1. Aguilera, E. Y.; Sanford, M. S. "Model Complexes for the Palladium-Catalyzed Transannular C–H Functionalization of Alicyclic Amines," Organometallics, Article ASAP.

  2. 122

  3. Mantell, M.; Kampf, J. W.; Sanford, M. S. "Improved Synthesis of [CpRRhCl2]2 Complexes," Organometallics, Article ASAP.

  4. 122

  5. Schimler, S. D.; Froese, R. D. J.; Bland, D. C.; Sanford, M. S. "Reactions of Arylsulfonate Electrophiles with NMe4F: Mechanistic Insight, Reactivity, and Scope," J. Org. Chem., 83, 11178–11190.

  6. 122

  7. Cabrera, P. J.; Lee, M.; Sanford, M. S. "Second-Generation Palladium Catalyst System for Transannular C–H Functionalization of Azabicycloalkanes," J. Am. Chem. Soc. 2018, 140, 5599–5606.

  8. 122

  9. Makaravage, K. J.; Shao, X.; Brooks, A. F.; Yang, L.; Sanford, M. S.; Scott, P. J. H. "Copper(II)-Mediated [11C]Cyanation of Arylboronic Acids and Arylstannanes," Org. Lett. 2018, 20, 1530–1533.

  10. 122

  11. Hendricks, K. H.; Robinson, S. G.; Braten, M. N.; Sevov, C. S.; Helms, B. A.; Sigman, M. S.; Minteer, S. D.; Sanford, M. S. "High-Performance Oligomeric Catholytes for Effective Macromolecular Separation in Nonaqueous Redox Flow Batteries," ACS Cent. Sci. 2018, 4, 189–196.

  12. 122

  13. James, B. R.; Boissonnault, J. A.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. "Structure activity relationships in metal–organic framework catalysts for the continuous flow synthesis of propylene carbonate from CO2 and propylene oxide," RSC Adv. 2018, 8, 2132–2137.

  14. 122

  15. Mossine, A. V.; Brooks, A. F.; Bernard-Gauthier, V.; Bailey, J. J.; Ichiishi, N.; Schirrmacher, R.; Sanford, M. S.; Scott, P. J. H. "Automated Synthesis of PET Radiotracers by Copper-mediated 18F-Fluorination of Organoborons: Importance of the Order of Addition and Competing Protodeborylation," J. Label. Compd. Radiopharm. 2017, 1–9.

  16. Shrestha, A.; Lee, M.; Dunn, A. L.; Sanford, M. S. "Palladium-Catalyzed C–H Bond Acetoxylation via Electrochemical Oxidation," Org. Lett. 2017, 20, 204–207.

  17. 122

  18. Ichiishi, N.; Malapit, C. A.; Wozniak, L.; Sanford, M. S. "Palladium- and Nickel-Catalyzed Decarbonylative C–S Coupling to Convert Thioesters to Thioethers," Org. Lett. 2017, 20, 44–47.

  19. 122

  20. Sevov, C. S.; Hendriks, K. H.; Sanford, M. S. "Low-Potential Pyridinium Anolyte for Aqueous Redox Flow Batteries," J. Phys. Chem. C 2017, 121, 24376–24380.

  21. 122

  22. Camasso, N. M.; Canty, A. J.; Ariafard, A.; Sanford, M. S. "Experimental and Computational Studies of High-Valent Nickel and Palladium Complexes," Organometallics 2017, 36, 4382–4393.

  23. 122

  24. Hendriks, K. H.; Sevov, C. S.; Cook, M. E.; Sanford, M. S. "Multielectron Cycling of a Low-Potential Anolyte in Alkali Metal Electrolytes for Nonaqueous Redox Flow Batteries," ACS Energy Lett. 2017, 2, 2430–2435.

  25. 122

  26. Ferguson, D. M. Bour, J. R.; Canty, A. J.; Kampf, J. W.; Sanford, M. S. "Stoichiometric and Catalytic Aryl–Perfluoroalkyl Coupling at Tri-tert-butylphosphine Palladium(II) Complexes," J. Am. Chem. Soc. 2017, 139, 11662–11665.

  27. 122

  28. Malapit, C. A.; Ichiishi, N.; Sanford, M. S. "Pd-Catalyzed Decarbonylative Cross-Couplings of Aroyl Chlorides," Org. Lett. 2017, 19, 4142–4145.

