1. Lotz, M. D.; Camasso, N. M.; Canty, A. J.; Sanford, M. S. "Role of Silver Salts in Palladium-Catalyzed Arene and Heteroarene C–H Functionalization Reactions," Organometallics 2016, ASAP

  2. 122

  3. Pendleton, I. M.; Pérez-Temprano, M. H.; Sanford, M. S.; Zimmerman, P. M. "Experimental and Computational Assessment of Reactivity and Mechanism in C(sp3)–N Bond-Forming Reductive Elimination from PdIV," J. Am. Chem. Soc. 2016, 138, 6049–6060.

  4. 122

  5. Genna, D. T.; Pfund, L. Y.; Samblanet, D. C.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. "Rhodium Hydrogenation Catalysts Supported in Metal Organic Frameworks: Influence of the Framework on Catalytic Activity and Selectivity," ACS Catal. 2016, 6, 3569–3574.

  6. 122

  7. Brewster, T. P.; Rezayee, N. M.; Culakova, Z.; Sanford, M. S.; Goldberg, K. I. "Base-Free Iridium-Catalyzed Hydrogenation of Esters and Lactones," ACS Catal. 2016, 6, 3113-3117.

  8. 113

  9. Cook, A. K.; Schimler, S. D.; Matzger, A. J.; Sanford, M. S. "Catalyst-Controlled Selectivity in the C–H Borylation of Methane and Ethane," Science 2016, 351, 1421-1424.

  10. 113

  11. Sanford, M. S.; Scott, P. J. H. "Moving Metal-Mediated 18F‐Fluorination from Concept to Clinic," ACS Cent. Sci. 2016, 2, 128–130.

  12. Topczewski, J. T.; Cabrera, P. J.; Saper, N. I.; Sanford, M. S. "Palladium-Catalysed Transannular C–H Functionalization of Alicyclic Amines," Nature 2016, 531, 220-224.

  13. 122
  14. Schimler, S. D.; Ryan, S. J.; Bland, D. C.; Anderson, J. E.; Sanford, M. S. "Anhydrous Tetramethylammonium Fluoride for Room-Temperature SNAr Fluorination," J. Org. Chem. 2015, 80, 12137-12145.

  15. 120

  16. Mossine, A. V.; Brooks, A. F.; Makaravage, K. J.; Miller, J. M.; Ichiishi, N.; Sanford, M. S.; Scott, P. J. H. "Synthesis of [18F]Arenes via the Copper-Mediated [18F]Fluorination of Boronic Acids," Org. Let. 2015, 17, 5780-5783.

  17. 119

  18. Sevov, C. S.; Brooner, R. E. M.; Chénard, E.; Assary, R. S.; Moore, J. S.; Rodríguez-López, J.; Sanford, M. S. "Evolutionary Design of Low Molecular Weight Organic Anolyte Materials for Applications in Nonaqueous Redox Flow Batteries," J. Am. Chem. Soc. 2015, 137, 14465-14472.

  19. 118

  20. Cabrera, P. J.; Yang, X.; Suttil, J. A.; Brooner, R. E. M.; Thompson, L. T.; Sanford, M. S. "Evaluation of Tris-Bipyridine Chromium Complexes for Flow Battery Applications: Impact of Bipyridine Ligand Structure on Solubility and Electrochemistry," Inorg. Chem. 2015, 54, 10214-10223.

  21. 117

  22. Cook, A.; Sanford, M. S. "C-Hal Bond Formation by Arene C-H Activation," In Catalytic Transformations via C-H Activation, Vol. 2; Science of Synthesis, Yu, J.-Q., 2015, 183-219.

  23. Lee, M.; Sanford, M. S. "Platinum-Catalyzed, Terminal-Selective C(sp3)–H Oxidation of Aliphatic Amines," J. Am. Chem. Soc. 2015, 137, 12796-12799.

  24. 115

  25. Bour, J. R.; Camasso, N. M.; Sanford, M. S. "Oxidation of NiII to NiIV with Aryl Electrophiles Enables Ni-Mediated Aryl–CF3 Coupling," J. Am. Chem. Soc. 2015, 137, 8034-8037.

