For updates on the CD and new and exciting applications, see the web site:
http://www.engin.umich.edu/~cre
or
http://www.engin.umich.edu/~cre/fogler&gurmen
For typographical errors click on updates on the home page to find
http://www.engin.umich.edu/~cre/byconcept/updates/frames.htm
Chapter 1
Page 12, Equation (1-6), minus sign missing, should read
Page 21, end of the first paragraph under 1.5
… at the University of Michigan
Page 21, margin should read
Chapter 2
Page 56, just above
For Reactor 2 at bottom of page.
Insert X1 and delete one of the (0.4)s
… 
Page 64, 4th line from bottom should read
Figure E2-7.2
NOT E7-2.2
Page 70, Move top of page 71 to bottom of page 70.
Page 70, Insert below figure
The PFR integral can be evaluated by
(A-23)
Page 73, Problem 2-2b. web site address should read
www.engin.umich.edu/~cre/asyLearn/itresources.htm
Page 73, For P2-4 b, the second value in the parentheses should be 3.2 m3 not 3.2m.
Page 75, Problem 2-8. Add sub B to figure caption, should read
P2-8B
Page 75, Problem 2-9B. just above part (a)
… shown in Figure P2-9B on the next page.
Page 76, Problem 2-9. Add sub B to figure caption, should read
P2-9B
Page 76, Problem 2-12. Add sub B to figure caption, should read
P2-12B
and also add
… adiabatic exothermic reaction.
Page 77, Problem 2-12B. part (f) should read, catalyst weight,
… as a function of PBR catalyst weight.
Page 77, Problem 2-12B. delete part (g)
Chapter 3
Page 85, (1) under second order reaction should be lower case "l" (ell)
… + NHCl
Page 85, (2) Footnote† should go under the line
Page 135, top of page add CSTR, should read
… calculate the CSTR space-time …
Page 135, top of page add
… -rA(X). calculate τ for (i) a CSTR (ii) a PFR
Page 135, Problem 3-11 (d), 2 missing in equation (2H2)
Page 135, Problem 3-11 (d), replace "PBR" with "fluidized CSTR" in 2 places, should read
… For the isothermal, isobaric, catalytic gas-phase reaction is carried out in a fluidized CSTR.
and
… the feed enters a fluidized CSTR at 6 atm …
Page 135, insert in margin next to P3-12, repeat margin figure from page 242, except delete "reactor"
Page 136, Problem 3-13 (g), delete "molar" and replace "mol" with "dm3", should read
… 288°C for a feed rate of 2 dm3/min
Chapter 4
Page 147, delete "X" in equation B, should read
Page 152, change "0.995" to "0.957"
Page 162, Equation just above Eqn. 4-15. Should read sub CA0
Page 164 The volumetric flow rate going into the tank should be 
not
Page 165, Should read
CA0 = 1 lbmol/ft3
Page 170, Figure 4-7, all "∈" should be epsilon "ε" as shown in Equation (4-17).
Page 171, Figure 4-8, all "∈" should be epsilon "ε" as shown in Equation (4-17).
Page 185, second sentence under 4.5.4 should read "on"
… on reactor design.
Page 190, in margin, next to Figure E4-5.1, add "Also see Ch.4 Summary Notes" and add Summary Notes Icon
Page 193, Equation (E4-6.12) should read
Page 209, "Figure 4-12 … " should read "Figure 4-13 … " (change in 2 places)
Page 215, second line from the top should read
… leaving through the sides of the membrane reactor, species can also be fed to the reactor through the membrane.
Page 217, "CA = CA0" should read "CA0 = 0"
Page 225, next to last sentence add "s"
… products
Page 239, Problem P4-8B Part (c) should read 52.6%
… was amazingly 52.6% exactly
Page 241, margin
Strive to solve the California problems in 30 minutes.
Page 242, margin figure, delete "reactor", should read
Page 242 Problem P4-16A
Part (b) should read
Page 242 Problem P4-16A
Part (c) should read
Page 243, Problem 4-19B Part (a) and (i.e., W) should read
… the length (i.e., W) of the reactor.