  29. 122

  30. McCammant, M. S.; Thompson, S.; Brookes, A. F.; Krska, S. W.; Scott, P. J. H.; Sanford, M. S. "Cu-Mediated C–H 18F-Fluorination of Electron-Rich (Hetero)arenes," Org. Lett. 2017, 19, 3939–3942.

  31. 122

  32. Cismesia, M. A.; Ryan, S. J.; Bland, D. C.; Sanford, M. S. "Multiple Approaches to the In Situ Generation of Anhydrous Tetraalkylammonium Fluoride Salts for SNAr Fluorination Reactions," J. Org. Chem. 2017, 82, 5020–5026.

  33. 122

  34. Chong, E.; Kampf, J. W.; Ariafard, A.; Canty, A. J.; Sanford, M. S. "Oxidatively Induced C–H Activation at High Valent Nickel," J. Am. Chem. Soc. 2017, 139, 6058–6061.

  35. 122

  36. Bour, J. R.; Kariofillis, S. K.; Sanford, M. S. "Synthesis, Reactivity, and Catalytic Applications of Isolable (NHC)Cu(CHF2) Complexes," Organometallics 2017, 36, 1220–1223.

  37. 122

  38. Mossine, A. V.; Brooks, A. F.; Ichiishi, N.; Makaravage, K. J.; Sanford, M. S.; Scott, P. J. H. "Development of Customized [18F]Fluoride Elution Techniques for the Enhancement of Copper-Mediated Late-Stage Radiofluorination," Scientific Reports 2017, 7, 233.

  39. Canty, A. J.; Ariafard, A.; Camasso, N. M.; Higgs, A. T.; Yates, B. F.; Sanford, M. S. "Computational study of C(sp3)–O bond formation at a PdIV centre," Dalton Trans. 2017, 46, 3742–3748.

  40. 122

  41. Sevov, C. S.; Hickey, D. P.; Cook, M. E.; Robinson, S. G.; Barnett, S.; Minteer, S. D.; Sigman, M. S.; Sanford, M. S. "Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications," J. Am. Chem. Soc. 2017, 139, 2924–2927.

  42. 122

  43. Schimler, S. D.; Cismesia, M. A.; Hanley, P. S.; Froese, R. D. J.; Jansma, M. J.; Bland, D. C.; Sanford, M. S. "Nucleophilic Deoxyfluorination of Phenols via Aryl Fluorosulfonate Intermediates," J. Am. Chem. Soc. 2017, 139, 1452–1455.

  44. 122

  45. Lee, M.; Sanford, M. S. "Remote C(sp3)–H Oxygenation of Protonated Aliphatic Amines with Potassium Persulfate," Org. Lett. 2017, 19, 572–575.

  46. 122

  47. Lotz, M. D.; Camasso, N. M.; Canty, A. J.; Sanford, M. S. "Role of Silver Salts in Palladium-Catalyzed Arene and Heteroarene C–H Functionalization Reactions," Organometallics 2017, 36, 165–171.

  48. 122

  49. Meucci, E. A.; Camasso, N. M.; Sanford, M. S. "An Organometallic NiIV Complex That Participates in Competing Transmetalation and C(sp2)–O Bond-Forming Reductive Elimination," Organometallics 2017, 36, 247–250.

  50. 122

  51. Bour, J. R.; Camasso, N. M.; Meucci, E. A.; Kampf, J. W.; Canty, A. J.; Sanford, M. S. "Carbon–Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) Complexes," J. Am. Chem. Soc. 2016, 138, 16105–16111.

  52. 122

  53. Sevov, C. S.; Samaroo, S. K.; Sanford, M. S. "Cyclopropenium Salts as Cyclable, High-Potential Catholytes in Nonaqueous Media," Adv. Energy Mater. 2016, 1602027.

  54. 122

  55. Sevov, C. S.; Fisher, S. L.; Thompson, L. T.; Sanford, M. S. "Mechanism-Based Development of a Low-Potential, Soluble, and Cyclable Multielectron Anolyte for Nonaqueous Redox Flow Batteries," J. Am. Chem. Soc. 2016, 138, 15378–15384.

  56. 122

  57. Makaravage, K. J.; Brooks, A. F.; Mossine, A. V.; Sanford, M. S.; Scott, P. J. H. "Copper-Mediated Radiofluorination of Arylstannanes with [18F]KF," Org. Lett. 2016, 18, 5440–5443.