  26. 114

  27. Cabrera, P. J.; Yang, X.; Suttil, J. A.; Hawthorne, K. L. Brooner, R. E. M.; Sanford, M. S.; Thompson, L. T. "Complexes Containing Redox Noninnocent Ligands for Symmetric, Multielectron Transfer Nonaqueous Redox Flow Batteries, " J. Phys. Chem. C 2015, 119, 15882-15889.

  28. 113

  29. Ryan, S. J.; Schimler, S. D.; Bland, D. C.; Sanford, M. S. "Acyl Azolium Fluorides for Room Temperature Nucleophilic Aromatic Fluorination of Chloro- and Nitroarenes," Org. Lett. 2015, 17, 1866-1869.

  30. 113

  31. Suttil, J. A.; Kucharyson, J. F.; Escalante-Garcia, I. L.; Cabrera, P. J.; James, B. R.; Savinell, R. F.; Sanford, M. S.; Thompson, L. T. "Metal Acetylacetonate Complexes for High Energy Density Non-Aqueous Redox Flow Batteries," J. Mater. Chem. A 2015, 3, 7929-7938.

  32. 113

  33. Canty, A. J.; Ariafard, A.; Yates, B. F.; Sanford, M. S. "Computational Study of Intramolecular Arene Palladation at a Palladium(IV) Center," Organometallics 2015, 34, 1085-1090.

  34. 113

  35. Cook, A. K.; Sanford, M. S. "Mechanism of the Palladium-Catalyzed Arene C-H Acetoxylation: A Comparison of Catalysis and Ligand Effects," J. Am. Chem. Soc. 2015, 137, 3109-3118.

  36. 113

  37. Camasso, N. M.; Sanford, M. S. "Design, Synthesis, and Carbon-Heteroatom Coupling Reactions of Organometallic Nickel (IV) Complexes," Science 2015, 347, 1218-1220.

  38. 113

  39. Rezayee, N. M.; Huff, C. A.; Sanford, M. S. "Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol," J. Am. Chem. Soc. 2015, 137, 1028-1031.

  40. 113

  41. Topczewski, J. J.; Sanford, M. S. "Carbon–Hydrogen (C–H) Bond Activation at PdIV: A Frontier in C–H Functionalization Catalysis," Chem. Sci. 2014, 6, 70-76.

  42. 113

  43. Ichiishi, N.; Canty, A. J.; Yates, B. F.; Sanford, M. S. "Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the CuI/CuIII Manifold in Copper Catalysis," Organometallics 2014, 33, 5525–5534.

  44. 113

  45. Brooks, A. F.; Topczewski, J. J.; Ichiishi, N.; Sanford, M. S.; Scott, P. J. H. "Late-Stage [18F]Fluorination: New Solutions to Old Problems," Chem. Sci. 2014, 5, 4545-4553.

  46. 113

  47. Camasso, N. M.; Pérez-Temprano, M. H.; Sanford, M. S. "C(sp3)–O Bond-Forming Reductive Elimination from PdIV with Diverse Oxygen Nucleophiles," J. Am. Chem. Soc. 2014, 136, 12771-12775.

  48. 113

  49. Allen, L. J.; Lee, S. H.; Cheng, Y.; Hanley, P. S.; Muhuhi, J. M.; Kane, E.; Powers, S. L.; Anderson, J. E.; Bell, B. M.; Roth, G. A.; Sanford, M. S.; Bland, D. C. "Developing Efficient Nucleophilic Fluorination Methods and Application to Substituted Picolinate Esters," Org. Process Res. Dev. 2014, 18, 1045-1054.

  50. 113

  51. Maleckis, A.; Sanford, M. S. "Synthesis of Fluoroalkyl Palladium and Nickel Complexes via Decarbonylation of Acylmetal Species" Organometallics 2014, 33, 3831-3839.

  52. 113

  53. Ichiishi, N.; Brooks, A. F.; Topczewski, J. J.; Rodnick, M. E.; Sanford, M. S.; Scott, P. J. H. "Copper-Catalyzed [18F]Fluorination of (Mesityl)(aryl)iodonium Salts," Org. Lett. 2014, 16, 3224–3227.

