1. Cabrera, P. J.; Lee, M.; Sanford, M. S. "Second-Generation Palladium Catalyst System for Transannular C–H Functionalization of Azabicycloalkanes," J. Am. Chem. Soc. 2018, 140, 5599–5606.

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  3. Makaravage, K. J.; Shao, X.; Brooks, A. F.; Yang, L.; Sanford, M. S.; Scott, P. J. H. "Copper(II)-Mediated [11C]Cyanation of Arylboronic Acids and Arylstannanes," Org. Lett. 2018, 20, 1530–1533.

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  5. Hendricks, K. H.; Robinson, S. G.; Braten, M. N.; Sevov, C. S.; Helms, B. A.; Sigman, M. S.; Minteer, S. D.; Sanford, M. S. "High-Performance Oligomeric Catholytes for Effective Macromolecular Separation in Nonaqueous Redox Flow Batteries," ACS Cent. Sci. 2018, 4, 189–196.

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  7. James, B. R.; Boissonnault, J. A.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. "Structure activity relationships in metal–organic framework catalysts for the continuous flow synthesis of propylene carbonate from CO2 and propylene oxide," RSC Adv. 2018, 8, 2132–2137.

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  9. Mossine, A. V.; Brooks, A. F.; Bernard-Gauthier, V.; Bailey, J. J.; Ichiishi, N.; Schirrmacher, R.; Sanford, M. S.; Scott, P. J. H. "Automated Synthesis of PET Radiotracers by Copper-mediated 18F-Fluorination of Organoborons: Importance of the Order of Addition and Competing Protodeborylation," J. Label. Compd. Radiopharm. 2017, 1–9.

  10. Shrestha, A.; Lee, M.; Dunn, A. L.; Sanford, M. S. "Palladium-Catalyzed C–H Bond Acetoxylation via Electrochemical Oxidation," Org. Lett. 2017, 20, 204–207.

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  12. Ichiishi, N.; Malapit, C. A.; Wozniak, L.; Sanford, M. S. "Palladium- and Nickel-Catalyzed Decarbonylative C–S Coupling to Convert Thioesters to Thioethers," Org. Lett. 2017, 20, 44–47.

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  14. Sevov, C. S.; Hendriks, K. H.; Sanford, M. S. "Low-Potential Pyridinium Anolyte for Aqueous Redox Flow Batteries," J. Phys. Chem. C 2017, 121, 24376–24380.

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  16. Camasso, N. M.; Canty, A. J.; Ariafard, A.; Sanford, M. S. "Experimental and Computational Studies of High-Valent Nickel and Palladium Complexes," Organometallics 2017, 36, 4382–4393.

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  18. Hendriks, K. H.; Sevov, C. S.; Cook, M. E.; Sanford, M. S. "Multielectron Cycling of a Low-Potential Anolyte in Alkali Metal Electrolytes for Nonaqueous Redox Flow Batteries," ACS Energy Lett. 2017, 2, 2430–2435.

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  20. Ferguson, D. M. Bour, J. R.; Canty, A. J.; Kampf, J. W.; Sanford, M. S. "Stoichiometric and Catalytic Aryl–Perfluoroalkyl Coupling at Tri-tert-butylphosphine Palladium(II) Complexes," J. Am. Chem. Soc. 2017, 139, 11662–11665.

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  22. Malapit, C. A.; Ichiishi, N.; Sanford, M. S. "Pd-Catalyzed Decarbonylative Cross-Couplings of Aroyl Chlorides," Org. Lett. 2017, 19, 4142–4145.

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  24. McCammant, M. S.; Thompson, S.; Brookes, A. F.; Krska, S. W.; Scott, P. J. H.; Sanford, M. S. "Cu-Mediated C–H 18F-Fluorination of Electron-Rich (Hetero)arenes," Org. Lett. 2017, 19, 3939–3942.

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  26. Cismesia, M. A.; Ryan, S. J.; Bland, D. C.; Sanford, M. S. "Multiple Approaches to the In Situ Generation of Anhydrous Tetraalkylammonium Fluoride Salts for SNAr Fluorination Reactions," J. Org. Chem. 2017, 82, 5020–5026.

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  28. Chong, E.; Kampf, J. W.; Ariafard, A.; Canty, A. J.; Sanford, M. S. "Oxidatively Induced C–H Activation at High Valent Nickel," J. Am. Chem. Soc. 2017, 139, 6058–6061.

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  30. Bour, J. R.; Kariofillis, S. K.; Sanford, M. S. "Synthesis, Reactivity, and Catalytic Applications of Isolable (NHC)Cu(CHF2) Complexes," Organometallics 2017, 36, 1220–1223.

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  32. Mossine, A. V.; Brooks, A. F.; Ichiishi, N.; Makaravage, K. J.; Sanford, M. S.; Scott, P. J. H. "Development of Customized [18F]Fluoride Elution Techniques for the Enhancement of Copper-Mediated Late-Stage Radiofluorination," Scientific Reports 2017, 7, 233.