  58. 122

  59. Schimler, S. D.; Sanford, M. S. "Copper-Mediated Functionalization of Aryl Trifluoroborates," Synlett. 2016, 27, 2279–2284.

  60. Rezayee, N. M.; Samblanet, D. C.; Sanford, M. S. "Iron-Catalyzed Hydrogenation of Amides to Alcohols and Amines," ACS Catal. 2016, 6, 6377–6383.

  61. 122

  62. Mbofana, C. T.; Chong, E.; Lawniczak, J.; Sanford, M. S. "Iron-Catalyzed Oxyfunctionalization of Aliphatic Amines at Remote Benzylic C–H Sites," Org. Lett. 2016, 18, 4258–4261.

  63. 122

  64. Pendleton, I. M.; Pérez-Temprano, M. H.; Sanford, M. S.; Zimmerman, P. M. "Experimental and Computational Assessment of Reactivity and Mechanism in C(sp3)–N Bond-Forming Reductive Elimination from PdIV," J. Am. Chem. Soc. 2016, 138, 6049–6060.

  65. 122

  66. Genna, D. T.; Pfund, L. Y.; Samblanet, D. C.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. "Rhodium Hydrogenation Catalysts Supported in Metal Organic Frameworks: Influence of the Framework on Catalytic Activity and Selectivity," ACS Catal. 2016, 6, 3569–3574.

  67. 122

  68. Brewster, T. P.; Rezayee, N. M.; Culakova, Z.; Sanford, M. S.; Goldberg, K. I. "Base-Free Iridium-Catalyzed Hydrogenation of Esters and Lactones," ACS Catal. 2016, 6, 3113–3117.

  69. 113

  70. Cook, A. K.; Schimler, S. D.; Matzger, A. J.; Sanford, M. S. "Catalyst-Controlled Selectivity in the C–H Borylation of Methane and Ethane," Science 2016, 351, 1421–1424.

  71. 113

  72. Sanford, M. S.; Scott, P. J. H. "Moving Metal-Mediated 18F‐Fluorination from Concept to Clinic," ACS Cent. Sci. 2016, 2, 128–130.

  73. Topczewski, J. T.; Cabrera, P. J.; Saper, N. I.; Sanford, M. S. "Palladium-Catalysed Transannular C–H Functionalization of Alicyclic Amines," Nature 2016, 531, 220–224.

  74. 122
  75. Schimler, S. D.; Ryan, S. J.; Bland, D. C.; Anderson, J. E.; Sanford, M. S. "Anhydrous Tetramethylammonium Fluoride for Room-Temperature SNAr Fluorination," J. Org. Chem. 2015, 80, 12137–12145.

  76. 120

  77. Mossine, A. V.; Brooks, A. F.; Makaravage, K. J.; Miller, J. M.; Ichiishi, N.; Sanford, M. S.; Scott, P. J. H. "Synthesis of [18F]Arenes via the Copper-Mediated [18F]Fluorination of Boronic Acids," Org. Lett. 2015, 17, 5780–5783.

  78. 119

  79. Sevov, C. S.; Brooner, R. E. M.; Chénard, E.; Assary, R. S.; Moore, J. S.; Rodríguez-López, J.; Sanford, M. S. "Evolutionary Design of Low Molecular Weight Organic Anolyte Materials for Applications in Nonaqueous Redox Flow Batteries," J. Am. Chem. Soc. 2015, 137, 14465–14472.

  80. 118

  81. Cabrera, P. J.; Yang, X.; Suttil, J. A.; Brooner, R. E. M.; Thompson, L. T.; Sanford, M. S. "Evaluation of Tris-Bipyridine Chromium Complexes for Flow Battery Applications: Impact of Bipyridine Ligand Structure on Solubility and Electrochemistry," Inorg. Chem. 2015, 54, 10214–10223.

  82. 117

  83. Cook, A.; Sanford, M. S. "C–Hal Bond Formation by Arene C–H Activation," In Catalytic Transformations via C-H Activation, Vol. 2; Science of Synthesis, Yu, J.-Q., 2015, 183–219.

  84. Lee, M.; Sanford, M. S. "Platinum-Catalyzed, Terminal-Selective C(sp3)–H Oxidation of Aliphatic Amines," J. Am. Chem. Soc. 2015, 137, 12796–12799.