Chapter 5
Page 255, “(TE5-1.6)” should read “(TE5-1.4)”
Page 265, change number in table heading, “Table E5-1.3” should read Table E5-1.4”
Page 295, add
… with CA0 = 2.33 x 10 –6 mol/dm3
Page 301, P5-15B add "Hint: See Chapter 7, Section 7.4"
Chapter 6
Page 313 Equation (E6-2.4) should read
…
Page 325, Bottom of page, Equation (1), "XA" should be "Xa"
Page 345, add minus sign in Equation (E6-8.1), should read
υ0CH0 -υ0CH = -rHV
Page 345, add minus sign in Equation (E6-8.2), should read
υ0CM0 -υ0CM = -rMV
Page 361, P6-2A part (b), add "used for", should read
… Semibatch: used for (1) highly …
Page 365, Problem 6-9C. Third line should read
… the selectivity to D. Make…
Page 365, Problem 6-9C. part (c), replace –r2A in the rate law for reaction (2) on the left hand side with –r2B , should read
–r2B = …
Page 366, Problem 6-9C. Delete part (g)
(g) Delete part (g)
Page 366, Problem 6-9C. Add to part (h), just above MR and PFR add at 300K and 1000K, should read
the concentration of O2 at 300K and 1000K. [CES, 58…
Page 371, Problem 6-21B. add part (c)
(c) Describe the major differences you observe when C diffuses out of the membrane instead of B with the same mass transfer coefficient.
Chapter 7
Page 378, second line from top, add "for"
… However, for a …
Page 378, In footnote 2, remove “r” in “Lindermann” should be “Lindemann”
Page 391 Figure 7-2, arrow combining CH3• and C2H6 should point in only one direction, down
Page 397, Top of page should read
Page 403, “substrated” should read “substrate”
Page 404, just above Equation (7-29) should read
Page 405, “(7-31)” should read “(7-32)”
We can write Equation (7-32) in terms of conversion as
Page 407, Last sentence in first paragraph “Figure 7-9” should read “Figure 7-8”
Figure 7-8 shows an example of this optimum in enzyme activity.
Page 417, last line of first paragraph, under 7.3.5
… in the Professional Reference Shelf 7.4.1
Page 430, last line add "g", should read
Page 434, Figure E7-6.1 top left hand figure y axis, should read
rate
g/dm3•h
Page 446, Figure E7-6.1 top left hand figure should read
… and Fogler)22 on the CDROM,
Page 453 should read
R7.4 Multiple Enzyme and Substrate Systems
R7.4.1 Microbial Growth on Multiple Substrates
R7.4.2 Enzyme Regeneration
Example R7.4-1 Construct a Lineweaver-Burk Plot for Different Oxygen Concentration
R7.4.3 Enzyme Cofactors
Example R7.4-2 Derive a Rate Law for Alcohol Dehydrogenase
R7.4.4 Multiple Substrates
Example R7.4-3 Derive a Rate Law a Multiple Substrate System
Example R7.4-4 Calculate the Initial Rate of Formation of Ethanol in the Presence of Propanediol
R7.4.5 Multiple Enzymes
Page 460 Problem P7-10, Part (a) replace S and for right with E should read
Page 460 Problem P7-10, Part (d) the last step should read
irreversible
Chapter 8
Page 482, Eqn. (8-17) liquid heat capacity should be sub "l" (ell), not sub "g", should read
Page 491 margin, delete "o" in first equation, should read
Page 498, third line from the bottom, "k" missing in "kmol", should read
Page 498, margin note left out
Page 498, next to last line at the bottom of the page, "k" is missing in kmol. Should read
… and
Page 500, Equation (8-40), add subscript “c”
Page 510, margin should read
… constant heating medium…
Page 515 Figure E8-6.1 x axis should have units of (K)
T(K)
Page 519, just above "5. Second Reactor"should read 31.6 m2 NOT 3.16 m2.
...31.6 m2.
Page 536, Replace Figure 8-16
Page 536, Caption for Figure 8-16 should read
Figure 8-16 heat generation curves for identical frequency factors, A.
Page 541, insert bottom of page
Insert 1
We shall use S* and Equation (8-67) to develop our stability diagram. As an example we will consider an irreversible reaction that follows a power law model and the reacting species are a very weak function of temperature.†
Insert 2
__________________
†Strictly speaking this development is only true for a zero order reaction. A development for other reaction orders is given in Professional Reference Shelf R8.1A.
Page 543, insert in margin
Rule of
Thumb for
Zero Order
Reactions
Page 543, Equation (8-73), (1+k) missing in denominator, should read
Insert 1
As shown in PRS R8.1A, the equation for S* for a first order reaction is
 |
(8-73) |
Page 555, Equation (8-94)
"Hiz" should read "Hi"
Page 556,
The last three lines (For laminar flow … equation (8-100) where U0 is …) including equation (8-100) should be moved right after the equation (8-97) in the same page. Because of this change, the equation numbers (8-98) through (8-100) should be corrected properly (i.e. order of appearance).