  54. 113

  55. Lotz, M. D.; Remy, M. S.; Lao, D. B.; Ariafard, A.; Yates, B. F.; Canty, A. J.; Mayer, J. M.; Sanford, M. S. "Formation of Ethane from Mono-Methyl PalladiumII Complexes," J. Am. Chem. Soc. 2014, 136, 8237–8242.

  56. 113

  57. Allen, L. J.; Muhuhi, J. M.; Bland, D. C.; Merzel, R.; Sanford, M. S. "Mild Fluorination of Chloropyridines with In Situ Generated Anhydrous Tetrabutylammonium Fluoride," J. Org. Chem. 2014, 79, 5827–5833.

  58. 113

  59. Maleckis, A.; Sanford, M. S. "Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source," Organometallics 2014, 33, 2653-2660.

  60. 113

  61. Allen, L. J.; Cabrera, P. J.; Lee, M.; Sanford, M. S. "N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes," J. Am. Chem. Soc. 2014, 136, 5607-5610.

  62. 113

  63. Pérez-Temprano, M. H.; Racowski, J. M.; Kampf, J. W.; Sanford, M. S. "Competition Between sp 3-C–N vs sp 3-C–F Reductive Elimination from PdIV Complexes," J. Am. Chem. Soc. 2014, 136, 4097–4100.

  64. 113

  65. Wagner, A. M.; Sanford, M. S. "Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers," J. Org. Chem. 2014, 79, 2263-2267.

  66. 113

  67. Ye, Y.; Schimler, S. D.; Hanley, P. S.; Sanford, M. S. " Cu(OTf)2-Mediated Fluorination of Aryltrifluoroborates with Potassium Fluoride, " J. Am. Chem. Soc. 2013, 135, 16292-16295.

  68. 113

  69. Wagner, A. M. ; Hickman, A. J. ; Sanford, M. S. "Platinum-Catalyzed C–H Arylation of Simple Arenes," J. Am. Chem. Soc. 2013, 135, 15710-15713.

  70. 113

  71. Cook, A. K.; Emmert, M. H.; Sanford, M. S. "Steric Control of Site Selectivity in the Pd-Catalyzed C–H Acetoxylation of Simple Arenes," Org. Lett. 2013, 15, 5428-5431.

  72. 113

  73. Lehman, M. C.; Gary, J. B.; Boyle, P. D.; Sanford, M. S.; Ison, E. A. "Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*IrIII(L) Complexes," ACS Catalysis. 2013, 3, 2304–2310.

  74. 113

  75. Huff, C. A.; Sanford, M. S. "Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex," ACS Catalysis. 2013, 3, 2412-2416.

  76. 113

  77. Ichiishi, N.; Canty, A. J.; Yates, B. F.; Sanford, M. S. "Cu-Catalyzed Fluorination of Diaryliodonium Salts With KF," Org. Lett. 2013, 15, 5134–5137.

  78. 113

  79. Genna, D. T.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. "Heterogenization of Homogeneous Catalysts in Metal–Organic Frameworks Via Cation Exchange," J. Am. Chem. Soc. 2013, 135, 10586–10589.

  80. 113

  81. Huff, C. A.; Kampf, J. W.; Sanford, M. S. "Reversible Carbon-Carbon Bond Formation Between Carbonyl Compounds and a Ruthenium Pincer Complex," Chem. Commun. 2013, 49, 7147-7149.

  82. 113

  83. Sanhueza, I. A.; Wagner, A. M.; Sanford, M. S.; Schoenebeck, F. "On the Role of Anionic Ligands in the Site-Selectivity of Oxidative C–H Functionalization Reactions of Arenes." Chem. Sci. 2013, 4, 2767-2775.

  84. 113

  85. Gary, J. B.; Cook, A. K.; Sanford, M. S. "Palladium Catalysts Containing Pyridinium-Substituted Pyridine Ligands for the C–H Oxygenation of Benzene with K2S2O8," ACS Catalysis. 2013, 3, 700-703.