  85. 115

  86. Bour, J. R.; Camasso, N. M.; Sanford, M. S. "Oxidation of NiII to NiIV with Aryl Electrophiles Enables Ni-Mediated Aryl–CF3 Coupling," J. Am. Chem. Soc. 2015, 137, 8034–8037.

  87. 114

  88. Cabrera, P. J.; Yang, X.; Suttil, J. A.; Hawthorne, K. L. Brooner, R. E. M.; Sanford, M. S.; Thompson, L. T. "Complexes Containing Redox Noninnocent Ligands for Symmetric, Multielectron Transfer Nonaqueous Redox Flow Batteries, " J. Phys. Chem. C 2015, 119, 15882–15889.

  89. 113

  90. Ryan, S. J.; Schimler, S. D.; Bland, D. C.; Sanford, M. S. "Acyl Azolium Fluorides for Room Temperature Nucleophilic Aromatic Fluorination of Chloro- and Nitroarenes," Org. Lett. 2015, 17, 1866–1869.

  91. 113

  92. Suttil, J. A.; Kucharyson, J. F.; Escalante-Garcia, I. L.; Cabrera, P. J.; James, B. R.; Savinell, R. F.; Sanford, M. S.; Thompson, L. T. "Metal Acetylacetonate Complexes for High Energy Density Non-Aqueous Redox Flow Batteries," J. Mater. Chem. A 2015, 3, 7929–7938.

  93. 113

  94. Canty, A. J.; Ariafard, A.; Yates, B. F.; Sanford, M. S. "Computational Study of Intramolecular Arene Palladation at a Palladium(IV) Center," Organometallics 2015, 34, 1085–1090.

  95. 113

  96. Cook, A. K.; Sanford, M. S. "Mechanism of the Palladium-Catalyzed Arene C–H Acetoxylation: A Comparison of Catalysis and Ligand Effects," J. Am. Chem. Soc. 2015, 137, 3109–3118.

  97. 113

  98. Camasso, N. M.; Sanford, M. S. "Design, Synthesis, and Carbon-Heteroatom Coupling Reactions of Organometallic Nickel (IV) Complexes," Science 2015, 347, 1218–1220.

  99. 113

  100. Rezayee, N. M.; Huff, C. A.; Sanford, M. S. "Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol," J. Am. Chem. Soc. 2015, 137, 1028–1031.

  101. 113

  102. Topczewski, J. J.; Sanford, M. S. "Carbon–Hydrogen (C–H) Bond Activation at PdIV: A Frontier in C–H Functionalization Catalysis," Chem. Sci. 2014, 6, 70–76.

  103. 113

  104. Ichiishi, N.; Canty, A. J.; Yates, B. F.; Sanford, M. S. "Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the CuI/CuIII Manifold in Copper Catalysis," Organometallics 2014, 33, 5525–5534.

  105. 113

  106. Brooks, A. F.; Topczewski, J. J.; Ichiishi, N.; Sanford, M. S.; Scott, P. J. H. "Late-Stage [18F]Fluorination: New Solutions to Old Problems," Chem. Sci. 2014, 5, 4545–4553.

  107. 113

  108. Camasso, N. M.; Pérez-Temprano, M. H.; Sanford, M. S. "C(sp3)–O Bond-Forming Reductive Elimination from PdIV with Diverse Oxygen Nucleophiles," J. Am. Chem. Soc. 2014, 136, 12771–12775.

  109. 113

  110. Allen, L. J.; Lee, S. H.; Cheng, Y.; Hanley, P. S.; Muhuhi, J. M.; Kane, E.; Powers, S. L.; Anderson, J. E.; Bell, B. M.; Roth, G. A.; Sanford, M. S.; Bland, D. C. "Developing Efficient Nucleophilic Fluorination Methods and Application to Substituted Picolinate Esters," Org. Process Res. Dev. 2014, 18, 1045–1054.

  111. 113

  112. Maleckis, A.; Sanford, M. S. "Synthesis of Fluoroalkyl Palladium and Nickel Complexes via Decarbonylation of Acylmetal Species" Organometallics 2014, 33, 3831–3839.

  113. 113

  114. Ichiishi, N.; Brooks, A. F.; Topczewski, J. J.; Rodnick, M. E.; Sanford, M. S.; Scott, P. J. H. "Copper-Catalyzed [18F]Fluorination of (Mesityl)(aryl)iodonium Salts," Org. Lett. 2014, 16, 3224–3227.