Page 560, Figure E8-12.1 title
… for a 2nd order reaction
Page 564, 9. Multiple Steady State should be T sub c, should read
Page 564, Equation (S8-13), plus sign missing in the numerator, should read
Page 569, P8-2 (i) ΔHRx = 38,700, not 58,700
Page 570. P8-2 (i) 
Page 570. P8-2 (k)
[(700 < UA < 70,000 J/m3•s•K)]. 2) If tau were varied [(0.1 > τ > 0.00001 min)]
Page 570 P8-2 (l) should read
Example PRS
P8-4.1
Page 571, P8-2 (n) Example 8-12, Replace with following insert A
Click on Chapter 2 radial effects in the left hand margin. This section gives an overview of the model equations. Next, click on "non-isothermal reactor with non-isothermal cooling jacket and follow the step by step instructions and screen shots.
Page 578, last equation on page should be "m" sub "c" in exponents
Page 582
… discussed in P8-2 (n)
Page 583 Problem P8-23 Heat of reaction for first reaction should be negative
Page 586 (g), should read
… 
Chapter 9
Page 597 should read
Table E9-1.1 Summary for a First Order Adiabatic Reaction
Page 605, margin should read disk
Page 611, fourth equation down from top, minus sign left out, should read
Page 619, small k on second figure should read
Page 627, y axis of Figure E9-7.1 should read
(mol/dm3)
Chapter 10
Page 659, Left hand figure "Thick Boundary Layer"
Page 664, margin
Page 665, margin
Page 696
Figure E10-3.1 should level off around 0.69 instead of 0.60
Page 697, Fourth equation up from bottom, equal sign is missing
Units should be Roman
Page 704, replace margin figure with Figure 5-7 on page 272.
Page 705 (a) KA should be KEA
Page 706, top of page, denominator, should read
Page 711, margin figure add "t" to x-axis
Page 718 Top of page, Change "crude oil" to "gas oil"
Page 722, Insert margin figure
Page 723, below Figure 10-31 should read
EA (cal/mol) A (h-1) h-1 Ed (cal/mol) Ad (h-1)
Page 730, Equation E10-8.1 and Equation just above it should be U0 not Ug, should read
The height of the catalyst particle at time "t" is after entering the STTR is
Differentiating we can find a relation between the time of the catalyst particle has been in the STTR a height of the practice which we can use to find the activity a.
Page 732, Table E10-8.1 replace Polymath Program and figure
Page 739 P10-2, (f), last two lines of problem the ts should be changed to τs (Tau), e.g.,
… τ changes if τ = 0.005 h-1 If τ = 0.01 h-1
Page 741 Problem P10-5B, Part (c) last line should be H sub 5 not 6, i.e.,
Page 748 P10-17B, delete equation in middle
and switch parts (b) and (c)
Page 749, P10-19, Part (e) should read,
How would your answer to part (a) change if the reactant and catalyst were fed at opposite ends
Page 749, P10-19, Part (h) should now read
(h) Now consider the reaction to be zero order with k = 0.2 mol/kgcat•min.
Chapter 11
Page 759, opposite mole balance in margin Dy should be Dz in third term for
… 
…
Page 764, Insert at the very bottom of the page
This form of the mole balance will be used in Comsol MultiphysicsTM.
Page 776, Example 11-2 at the end of the last line before solution insert
T = 300 K
Page 785, y-axis of Figure 11-10 rotate label 90°. should read
Page 803, P11-8, (e) Example 11-2(e)
Page 803, P11-2, Part (f) add δ2, should read
DAB2, δ2, and CAP
Page 805, P11-6, Change respiration rate from 0.5 mmoles/min to 1.5 micromoles/min and the volumetric gas up take is 0.05 dm3/min and add Ann Arbor, MI? DAB = 0.18 cm2/s.
Should read
… rate of a chipmunk is 1.5 micromoles/min
… gas intake of 0.05 dm3/min 0.05 dm3/min
… Ann Arbor, MI. DAB = 0.18 cm2/s
Page 806, P11-8, Part (a) left hand side should have subscript 1 and should read
Chapter 12
Page 818, second boxed material in left hand margin "Surface" misspelled
… Surface Area…
Page 818, third line in box, transpose, (and l, should read
… 
Page 818, fourth line in box
… 
Page 826, just above 
The Thiele modulus is
Page 826, Equation (E12-2.14) should read
Page 826, Equation (E12-2.15) should read
Page 826, Equation (E12-2.16) should read
Page 826, Equation (E12-2.17) should read
Page 840, Title of Table E12-3.1
… Basket Reactor
Page 841, Fix box
Page 842, top of page
, kg/m3
Page 842
Rg = gas constant = 8.31 kJ/kmol•K
Page 843 and 844, add primes throughout. -rA should read -rA′
Page 847, half way down the page, "S"… should be lower case s in denominator
Page 847, very bottom of the page should read
Page 855, Problem P12-2, Delete part (2), Monad Kinetics
Insert: Sketch ψ versus λ at different times. Sketch λc as a function of time. Hint: See P12-10C.