  86. 113

  87. Seigerman, C. K.; Micyus, T. M.; Neufeldt, S. R.; Sanford, M. S. "Palladium-Catalyzed C–H Arylation Using Aryltrifluoroborates in Conjunction with a MnIII Oxidant under Mild Conditions," Tetrahedron. 2013, 69, 5580-5587.

  88. 113

  89. Maleckis, A.; Kampf, J. W.; Sanford, M. S. "A Detailed Study of Acetate-Assisted C–H Activation at Palladium (IV) Centers," J. Am. Chem. Soc. 2013, 135, 6618-6625.

  90. 113

  91. Neufeldt, S. R.; Seigerman, C. K.; Sanford, M. S. "Mild Palladium-Catalyzed C–H Alkylation Using Potassium Alkyltrifluoroborates in Combination with MnF3," Org. Lett. 2013, 15, 2302-2305.

  92. 113

  93. Ye, Y.; Sanford, M. S. "Mild Copper-Mediated Fluorination of Aryl Stannanes and Aryl Trifluoroborates," J. Am. Chem. Soc. 2013, 135, 4648–4651.

  94. 113

  95. Canty, A. J.; Ariafard, A.; Sanford, M. S.; Yates, B. F. "Mechanism of Pd-Catalyzed Ar-Ar Bond Formation Involving Ligand-Directed C-H Arylation and Diaryliodonium Oxidants: Computational Studies of Orthopalladation at Binuclear PdII Centers, Oxidation To Form Binuclear Palladium (III) Species, and Ar···Ar Reductive Coupling, " Organometallics 2013, 32, 544-555.

  96. 113

  97. Neufeldt, S. R.; Sanford, M. S. "Asymmetric Chiral Ligand-Directed Alkene Dioxygenation," Org. Lett. 2013, 15, 46-49.

  98. 113

  99. McMurtrey, K. B.; Sanford, M. S. "C-F Bond-Forming Reactions," In Cross-Coupling and Heck-Type Reactions from the Science of Synthesis Reference Library. Vol. 2, John P. Wolfe, Ed., Thieme, 2012.

  100. Neufeldt, S. R.; Sanford, M. S. "Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed C–H Arylation with Diaryliodonium Salts," Adv. Synth. Catal. 2012, 354, 3517-3522.

  101. Ye,Y.; Kuenzi, S. A.; Sanford, M. S. "Practical Method for the Cu-Mediated Trifluoromethylation of Arylboronic Acids with CF3 Radicals Derived from NaSO2CF3 and tert-Butyl Hydroperoxide (TBHP)," Org. Lett. 2012, 14, 4979-4981.

  102. 113

  103. Stowers, K. J.; Kubota, A.; Sanford, M. S. "Nitrate as a Redox Co-Catalyst for the Aerobic Pd-Catalyzed Oxidation of Unactivated sp3-C–H Bonds," Chem. Sci. 2012, 3, 3192-3195.

  104. 113

  105. McMurtrey, K. B.; Racowski, J. M.; Sanford, M. S. "Pd-Catalyzed C-H Fluorination with Nucleophilic Fluoride," Org. Lett. 2012, 14, 4094-4097.

  106. 113

  107. Powers, D. C.; Lee, E.; Ariafard, A.; Sanford, M. S.; Yates, B. F.; Canty, A. J.; Ritter, T. "Connecting Binuclear PdIII and Mononuclear PdIV Chemistry by Pd-Pd Bond Cleavage," J. Am. Chem. Soc. 2012, 134, 12002-12009.

  108. 113

  109. Ye, Y.; Sanford, M. S. "Investigations into Transition-Metal-Catalyzed Arene Trifluoromethylation Reactions," Synlett. 2012, 23, 2005-2013.

  110. Gary, J. B; Carter, T. J.; Sanford, M. S. "RhIII) Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange," Top. Catal. 2012, 55, 565-570.

  111. Huff, C. A.; Kampf, J. W.; Sanford, M. S. "Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO)," Organometallics 2012, 31, 4643-4635.