  115. 113

  116. Lotz, M. D.; Remy, M. S.; Lao, D. B.; Ariafard, A.; Yates, B. F.; Canty, A. J.; Mayer, J. M.; Sanford, M. S. "Formation of Ethane from Mono-Methyl PalladiumII Complexes," J. Am. Chem. Soc. 2014, 136, 8237–8242.

  117. 113

  118. Allen, L. J.; Muhuhi, J. M.; Bland, D. C.; Merzel, R.; Sanford, M. S. "Mild Fluorination of Chloropyridines with In Situ Generated Anhydrous Tetrabutylammonium Fluoride," J. Org. Chem. 2014, 79, 5827–5833.

  119. 113

  120. Maleckis, A.; Sanford, M. S. "Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source," Organometallics 2014, 33, 2653–2660.

  121. 113

  122. Allen, L. J.; Cabrera, P. J.; Lee, M.; Sanford, M. S. "N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes," J. Am. Chem. Soc. 2014, 136, 5607–5610.

  123. 113

  124. Pérez-Temprano, M. H.; Racowski, J. M.; Kampf, J. W.; Sanford, M. S. "Competition Between sp 3-C–N vs sp 3-C–F Reductive Elimination from PdIV Complexes," J. Am. Chem. Soc. 2014, 136, 4097–4100.

  125. 113

  126. Wagner, A. M.; Sanford, M. S. "Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers," J. Org. Chem. 2014, 79, 2263–2267.

  127. 113

  128. Ye, Y.; Schimler, S. D.; Hanley, P. S.; Sanford, M. S. " Cu(OTf)2-Mediated Fluorination of Aryltrifluoroborates with Potassium Fluoride, " J. Am. Chem. Soc. 2013, 135, 16292–16295.

  129. 113

  130. Wagner, A. M. ; Hickman, A. J. ; Sanford, M. S. "Platinum-Catalyzed C–H Arylation of Simple Arenes," J. Am. Chem. Soc. 2013, 135, 15710–15713.

  131. 113

  132. Cook, A. K.; Emmert, M. H.; Sanford, M. S. "Steric Control of Site Selectivity in the Pd-Catalyzed C–H Acetoxylation of Simple Arenes," Org. Lett. 2013, 15, 5428–5431.

  133. 113

  134. Lehman, M. C.; Gary, J. B.; Boyle, P. D.; Sanford, M. S.; Ison, E. A. "Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*IrIII(L) Complexes," ACS Catalysis. 2013, 3, 2304–2310.

  135. 113

  136. Huff, C. A.; Sanford, M. S. "Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex," ACS Catalysis. 2013, 3, 2412–2416.

  137. 113

  138. Ichiishi, N.; Canty, A. J.; Yates, B. F.; Sanford, M. S. "Cu-Catalyzed Fluorination of Diaryliodonium Salts With KF," Org. Lett. 2013, 15, 5134–5137.

  139. 113

  140. Genna, D. T.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. "Heterogenization of Homogeneous Catalysts in Metal–Organic Frameworks Via Cation Exchange," J. Am. Chem. Soc. 2013, 135, 10586–10589.

  141. 113

  142. Huff, C. A.; Kampf, J. W.; Sanford, M. S. "Reversible Carbon-Carbon Bond Formation Between Carbonyl Compounds and a Ruthenium Pincer Complex," Chem. Commun. 2013, 49, 7147–7149.

  143. 113

  144. Sanhueza, I. A.; Wagner, A. M.; Sanford, M. S.; Schoenebeck, F. "On the Role of Anionic Ligands in the Site-Selectivity of Oxidative C–H Functionalization Reactions of Arenes." Chem. Sci. 2013, 4, 2767–2775.

  145. 113

  146. Gary, J. B.; Cook, A. K.; Sanford, M. S. "Palladium Catalysts Containing Pyridinium-Substituted Pyridine Ligands for the C–H Oxygenation of Benzene with K2S2O8," ACS Catalysis. 2013, 3, 700–703.

  147. 113

  148. Seigerman, C. K.; Micyus, T. M.; Neufeldt, S. R.; Sanford, M. S. "Palladium-Catalyzed C–H Arylation Using Aryltrifluoroborates in Conjunction with a MnIII Oxidant under Mild Conditions," Tetrahedron. 2013, 69, 5580–5587.