  33. Canty, A. J.; Ariafard, A.; Camasso, N. M.; Higgs, A. T.; Yates, B. F.; Sanford, M. S. "Computational study of C(sp3)–O bond formation at a PdIV centre," Dalton Trans. 2017, 46, 3742–3748.

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  35. Sevov, C. S.; Hickey, D. P.; Cook, M. E.; Robinson, S. G.; Barnett, S.; Minteer, S. D.; Sigman, M. S.; Sanford, M. S. "Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications," J. Am. Chem. Soc. 2017, 139, 2924–2927.

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  37. Schimler, S. D.; Cismesia, M. A.; Hanley, P. S.; Froese, R. D. J.; Jansma, M. J.; Bland, D. C.; Sanford, M. S. "Nucleophilic Deoxyfluorination of Phenols via Aryl Fluorosulfonate Intermediates," J. Am. Chem. Soc. 2017, 139, 1452–1455.

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  39. Lee, M.; Sanford, M. S. "Remote C(sp3)–H Oxygenation of Protonated Aliphatic Amines with Potassium Persulfate," Org. Lett. 2017, 19, 572–575.

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  41. Lotz, M. D.; Camasso, N. M.; Canty, A. J.; Sanford, M. S. "Role of Silver Salts in Palladium-Catalyzed Arene and Heteroarene C–H Functionalization Reactions," Organometallics 2017, 36, 165–171.

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  43. Meucci, E. A.; Camasso, N. M.; Sanford, M. S. "An Organometallic NiIV Complex That Participates in Competing Transmetalation and C(sp2)–O Bond-Forming Reductive Elimination," Organometallics 2017, 36, 247–250.

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  45. Bour, J. R.; Camasso, N. M.; Meucci, E. A.; Kampf, J. W.; Canty, A. J.; Sanford, M. S. "Carbon–Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) Complexes," J. Am. Chem. Soc. 2016, 138, 16105–16111.

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  47. Sevov, C. S.; Samaroo, S. K.; Sanford, M. S. "Cyclopropenium Salts as Cyclable, High-Potential Catholytes in Nonaqueous Media," Adv. Energy Mater. 2016, 1602027.

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  49. Sevov, C. S.; Fisher, S. L.; Thompson, L. T.; Sanford, M. S. "Mechanism-Based Development of a Low-Potential, Soluble, and Cyclable Multielectron Anolyte for Nonaqueous Redox Flow Batteries," J. Am. Chem. Soc. 2016, 138, 15378–15384.

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  51. Makaravage, K. J.; Brooks, A. F.; Mossine, A. V.; Sanford, M. S.; Scott, P. J. H. "Copper-Mediated Radiofluorination of Arylstannanes with [18F]KF," Org. Lett. 2016, 18, 5440–5443.

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  53. Schimler, S. D.; Sanford, M. S. "Copper-Mediated Functionalization of Aryl Trifluoroborates," Synlett. 2016, 27, 2279–2284.

  54. Rezayee, N. M.; Samblanet, D. C.; Sanford, M. S. "Iron-Catalyzed Hydrogenation of Amides to Alcohols and Amines," ACS Catal. 2016, 6, 6377–6383.

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  56. Mbofana, C. T.; Chong, E.; Lawniczak, J.; Sanford, M. S. "Iron-Catalyzed Oxyfunctionalization of Aliphatic Amines at Remote Benzylic C–H Sites," Org. Lett. 2016, 18, 4258–4261.

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  58. Pendleton, I. M.; Pérez-Temprano, M. H.; Sanford, M. S.; Zimmerman, P. M. "Experimental and Computational Assessment of Reactivity and Mechanism in C(sp3)–N Bond-Forming Reductive Elimination from PdIV," J. Am. Chem. Soc. 2016, 138, 6049–6060.

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  60. Genna, D. T.; Pfund, L. Y.; Samblanet, D. C.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. "Rhodium Hydrogenation Catalysts Supported in Metal Organic Frameworks: Influence of the Framework on Catalytic Activity and Selectivity," ACS Catal. 2016, 6, 3569–3574.

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  62. Brewster, T. P.; Rezayee, N. M.; Culakova, Z.; Sanford, M. S.; Goldberg, K. I. "Base-Free Iridium-Catalyzed Hydrogenation of Esters and Lactones," ACS Catal. 2016, 6, 3113–3117.

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  64. Cook, A. K.; Schimler, S. D.; Matzger, A. J.; Sanford, M. S. "Catalyst-Controlled Selectivity in the C–H Borylation of Methane and Ethane," Science 2016, 351, 1421–1424.

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  66. Sanford, M. S.; Scott, P. J. H. "Moving Metal-Mediated 18F‐Fluorination from Concept to Clinic," ACS Cent. Sci. 2016, 2, 128–130.