  112. 113

  113. Hickman, A. J.; Sanford, M. S. "High-Valent Organometallic Copper and Palladium in Catalysis," Nature 2012, 484, 177-185.

  114. Ye, Y.; Sanford, M. S. "Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I," J. Am. Chem. Soc. 2012, 134, 9034-9037.

  115. 113

  116. Neufeldt, S. R.; Sanford, M. S. "Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization" Acc. Chem. Res. 2012, 45, 936-946.

  117. 113

  118. Kubota, A.; Emmert, M. H.; Sanford, M. S. "Pyridine Ligands as Promoters in PdII/0-Catalyzed C–H Olefination Reactions" Org. Lett. 2012, 14, 1760-1763.

  119. 113

  120. Hickman, A. J.; Cismesia, M. A.; Sanford, M. S. "Structure-Activity Relationship Study of Diimine PtII Catalysts for H/D Exchange" Organometallics 2012, 31, 1761-1766.

  121. 113

  122. Racowski, J. M.; Gary, B. G.; Sanford, M. S. "Carbon(sp3)–Fluorine Bond-Forming Reductive Elimination from Palladium (IV)" Angew. Chem. Int. Ed 2012, 51, 3414-3417

  123. 113

  124. Park, T.-H.; Hickman, A. J.; Koh, K.; Martin, S.; Wong-Foy, A. G.; Sanford, M. S.; Matzger, A. J. "Highly Dispersed Palladium (II) in a Defective MOF: Application to C–H Activation and Functionalization," J. Am. Chem. Soc. 2011, 133, 20138-20141.

  125. 113

  126. Maleckis, A; Sanford, M. S. "Facial Tridentate Ligands for Stabilizing Palladium (IV) Complexes," Organometallics 2011, 30, 6617-6627.

  127. 113

  128. Kalyani, D.; McMurtrey, K. B.; Neufeldt, S. R.; Sanford, M. S. "Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis," J. Am. Chem. Soc. 2011, 133, 18566-18569.

  129. 113

  130. Huff, C. A.; Sanford, M. S. "Cascade Catalysis for the Homogeneous Hydrogenation of CO2 to Methanol," J. Am. Chem. Soc. 2011, 133, 18122-18125.

  131. 113

  132. Gary, J. B.; Sanford, M. S. "Participation of Carbonyl Oxygen in Carbon-Carboxylate Bond-Forming Reductive Elimination from Palladium," Organometallics 2011, 30, 6143-6149.

  133. 113

  134. Racowski, J. M.; Ball, N. D.; Sanford, M. S. "C–H Bond Activation at Palladium (IV) Centers," J. Am. Chem. Soc. 2011, 133, 18022-18025.

  135. 113

  136. Ye, Y.; Lee, S.; Sanford, M. S. "Silver-Mediated Trifluoromethylation of Arenes Using TMSCF3," Org. Lett. 2011, 13, 5464-5467.

  137. 113

  138. Emmert, M. H.; Cook, A. K.; Xie, Y. J.; Sanford, M. S. "Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected C–H Oxygenation of Arenes," Angew. Chem. Int. Ed. 2011, 50, 9409-9412.

  139. 113

  140. Lanci, M. P.; Remy, M. S.; Lao, D. B.; Sanford, M. S.; Mayer, J. M. "Modulating Sterics in Trimethylplatinum (IV) Diimine Complexes to Achieve C–C Bond-Forming Reductive Elimination," Organometallics 2011, 30, 3704-3707.

  141. 113

  142. Kubota, A; Sanford, M. S. "Palladium-Catalyzed Ligand-Directed Oxidative Functionalization of Cyclopropanes," Synthesis 2011, 16, 2579-2589.

  143. Loy, R. N.; Sanford, M. S. "Palladium-Catalyzed C–H Perfluoroalkylation of Arenes," Org. Lett. 2011, 13, 2548-2551.

  144. 113

  145. Ball, N. D.; Gary, J. B.; Ye, Y.; Sanford, M. S. "Mechanistic and Computational Studies of Oxidatively-Induced Aryl–CF3 Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation," J. Am. Chem. Soc. 2011, 133, 7577-7584.

