Chapter 9

Example 9.3: Calculate Xnfor Monomers with Different End Groups

 

10 molecules of ARB initially

MWR = 100 , Meg ~ 18, we neglect MWeg wrt MWR.

At time t we have 5 polymer molecules with the following distribution

MW*

Species

By product

Conversion of monomer

where:

NM = Concentration of monomer ARB (2ARB).
NM0 = Initial concentration of monomer (10 ARB).


100

ARB

100

ARB

200

AR2B

+ AB

300

AR3B

+ 2AB

300

AR3B

+ 2AB

*Neglecting Meg

 

p = fraction of functional groups of A that have reacted.

There are 5 molecules of polymer that remain: 2 of ARB, 1 of AR2B, and 2 of AR3B.

 

We are giving to calculate by three different methods, all of which yield the same result.

 

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