  67. Topczewski, J. T.; Cabrera, P. J.; Saper, N. I.; Sanford, M. S. "Palladium-Catalysed Transannular C–H Functionalization of Alicyclic Amines," Nature 2016, 531, 220–224.

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  69. Schimler, S. D.; Ryan, S. J.; Bland, D. C.; Anderson, J. E.; Sanford, M. S. "Anhydrous Tetramethylammonium Fluoride for Room-Temperature SNAr Fluorination," J. Org. Chem. 2015, 80, 12137–12145.

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  71. Mossine, A. V.; Brooks, A. F.; Makaravage, K. J.; Miller, J. M.; Ichiishi, N.; Sanford, M. S.; Scott, P. J. H. "Synthesis of [18F]Arenes via the Copper-Mediated [18F]Fluorination of Boronic Acids," Org. Lett. 2015, 17, 5780–5783.

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  73. Sevov, C. S.; Brooner, R. E. M.; Chénard, E.; Assary, R. S.; Moore, J. S.; Rodríguez-López, J.; Sanford, M. S. "Evolutionary Design of Low Molecular Weight Organic Anolyte Materials for Applications in Nonaqueous Redox Flow Batteries," J. Am. Chem. Soc. 2015, 137, 14465–14472.

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  75. Cabrera, P. J.; Yang, X.; Suttil, J. A.; Brooner, R. E. M.; Thompson, L. T.; Sanford, M. S. "Evaluation of Tris-Bipyridine Chromium Complexes for Flow Battery Applications: Impact of Bipyridine Ligand Structure on Solubility and Electrochemistry," Inorg. Chem. 2015, 54, 10214–10223.

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  77. Cook, A.; Sanford, M. S. "C–Hal Bond Formation by Arene C–H Activation," In Catalytic Transformations via C-H Activation, Vol. 2; Science of Synthesis, Yu, J.-Q., 2015, 183–219.

  78. Lee, M.; Sanford, M. S. "Platinum-Catalyzed, Terminal-Selective C(sp3)–H Oxidation of Aliphatic Amines," J. Am. Chem. Soc. 2015, 137, 12796–12799.

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  80. Bour, J. R.; Camasso, N. M.; Sanford, M. S. "Oxidation of NiII to NiIV with Aryl Electrophiles Enables Ni-Mediated Aryl–CF3 Coupling," J. Am. Chem. Soc. 2015, 137, 8034–8037.

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  82. Cabrera, P. J.; Yang, X.; Suttil, J. A.; Hawthorne, K. L. Brooner, R. E. M.; Sanford, M. S.; Thompson, L. T. "Complexes Containing Redox Noninnocent Ligands for Symmetric, Multielectron Transfer Nonaqueous Redox Flow Batteries, " J. Phys. Chem. C 2015, 119, 15882–15889.

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  84. Ryan, S. J.; Schimler, S. D.; Bland, D. C.; Sanford, M. S. "Acyl Azolium Fluorides for Room Temperature Nucleophilic Aromatic Fluorination of Chloro- and Nitroarenes," Org. Lett. 2015, 17, 1866–1869.

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  86. Suttil, J. A.; Kucharyson, J. F.; Escalante-Garcia, I. L.; Cabrera, P. J.; James, B. R.; Savinell, R. F.; Sanford, M. S.; Thompson, L. T. "Metal Acetylacetonate Complexes for High Energy Density Non-Aqueous Redox Flow Batteries," J. Mater. Chem. A 2015, 3, 7929–7938.

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  88. Canty, A. J.; Ariafard, A.; Yates, B. F.; Sanford, M. S. "Computational Study of Intramolecular Arene Palladation at a Palladium(IV) Center," Organometallics 2015, 34, 1085–1090.

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  90. Cook, A. K.; Sanford, M. S. "Mechanism of the Palladium-Catalyzed Arene C–H Acetoxylation: A Comparison of Catalysis and Ligand Effects," J. Am. Chem. Soc. 2015, 137, 3109–3118.

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  92. Camasso, N. M.; Sanford, M. S. "Design, Synthesis, and Carbon-Heteroatom Coupling Reactions of Organometallic Nickel (IV) Complexes," Science 2015, 347, 1218–1220.

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  94. Rezayee, N. M.; Huff, C. A.; Sanford, M. S. "Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol," J. Am. Chem. Soc. 2015, 137, 1028–1031.

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  96. Topczewski, J. J.; Sanford, M. S. "Carbon–Hydrogen (C–H) Bond Activation at PdIV: A Frontier in C–H Functionalization Catalysis," Chem. Sci. 2014, 6, 70–76.

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  98. Ichiishi, N.; Canty, A. J.; Yates, B. F.; Sanford, M. S. "Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the CuI/CuIII Manifold in Copper Catalysis," Organometallics 2014, 33, 5525–5534.

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  100. Brooks, A. F.; Topczewski, J. J.; Ichiishi, N.; Sanford, M. S.; Scott, P. J. H. "Late-Stage [18F]Fluorination: New Solutions to Old Problems," Chem. Sci. 2014, 5, 4545–4553.