  146. 113

  147. Stowers, K. J.; Fortner, K. C.; Sanford, M. S. "Aerobic Pd-Catalyzed sp3 C–H Olefination: A Route to Both N-Heterocyclic Scaffolds and Alkenes," J. Am. Chem. Soc. 2011, 133, 6541-6544.

  148. 113

  149. Racowski, J.; Sanford, M. S. "Carbon-Heteroatom Bond Forming Reductive Elimination from Palladium (IV) Complexes," In Topics in Organometallic Chemistry, Vol. 53, Allan Canty, Ed., Springer, 2011, 61-84.

  150. Satterfield, A. D.; Kubota, A.; Sanford, M. S. "Palladium-Catalyzed 1,1-Aryloxygenation of Terminal Olefins," Org. Lett. 2011, 13, 1076-1079.

  151. 113

  152. Lyons, T. W.; Hull, K. L.; Sanford M. S. "Controlling Site Selectivity in Palladium-Catalyzed C–H Oxidative Cross-Coupling," J. Am. Chem. Soc. 2011, 133, 4455-4464.

  153. 113

  154. Hickman, A. J.; Sanford, M. S. "Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene," ACS Catal. 2011, 1, 170-174.

  155. 113

  156. Wagner, A. M.; Sanford, M. S. "Palladium-Catalyzed C–H Arylation of 2,5-Disubstituted Pyrroles," Org. Lett. 2011, 13, 288-291.

  157. 113

  158. Ye, Y.; Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Oxidation of Catalytically Relevant Palladium Dimer with "CF3+": Formation and Reactivity of a Monomeric Palladium (IV) Aquo Product," J. Am. Chem. Soc. 2010, 132, 14682-14687.

  159. 113

  160. Higgs, A. T.; Zinn, P. J.; Sanford, M. S. "Synthesis and Reactivity of (Phpy)2Ni (Phpy = 2-Phenylpyridine)," Organometallics 2010, 29, 5446-5449.

  161. 113

  162. Emmert, M. H.; Villalobos, J. M.; Gary, J. B.; Sanford, M. S. "Pt and Pd Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation," Angew. Chem. Int. Ed. 2010, 49, 5884-5886.

  163. 113

  164. Kalyani, D.; Satterfield, A. D.; Sanford, M. S. "Palladium-Catalyzed Oxidative Arylhalogenation of Alkenes: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2010, 132, 8419-8427.

  165. 113

  166. Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Aryl-CF3 Bond-Forming Reductive Elimination from Palladium (IV)," J. Am. Chem. Soc. 2010, 132, 2878-2879.

  167. 113

  168. Remy, M. S.; Cundari, T.; Sanford, M. S. "Computational and Experimental Studies of Methyl Group Exchange Between Group 10 Metal Centers," Organometallics 2010, 29, 1522-1525.

  169. 113

  170. Neufeldt, S. R.; Sanford, M. S. "O-Acetyl Oximes as Transformable Directing Groups for Pd-Catalyzed C–H Functionalization," Org. Lett. 2010, 12, 532-535.

  171. 113

  172. Villalobos, J. M.; Hickman, A. J.; Sanford, M. S. "Platinum (II) Complexes Containing Quaternized Nitrogen Ligands: Synthesis, Stability, and Evaluation as Catalysts for Methane and Benzene H/D Exchange," Organometallics 2010, 29, 257-262.

  173. 113

  174. Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Synthesis and Reactivity of Palladium (II) Fluoride Complexes Containing Nitrogen Donor Ligands," Dalton Trans. 2010, 39, 632-640.

  175. 113

  176. Lyons, T. W.; Sanford, M. S. "Palladium-Catalyzed Ligand-Directed C–H Functionalization Reactions," Chem. Rev. 2010, 110, 1147-1169.

  177. Higgs, A. T.; Zinn, P. J.; Simmons, S. J.; Sanford, M. S. "Oxidatively Induced Carbon-Halogen Bond-Forming Reactions at Nickel," Organometallics 2009, 28, 6142-6144.