Page 855, Problem 12-2B Part (b), delete V in denominator, should read
Page 856, Problem 12-2B delete part (i)
Page 857, Figure P12-3, y axis should read
Page 857, Figure P12-3, x axis should have "T(K)" instead of "T(k)"
Page 861, P12-13, delete TS in denominator of 2nd term, Part (b) should read
Page 863, P12-17, second equation should read, 
, i.e.,
Chapter 13
Page 878, Sentence split in half, third line from the bottom should read
The shape of the F(t) curve is shown in Figure 13-5,
Page 883, Just above Equation (E13-2.3) at bottom of page should read
(E13-2.2)
Page 884, lower υ1 should be υ2, bottom curve should read
Page 885, Figure in margin, there should be a comma between υ1 and υ2, i.e.,
υ1, υ2
Page 894, Figure 13-12 incept of first plot should be
also add tick at that point
Page 905, add v to margin should read
… removal …
Page 906, insert just opposite summary notes icon should read
… the CD-ROM, click the 
click back button …
Page 919 the bottom equation, the minus sign is missing, should read
Page 936 Problem P13-2A, Part (b) just under the figures insert
Suggest a model for each.
Page 936 Problem P13-2A, Part (f) last line of the problem should read
… with E = 8 kcal/mol
Page 939 Problem P13-5, Part (f) add E/R=5000K
… E/R = 5000 K.
Page 939 Problem P13-6B, add figure
RTD Reactior B
The following E(t) curves were obtained form a tracer test on two reactors A and B
(a) … for Reactor A (b) Repeat for Reactor (B)
Page 939 Problem P13-8B, add units of min-1
E(t) = 1.0 min-1
Hint: Find tm from data then use E(t) for each ideal reactor
Page 941 Problem P13-12, third line down from top should read
Page 941 Problem P13-15, second line of the page should read
… in Problem CDP13-NB. (Delete rB)
Chapter 14
Page 949, Equation at bottom of page, Vi should be V2. Should read
Page 954, Equation (E14-1.5) should have "1 -" on right hand side and should read
Page 956, the left hand bell shaped curve in Figure 14-6 should be narrower, i.e., not as broad as the right hand bell shaped curve.
Page 961, last line should read
… determine Da by finding the Peclet number.
Page 970, should read
Page 977, margin should read
Be sure to view the documentation for COMSOL Multiphysics in the CD-ROM including a tutorial with screenhots.
Page 981, Delete parenthesis in Equation (14-62)
Page 981, Figure 14-16 should be υs
υs = (1-β)υ0
Page 982, Add to table caption
… For a Step Input
Page 982, Below table add
The entering tracer concentration is CT0 = 2000
mg/dm3
Page 991, fourth line infirst paragraph, Figure 14-9(a) should read
Figure
14-19(a)
Page 991, top right hand figure, the F intercept should be "β" not "(1-β)"
Figure 14-19(a)
Page 994, Equation 14-47 should read
Page 996, P14-2B, third line from bottom should read
A kinematic viscosity υ = μ/ρ = …
Page 997, 14-2(g), last prime, should read
Page 998, Problem 14-7 cm2 should be dm2
… area of 25 dm2
Page 998, bottom of page
and E(t) in min-1
Page 999, Problem P14-12 Part (b) should read
Page 1001 Problem P14-15, Part (c) should read
For t > 10 minutes, then
Page 1002, P14-19C, third line should read dm3
i.e., CA0 = 0.5 mol/dm3
Hint: you can also use the non isothermal reactor with non isothermal coolant and set ΔHRx = 0, Ua = 0, and kt = 0.
Page 1004, P14-24B, Insert E(t) figure
Page 1004, insert problem number
P14-25B
Appendix
Page 1009, Equation (A-5), “e” should be “ε”
Page 1009, Equation (A-6), “e” should be “ε”
Page 1012, in box for integrating factor third line should read
…
Page 1018 …
… = 0.01 poise = 0.1 micro Pascal • second
Page 1032, Insert at bottom of box Insert B
Tutorial
Tutorials with step-by-step explanation and screen shots can be found by opening the documentation section on the COMSOL ECRE CD-ROM. Start with the documentation for 1. Isothermal Reactor and then go to the documentation section for each of the other modules. Tutorial material discussed in this module is built on, but not repeated in modules that follow. Next go to the nonisothermal adiabatic reaction, and read the document there. This tutorial material will be built on but not repeated in the later modules. The same hold for each of the sequential modules.