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  102. Camasso, N. M.; Pérez-Temprano, M. H.; Sanford, M. S. "C(sp3)–O Bond-Forming Reductive Elimination from PdIV with Diverse Oxygen Nucleophiles," J. Am. Chem. Soc. 2014, 136, 12771–12775.

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  104. Allen, L. J.; Lee, S. H.; Cheng, Y.; Hanley, P. S.; Muhuhi, J. M.; Kane, E.; Powers, S. L.; Anderson, J. E.; Bell, B. M.; Roth, G. A.; Sanford, M. S.; Bland, D. C. "Developing Efficient Nucleophilic Fluorination Methods and Application to Substituted Picolinate Esters," Org. Process Res. Dev. 2014, 18, 1045–1054.

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  106. Maleckis, A.; Sanford, M. S. "Synthesis of Fluoroalkyl Palladium and Nickel Complexes via Decarbonylation of Acylmetal Species" Organometallics 2014, 33, 3831–3839.

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  108. Ichiishi, N.; Brooks, A. F.; Topczewski, J. J.; Rodnick, M. E.; Sanford, M. S.; Scott, P. J. H. "Copper-Catalyzed [18F]Fluorination of (Mesityl)(aryl)iodonium Salts," Org. Lett. 2014, 16, 3224–3227.

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  110. Lotz, M. D.; Remy, M. S.; Lao, D. B.; Ariafard, A.; Yates, B. F.; Canty, A. J.; Mayer, J. M.; Sanford, M. S. "Formation of Ethane from Mono-Methyl PalladiumII Complexes," J. Am. Chem. Soc. 2014, 136, 8237–8242.

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  112. Allen, L. J.; Muhuhi, J. M.; Bland, D. C.; Merzel, R.; Sanford, M. S. "Mild Fluorination of Chloropyridines with In Situ Generated Anhydrous Tetrabutylammonium Fluoride," J. Org. Chem. 2014, 79, 5827–5833.

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  114. Maleckis, A.; Sanford, M. S. "Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source," Organometallics 2014, 33, 2653–2660.

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  116. Allen, L. J.; Cabrera, P. J.; Lee, M.; Sanford, M. S. "N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes," J. Am. Chem. Soc. 2014, 136, 5607–5610.

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  118. Pérez-Temprano, M. H.; Racowski, J. M.; Kampf, J. W.; Sanford, M. S. "Competition Between sp 3-C–N vs sp 3-C–F Reductive Elimination from PdIV Complexes," J. Am. Chem. Soc. 2014, 136, 4097–4100.

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  120. Wagner, A. M.; Sanford, M. S. "Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers," J. Org. Chem. 2014, 79, 2263–2267.

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  122. Ye, Y.; Schimler, S. D.; Hanley, P. S.; Sanford, M. S. " Cu(OTf)2-Mediated Fluorination of Aryltrifluoroborates with Potassium Fluoride, " J. Am. Chem. Soc. 2013, 135, 16292–16295.

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  124. Wagner, A. M. ; Hickman, A. J. ; Sanford, M. S. "Platinum-Catalyzed C–H Arylation of Simple Arenes," J. Am. Chem. Soc. 2013, 135, 15710–15713.

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  126. Cook, A. K.; Emmert, M. H.; Sanford, M. S. "Steric Control of Site Selectivity in the Pd-Catalyzed C–H Acetoxylation of Simple Arenes," Org. Lett. 2013, 15, 5428–5431.

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  128. Lehman, M. C.; Gary, J. B.; Boyle, P. D.; Sanford, M. S.; Ison, E. A. "Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*IrIII(L) Complexes," ACS Catalysis. 2013, 3, 2304–2310.

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  130. Huff, C. A.; Sanford, M. S. "Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex," ACS Catalysis. 2013, 3, 2412–2416.

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  132. Ichiishi, N.; Canty, A. J.; Yates, B. F.; Sanford, M. S. "Cu-Catalyzed Fluorination of Diaryliodonium Salts With KF," Org. Lett. 2013, 15, 5134–5137.

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  134. Genna, D. T.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. "Heterogenization of Homogeneous Catalysts in Metal–Organic Frameworks Via Cation Exchange," J. Am. Chem. Soc. 2013, 135, 10586–10589.

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  136. Huff, C. A.; Kampf, J. W.; Sanford, M. S. "Reversible Carbon-Carbon Bond Formation Between Carbonyl Compounds and a Ruthenium Pincer Complex," Chem. Commun. 2013, 49, 7147–7149.

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  138. Sanhueza, I. A.; Wagner, A. M.; Sanford, M. S.; Schoenebeck, F. "On the Role of Anionic Ligands in the Site-Selectivity of Oxidative C–H Functionalization Reactions of Arenes." Chem. Sci. 2013, 4, 2767–2775.