  178. 113

  179. Lanci, M. P.; Remy, M. S.; Kaminsky, W.; Mayer, J. M.; Sanford, M. S. "Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium (IV) Intermediates in a One Electron Oxidation Reaction," J. Am. Chem. Soc. 2009, 131, 15618-15620.

  180. 113

  181. Stowers, K. J.; Sanford, M. S. "Mechanistic Comparison Between Palladium-Catalyzed C–H Acetoxylation and C–H Chlorination," Org. Lett. 2009, 11, 4584-4587.

  182. 113

  183. Arnold, P. L.; Sanford, M. S.; Pearson, S. M. "Chelating N-Heterocyclic Carbene-Alkoxide as a Supporting Ligand for PdII/IV C–H Bond Functionalization Catalysis," J. Am. Chem. Soc. 2009, 131, 13912-13913.

  184. 113

  185. Hickman, A. J.; Villalobos, J. M.; Sanford, M. S. "A Quantitative Method to Assay Platinum Catalysts for Benzene H/D Exchange," Organometallics 2009, 28, 5316-5322.

  186. 113

  187. Deprez, N. R.; Sanford, M. S. "Synthetic and Mechanistic Studies of Pd-Catalyzed C–H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate," J. Am. Chem. Soc. 2009, 131, 11234-11241.

  188. 113

  189. Racowski, J. M.; Dick, A. R.; Sanford, M. S. "Detailed Study of C–O and C–C Bond-Forming Reductive Elimination from Stable C2N2O2 Palladium (IV) Complexes," J. Am. Chem. Soc. 2009, 131, 10974-10983.

  190. 113

  191. Hull, K. L.; Sanford, M. S. "Mechanism of Benzoquinone-Promoted Palladium-Catalyzed Oxidative Cross Coupling Reactions," J. Am. Chem. Soc. 2009, 131, 9651-9653.

  192. 113

  193. Ball, N. D.; Sanford, M. S. "Synthesis and Reactivity of a Mono-σ-Aryl Palladium (IV) Fluoride Complex," J. Am. Chem. Soc. 2009, 131, 3796-3797.

  194. 113

  195. Lyons, T. W.; Sanford, M. S. "PdII/IV-Catalyzed Cyclopropanation Reactions: Scope and Mechanism," Tetrahedron 2009, 65, 3211-3221.

  196. 113

  197. Desai, L. V.; Stowers, K. J.; Sanford, M. S. "Insights into Directing Group Ability in Palladium-Catalyzed C–H Bond Functionalization," J. Am. Chem. Soc. 2008, 130, 13285-13293.

  198. 113

  199. Whitfield, S. R.; Sanford, M. S. "Reactions of Platinum (II) Complexes with Chloride-Based Oxidants: Routes to PtIV and PtIII Products," Organometallics 2008, 27, 1683-1689.

  200. 113

  201. Kalyani, D.; Sanford, M. S. "Oxidatively Intercepting Heck Intermediates: Pd-Catalyzed 1,2- and 1,1-Arylhalogenation of Alkenes," J. Am. Chem. Soc. 2008, 130, 2150-2151.

  202. 113

  203. Whitfield, S. L.; Sanford, M. S. "Reactivity of PdII Complexes with Electrophilic Chlorinating Reagents: Isolation of PdIV Intermediates and Observation of C–Cl Bond-Forming Reductive Elimination," J. Am. Chem. Soc. 2007, 129, 15142-15143.

  204. 113

  205. Hull, K. L.; Sanford, M. S. "Catalytic and Highly Regioselective Cross-Coupling of Aromatic C–H Substrates," J. Am. Chem. Soc. 2007, 129, 11904-11905.

  206. 113

  207. Deprez, N. R.; Sanford, M. S. "Reactions of Hypervalent Iodine Reagents with Palladium: Mechanisms and Applications in Organic Synthesis," Inorg. Chem. 2007, 46, 1924-1935.

  208. 113

  209. Desai, L. V.; Sanford, M. S. "Construction of Tetrahydrofurans via PdII/IV-Catalyzed Aminooxygenation of Alkenes," Angew. Chem., Int. Ed. 2007, 46, 5737-5740.