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  140. Gary, J. B.; Cook, A. K.; Sanford, M. S. "Palladium Catalysts Containing Pyridinium-Substituted Pyridine Ligands for the C–H Oxygenation of Benzene with K2S2O8," ACS Catalysis. 2013, 3, 700–703.

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  142. Seigerman, C. K.; Micyus, T. M.; Neufeldt, S. R.; Sanford, M. S. "Palladium-Catalyzed C–H Arylation Using Aryltrifluoroborates in Conjunction with a MnIII Oxidant under Mild Conditions," Tetrahedron. 2013, 69, 5580–5587.

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  144. Maleckis, A.; Kampf, J. W.; Sanford, M. S. "A Detailed Study of Acetate-Assisted C–H Activation at Palladium (IV) Centers," J. Am. Chem. Soc. 2013, 135, 6618–6625.

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  146. Neufeldt, S. R.; Seigerman, C. K.; Sanford, M. S. "Mild Palladium-Catalyzed C–H Alkylation Using Potassium Alkyltrifluoroborates in Combination with MnF3," Org. Lett. 2013, 15, 2302–2305.

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  148. Ye, Y.; Sanford, M. S. "Mild Copper-Mediated Fluorination of Aryl Stannanes and Aryl Trifluoroborates," J. Am. Chem. Soc. 2013, 135, 4648–4651.

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  150. Canty, A. J.; Ariafard, A.; Sanford, M. S.; Yates, B. F. "Mechanism of Pd-Catalyzed Ar-Ar Bond Formation Involving Ligand-Directed C-H Arylation and Diaryliodonium Oxidants: Computational Studies of Orthopalladation at Binuclear PdII Centers, Oxidation To Form Binuclear Palladium (III) Species, and Ar···Ar Reductive Coupling, " Organometallics 2013, 32, 544–555.

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  152. Neufeldt, S. R.; Sanford, M. S. "Asymmetric Chiral Ligand-Directed Alkene Dioxygenation," Org. Lett. 2013, 15, 46≠49.

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  154. McMurtrey, K. B.; Sanford, M. S. "C–F Bond-Forming Reactions," In Cross-Coupling and Heck-Type Reactions from the Science of Synthesis Reference Library. Vol. 2, John P. Wolfe, Ed., Thieme, 2012.

  155. Neufeldt, S. R.; Sanford, M. S. "Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed C–H Arylation with Diaryliodonium Salts," Adv. Synth. Catal. 2012, 354, 3517–3522.

  156. Ye,Y.; Kuenzi, S. A.; Sanford, M. S. "Practical Method for the Cu-Mediated Trifluoromethylation of Arylboronic Acids with CF3 Radicals Derived from NaSO2CF3 and tert-Butyl Hydroperoxide (TBHP)," Org. Lett. 2012, 14, 4979–4981.

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  158. Stowers, K. J.; Kubota, A.; Sanford, M. S. "Nitrate as a Redox Co-Catalyst for the Aerobic Pd-Catalyzed Oxidation of Unactivated sp3-C–H Bonds," Chem. Sci. 2012, 3, 3192–3195.

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  160. McMurtrey, K. B.; Racowski, J. M.; Sanford, M. S. "Pd-Catalyzed C-H Fluorination with Nucleophilic Fluoride," Org. Lett. 2012, 14, 4094–4097.

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  162. Powers, D. C.; Lee, E.; Ariafard, A.; Sanford, M. S.; Yates, B. F.; Canty, A. J.; Ritter, T. "Connecting Binuclear PdIII and Mononuclear PdIV Chemistry by Pd-Pd Bond Cleavage," J. Am. Chem. Soc. 2012, 134, 12002–12009.

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  164. Ye, Y.; Sanford, M. S. "Investigations into Transition-Metal-Catalyzed Arene Trifluoromethylation Reactions," Synlett. 2012, 23, 2005–2013.

  165. Gary, J. B; Carter, T. J.; Sanford, M. S. "RhIII Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange," Top. Catal. 2012, 55, 565–570.

  166. Huff, C. A.; Kampf, J. W.; Sanford, M. S. "Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO)," Organometallics 2012, 31, 4643–4635.

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  168. Hickman, A. J.; Sanford, M. S. "High-Valent Organometallic Copper and Palladium in Catalysis," Nature 2012, 484, 177–185.

  169. Ye, Y.; Sanford, M. S. "Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I," J. Am. Chem. Soc. 2012, 134, 9034–9037.

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  171. Neufeldt, S. R.; Sanford, M. S. "Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization" Acc. Chem. Res. 2012, 45, 936–946.

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  173. Kubota, A.; Emmert, M. H.; Sanford, M. S. "Pyridine Ligands as Promoters in PdII/0-Catalyzed C–H Olefination Reactions" Org. Lett. 2012, 14, 1760–1763.

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  175. Hickman, A. J.; Cismesia, M. A.; Sanford, M. S. "Structure-Activity Relationship Study of Diimine PtII Catalysts for H/D Exchange" Organometallics 2012, 31, 1761–1766.

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  177. Racowski, J. M.; Gary, B. G.; Sanford, M. S. "Carbon(sp3)–Fluorine Bond-Forming Reductive Elimination from Palladium (IV)" Angew. Chem. Int. Ed 2012, 51, 3414–3417

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  179. Park, T.-H.; Hickman, A. J.; Koh, K.; Martin, S.; Wong-Foy, A. G.; Sanford, M. S.; Matzger, A. J. "Highly Dispersed Palladium (II) in a Defective MOF: Application to C–H Activation and Functionalization," J. Am. Chem. Soc. 2011, 133, 20138–20141.

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  181. Maleckis, A; Sanford, M. S. "Facial Tridentate Ligands for Stabilizing Palladium (IV) Complexes," Organometallics 2011, 30, 6617–6627.

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  183. Kalyani, D.; McMurtrey, K. B.; Neufeldt, S. R.; Sanford, M. S. "Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis," J. Am. Chem. Soc. 2011, 133, 18566–18569.

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  185. Huff, C. A.; Sanford, M. S. "Cascade Catalysis for the Homogeneous Hydrogenation of CO2 to Methanol," J. Am. Chem. Soc. 2011, 133, 18122–18125.

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  187. Gary, J. B.; Sanford, M. S. "Participation of Carbonyl Oxygen in Carbon-Carboxylate Bond-Forming Reductive Elimination from Palladium," Organometallics 2011, 30, 6143–6149.

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  189. Racowski, J. M.; Ball, N. D.; Sanford, M. S. "C–H Bond Activation at Palladium (IV) Centers," J. Am. Chem. Soc. 2011, 133, 18022–18025.

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  191. Ye, Y.; Lee, S.; Sanford, M. S. "Silver-Mediated Trifluoromethylation of Arenes Using TMSCF3," Org. Lett. 2011, 13, 5464–5467.

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  193. Emmert, M. H.; Cook, A. K.; Xie, Y. J.; Sanford, M. S. "Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected C–H Oxygenation of Arenes," Angew. Chem. Int. Ed. 2011, 50, 9409–9412.

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  195. Lanci, M. P.; Remy, M. S.; Lao, D. B.; Sanford, M. S.; Mayer, J. M. "Modulating Sterics in Trimethylplatinum (IV) Diimine Complexes to Achieve C–C Bond-Forming Reductive Elimination," Organometallics 2011, 30, 3704–3707.

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  197. Kubota, A; Sanford, M. S. "Palladium-Catalyzed Ligand-Directed Oxidative Functionalization of Cyclopropanes," Synthesis 2011, 16, 2579–2589.

  198. Loy, R. N.; Sanford, M. S. "Palladium-Catalyzed C–H Perfluoroalkylation of Arenes," Org. Lett. 2011, 13, 2548–2551.

  199. 113

  200. Ball, N. D.; Gary, J. B.; Ye, Y.; Sanford, M. S. "Mechanistic and Computational Studies of Oxidatively-Induced Aryl–CF3 Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation," J. Am. Chem. Soc. 2011, 133, 7577–7584.

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  202. Stowers, K. J.; Fortner, K. C.; Sanford, M. S. "Aerobic Pd-Catalyzed sp3 C–H Olefination: A Route to Both N-Heterocyclic Scaffolds and Alkenes," J. Am. Chem. Soc. 2011, 133, 6541–6544.

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  204. Racowski, J.; Sanford, M. S. "Carbon-Heteroatom Bond Forming Reductive Elimination from Palladium (IV) Complexes," In Topics in Organometallic Chemistry, Vol. 53, Allan Canty, Ed., Springer, 2011, 61-84.

  205. Satterfield, A. D.; Kubota, A.; Sanford, M. S. "Palladium-Catalyzed 1,1-Aryloxygenation of Terminal Olefins," Org. Lett. 2011, 13, 1076–1079.

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  207. Lyons, T. W.; Hull, K. L.; Sanford M. S. "Controlling Site Selectivity in Palladium-Catalyzed C–H Oxidative Cross-Coupling," J. Am. Chem. Soc. 2011, 133, 4455–4464.

  208. 113

  209. Hickman, A. J.; Sanford, M. S. "Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene," ACS Catal. 2011, 1, 170–174.

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  211. Wagner, A. M.; Sanford, M. S. "Palladium-Catalyzed C–H Arylation of 2,5-Disubstituted Pyrroles," Org. Lett. 2011, 13, 288–291.

  212. 113

  213. Ye, Y.; Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Oxidation of Catalytically Relevant Palladium Dimer with "CF3+": Formation and Reactivity of a Monomeric Palladium (IV) Aquo Product," J. Am. Chem. Soc. 2010, 132, 14682–14687.

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  215. Higgs, A. T.; Zinn, P. J.; Sanford, M. S. "Synthesis and Reactivity of (Phpy)2Ni (Phpy = 2-Phenylpyridine)," Organometallics 2010, 29, 5446–5449.