  210. 113

  211. Welbes, L. L.; Lyons, T. W.; Cychosz, K. A.; Sanford, M. S. "Synthesis of Cyclopropanes via PdII/IV-Catalyzed Reactions of Enynes," J. Am. Chem. Soc. 2007, 129, 5836-5837.

  212. 113

  213. Dick, A. R.; Remy, M. S.; Kampf, J. W.; Sanford, M. S. "Carbon-Nitrogen Bond-Forming Reactions Between Palladacycles and Hypervalent Iodine Reagents," Organometallics 2007, 26, 1365-1370.

  214. 113

  215. Kalyani, D.; Sanford, M. S. "Chelate-Directed Oxidative Functionalization of Carbon-Hydrogen Bonds: Synthetic Applications and Mechanistic Insights," In Topics in Organometallic Chemistry, Vol. 24, Naoto Chatani, Ed., Springer, 2007, 85-116.

  216. Hull, K. L.; Lanni, E. L.; Sanford, M. S. "Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2006, 128, 14047-14049.

  217. 113

  218. Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. "Scope and Selectivity in Palladium-Catalyzed Directed C–H Bond Halogenation Reactions," Tetrahedron 2006, 62, 11483-11498.

  219. 113

  220. Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. "A Simple Catalytic Method for the Regioselective Halogenation of Arenes," Org. Lett. 2006, 8, 2523-2526.

  221. 113

  222. Hull, K. L.; Anani, W. Q.; Sanford, M. S. "Palladium-Catalyzed Fluorination of Carbon-Hydrogen Bonds," J. Am. Chem. Soc. 2006, 128, 7134-7135.

  223. 113

  224. Deprez, N. R.; Kalyani, D.; Krause, A.; Sanford, M. S. "Room Temperature Palladium-Catalyzed 2-Arylation of Indoles," J. Am. Chem. Soc. 2006, 128, 4972-4973.

  225. 113

  226. Desai, L. V.; Malik, H. A.; Sanford, M. S. "Oxone as an Inexpensive Safe and Environmentally Benign Oxidant for C–H Bond Oxygenation," Org. Lett. 2006, 8, 1141-1144.

  227. 113

  228. Kalberer, E. W.; Whitfield, S. R.; Sanford, M. S. "Application of Recyclable, Polymer-Immobilized IodineIII Oxidants in Catalytic C–H Bond Functionalization," J. Mol. Catal. A. 2006, 251, 108-113.

  229. 113

  230. Dick, A. R.; Sanford, M. S. "Transition Metal Catalyzed Catalyzed Oxidative Functionalization of Carbon-Hydrogen Bonds," Tetrahedron 200662, 2439-2463.

  231. 113

  232. Dick, A. R.; Kampf, J. W.; Sanford, M. S. "Unusually Stable Palladium (IV) Complexes: Detailed Mechanistic Investigation of C–O Bond-Forming Reductive Elimination," J. Am. Chem. Soc. 2005, 127, 12790-12791.

  233. 113

  234. Kalyani, D.; Sanford, M. S. "Regioselectivity in Palladium-Catalyzed C–H Activation/Oxygenation Reactions," Org. Lett. 2005, 7, 4149-4152.

  235. 113

  236. Kalyani, D.; Deprez, N. R.; Desai, L. V.; Sanford, M. S. "Oxidative C–H Activation/C–C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2005, 127, 7330-7331.

  237. 113

  238. Dick, A. R.; Kampf, J. W.; Sanford, M. S. "Platinum Model Studies for Palladium-Catalyzed Oxidative Functionalization of C–H Bonds," Organometallics 2005, 24, 482-485.

  239. 113

  240. Desai, L. V.; Hull , K. L.; Sanford, M. S. "Palladium-Catalyzed Oxygenation of Unactivated sp3 C–H Bonds," J. Am. Chem. Soc. 2004, 126, 9542-9543.

  241. 113

  242. Dick, A. R.; Hull, K. L.; Sanford, M. S. "A Highly Selective Catalytic Method for the Oxidative Functionalization of C–H Bonds," J. Am. Chem. Soc. 2004, 126, 2300-2301.

  243. 113