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  217. Emmert, M. H.; Villalobos, J. M.; Gary, J. B.; Sanford, M. S. "Pt and Pd Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation," Angew. Chem. Int. Ed. 2010, 49, 5884–5886.

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  219. Kalyani, D.; Satterfield, A. D.; Sanford, M. S. "Palladium-Catalyzed Oxidative Arylhalogenation of Alkenes: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2010, 132, 8419–8427.

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  221. Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Aryl-CF3 Bond-Forming Reductive Elimination from Palladium (IV)," J. Am. Chem. Soc. 2010, 132, 2878–2879.

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  223. Remy, M. S.; Cundari, T.; Sanford, M. S. "Computational and Experimental Studies of Methyl Group Exchange Between Group 10 Metal Centers," Organometallics 2010, 29, 1522–1525.

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  225. Neufeldt, S. R.; Sanford, M. S. "O-Acetyl Oximes as Transformable Directing Groups for Pd-Catalyzed C–H Functionalization," Org. Lett. 2010, 12, 532–535.

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  227. Villalobos, J. M.; Hickman, A. J.; Sanford, M. S. "Platinum (II) Complexes Containing Quaternized Nitrogen Ligands: Synthesis, Stability, and Evaluation as Catalysts for Methane and Benzene H/D Exchange," Organometallics 2010, 29, 257–262.

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  229. Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Synthesis and Reactivity of Palladium (II) Fluoride Complexes Containing Nitrogen Donor Ligands," Dalton Trans. 2010, 39, 632–640.

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  231. Lyons, T. W.; Sanford, M. S. "Palladium-Catalyzed Ligand-Directed C–H Functionalization Reactions," Chem. Rev. 2010, 110, 1147–1169.

  232. Higgs, A. T.; Zinn, P. J.; Simmons, S. J.; Sanford, M. S. "Oxidatively Induced Carbon-Halogen Bond-Forming Reactions at Nickel," Organometallics 2009, 28, 6142–6144.

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  234. Lanci, M. P.; Remy, M. S.; Kaminsky, W.; Mayer, J. M.; Sanford, M. S. "Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium (IV) Intermediates in a One Electron Oxidation Reaction," J. Am. Chem. Soc. 2009, 131, 15618–15620.

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  236. Stowers, K. J.; Sanford, M. S. "Mechanistic Comparison Between Palladium-Catalyzed C–H Acetoxylation and C–H Chlorination," Org. Lett. 2009, 11, 4584–4587.

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  238. Arnold, P. L.; Sanford, M. S.; Pearson, S. M. "Chelating N-Heterocyclic Carbene-Alkoxide as a Supporting Ligand for PdII/IV C–H Bond Functionalization Catalysis," J. Am. Chem. Soc. 2009, 131, 13912–13913.

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  240. Hickman, A. J.; Villalobos, J. M.; Sanford, M. S. "A Quantitative Method to Assay Platinum Catalysts for Benzene H/D Exchange," Organometallics 2009, 28, 5316–5322.

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  242. Deprez, N. R.; Sanford, M. S. "Synthetic and Mechanistic Studies of Pd-Catalyzed C–H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate," J. Am. Chem. Soc. 2009, 131, 11234–11241.

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  244. Racowski, J. M.; Dick, A. R.; Sanford, M. S. "Detailed Study of C–O and C–C Bond-Forming Reductive Elimination from Stable C2N2O2 Palladium (IV) Complexes," J. Am. Chem. Soc. 2009, 131, 10974–10983.

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  246. Hull, K. L.; Sanford, M. S. "Mechanism of Benzoquinone-Promoted Palladium-Catalyzed Oxidative Cross Coupling Reactions," J. Am. Chem. Soc. 2009, 131, 9651–9653.

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  248. Ball, N. D.; Sanford, M. S. "Synthesis and Reactivity of a Mono-σ-Aryl Palladium (IV) Fluoride Complex," J. Am. Chem. Soc. 2009, 131, 3796–3797.

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  250. Lyons, T. W.; Sanford, M. S. "PdII/IV-Catalyzed Cyclopropanation Reactions: Scope and Mechanism," Tetrahedron 2009, 65, 3211–3221.

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  252. Desai, L. V.; Stowers, K. J.; Sanford, M. S. "Insights into Directing Group Ability in Palladium-Catalyzed C–H Bond Functionalization," J. Am. Chem. Soc. 2008, 130, 13285–13293.

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  254. Whitfield, S. R.; Sanford, M. S. "Reactions of Platinum (II) Complexes with Chloride-Based Oxidants: Routes to PtIV and PtIII Products," Organometallics 2008, 27, 1683–1689.

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  256. Kalyani, D.; Sanford, M. S. "Oxidatively Intercepting Heck Intermediates: Pd-Catalyzed 1,2- and 1,1-Arylhalogenation of Alkenes," J. Am. Chem. Soc. 2008, 130, 2150–2151.

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  258. Whitfield, S. L.; Sanford, M. S. "Reactivity of PdII Complexes with Electrophilic Chlorinating Reagents: Isolation of PdIV Intermediates and Observation of C–Cl Bond-Forming Reductive Elimination," J. Am. Chem. Soc. 2007, 129, 15142–15143.

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  260. Hull, K. L.; Sanford, M. S. "Catalytic and Highly Regioselective Cross-Coupling of Aromatic C–H Substrates," J. Am. Chem. Soc. 2007, 129, 11904–11905.

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  262. Deprez, N. R.; Sanford, M. S. "Reactions of Hypervalent Iodine Reagents with Palladium: Mechanisms and Applications in Organic Synthesis," Inorg. Chem. 2007, 46, 1924–1935.

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  264. Desai, L. V.; Sanford, M. S. "Construction of Tetrahydrofurans via PdII/IV-Catalyzed Aminooxygenation of Alkenes," Angew. Chem., Int. Ed. 2007, 46, 5737–5740.

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  266. Welbes, L. L.; Lyons, T. W.; Cychosz, K. A.; Sanford, M. S. "Synthesis of Cyclopropanes via PdII/IV-Catalyzed Reactions of Enynes," J. Am. Chem. Soc. 2007, 129, 5836–5837.

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  268. Dick, A. R.; Remy, M. S.; Kampf, J. W.; Sanford, M. S. "Carbon-Nitrogen Bond-Forming Reactions Between Palladacycles and Hypervalent Iodine Reagents," Organometallics 2007, 26, 1365–1370.

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  270. Kalyani, D.; Sanford, M. S. "Chelate-Directed Oxidative Functionalization of Carbon-Hydrogen Bonds: Synthetic Applications and Mechanistic Insights," In Topics in Organometallic Chemistry, Vol. 24, Naoto Chatani, Ed., Springer, 2007, 85–116.

  271. Hull, K. L.; Lanni, E. L.; Sanford, M. S. "Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2006, 128, 14047-14049.

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  273. Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. "Scope and Selectivity in Palladium-Catalyzed Directed C–H Bond Halogenation Reactions," Tetrahedron 2006, 62, 11483–11498.

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  275. Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. "A Simple Catalytic Method for the Regioselective Halogenation of Arenes," Org. Lett. 2006, 8, 2523–2526.

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  277. Hull, K. L.; Anani, W. Q.; Sanford, M. S. "Palladium-Catalyzed Fluorination of Carbon-Hydrogen Bonds," J. Am. Chem. Soc. 2006, 128, 7134–7135.

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  279. Deprez, N. R.; Kalyani, D.; Krause, A.; Sanford, M. S. "Room Temperature Palladium-Catalyzed 2-Arylation of Indoles," J. Am. Chem. Soc. 2006, 128, 4972–4973.

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  281. Desai, L. V.; Malik, H. A.; Sanford, M. S. "Oxone as an Inexpensive Safe and Environmentally Benign Oxidant for C–H Bond Oxygenation," Org. Lett. 2006, 8, 1141–1144.

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  283. Kalberer, E. W.; Whitfield, S. R.; Sanford, M. S. "Application of Recyclable, Polymer-Immobilized IodineIII Oxidants in Catalytic C–H Bond Functionalization," J. Mol. Catal. A. 2006, 251, 108–113.

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  285. Dick, A. R.; Sanford, M. S. "Transition Metal Catalyzed Catalyzed Oxidative Functionalization of Carbon-Hydrogen Bonds," Tetrahedron 200662, 2439–2463.

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  287. Dick, A. R.; Kampf, J. W.; Sanford, M. S. "Unusually Stable Palladium (IV) Complexes: Detailed Mechanistic Investigation of C–O Bond-Forming Reductive Elimination," J. Am. Chem. Soc. 2005, 127, 12790–12791.

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  289. Kalyani, D.; Sanford, M. S. "Regioselectivity in Palladium-Catalyzed C–H Activation/Oxygenation Reactions," Org. Lett. 2005, 7, 4149–4152.

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  291. Kalyani, D.; Deprez, N. R.; Desai, L. V.; Sanford, M. S. "Oxidative C–H Activation/C–C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2005, 127, 7330–7331.

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  293. Dick, A. R.; Kampf, J. W.; Sanford, M. S. "Platinum Model Studies for Palladium-Catalyzed Oxidative Functionalization of C–H Bonds," Organometallics 2005, 24, 482–485.

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  295. Desai, L. V.; Hull , K. L.; Sanford, M. S. "Palladium-Catalyzed Oxygenation of Unactivated sp3 C–H Bonds," J. Am. Chem. Soc. 2004, 126, 9542–9543.

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  297. Dick, A. R.; Hull, K. L.; Sanford, M. S. "A Highly Selective Catalytic Method for the Oxidative Functionalization of C–H Bonds," J. Am. Chem. Soc. 2004, 126, 2300–2301.

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