  149. 113

  150. Maleckis, A.; Kampf, J. W.; Sanford, M. S. "A Detailed Study of Acetate-Assisted C–H Activation at Palladium (IV) Centers," J. Am. Chem. Soc. 2013, 135, 6618–6625.

  151. 113

  152. Neufeldt, S. R.; Seigerman, C. K.; Sanford, M. S. "Mild Palladium-Catalyzed C–H Alkylation Using Potassium Alkyltrifluoroborates in Combination with MnF3," Org. Lett. 2013, 15, 2302–2305.

  153. 113

  154. Ye, Y.; Sanford, M. S. "Mild Copper-Mediated Fluorination of Aryl Stannanes and Aryl Trifluoroborates," J. Am. Chem. Soc. 2013, 135, 4648–4651.

  155. 113

  156. Canty, A. J.; Ariafard, A.; Sanford, M. S.; Yates, B. F. "Mechanism of Pd-Catalyzed Ar-Ar Bond Formation Involving Ligand-Directed C-H Arylation and Diaryliodonium Oxidants: Computational Studies of Orthopalladation at Binuclear PdII Centers, Oxidation To Form Binuclear Palladium (III) Species, and Ar···Ar Reductive Coupling, " Organometallics 2013, 32, 544–555.

  157. 113

  158. Neufeldt, S. R.; Sanford, M. S. "Asymmetric Chiral Ligand-Directed Alkene Dioxygenation," Org. Lett. 2013, 15, 46≠49.

  159. 113

  160. McMurtrey, K. B.; Sanford, M. S. "C–F Bond-Forming Reactions," In Cross-Coupling and Heck-Type Reactions from the Science of Synthesis Reference Library. Vol. 2, John P. Wolfe, Ed., Thieme, 2012.

  161. Neufeldt, S. R.; Sanford, M. S. "Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed C–H Arylation with Diaryliodonium Salts," Adv. Synth. Catal. 2012, 354, 3517–3522.

  162. Ye,Y.; Kuenzi, S. A.; Sanford, M. S. "Practical Method for the Cu-Mediated Trifluoromethylation of Arylboronic Acids with CF3 Radicals Derived from NaSO2CF3 and tert-Butyl Hydroperoxide (TBHP)," Org. Lett. 2012, 14, 4979–4981.

  163. 113

  164. Stowers, K. J.; Kubota, A.; Sanford, M. S. "Nitrate as a Redox Co-Catalyst for the Aerobic Pd-Catalyzed Oxidation of Unactivated sp3-C–H Bonds," Chem. Sci. 2012, 3, 3192–3195.

  165. 113

  166. McMurtrey, K. B.; Racowski, J. M.; Sanford, M. S. "Pd-Catalyzed C-H Fluorination with Nucleophilic Fluoride," Org. Lett. 2012, 14, 4094–4097.

  167. 113

  168. Powers, D. C.; Lee, E.; Ariafard, A.; Sanford, M. S.; Yates, B. F.; Canty, A. J.; Ritter, T. "Connecting Binuclear PdIII and Mononuclear PdIV Chemistry by Pd-Pd Bond Cleavage," J. Am. Chem. Soc. 2012, 134, 12002–12009.

  169. 113

  170. Ye, Y.; Sanford, M. S. "Investigations into Transition-Metal-Catalyzed Arene Trifluoromethylation Reactions," Synlett. 2012, 23, 2005–2013.

  171. Gary, J. B; Carter, T. J.; Sanford, M. S. "RhIII Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange," Top. Catal. 2012, 55, 565–570.

  172. Huff, C. A.; Kampf, J. W.; Sanford, M. S. "Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO)," Organometallics 2012, 31, 4643–4635.

  173. 113

  174. Hickman, A. J.; Sanford, M. S. "High-Valent Organometallic Copper and Palladium in Catalysis," Nature 2012, 484, 177–185.

  175. Ye, Y.; Sanford, M. S. "Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I," J. Am. Chem. Soc. 2012, 134, 9034–9037.

  176. 113

  177. Neufeldt, S. R.; Sanford, M. S. "Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization" Acc. Chem. Res. 2012, 45, 936–946.

  178. 113

  179. Kubota, A.; Emmert, M. H.; Sanford, M. S. "Pyridine Ligands as Promoters in PdII/0-Catalyzed C–H Olefination Reactions" Org. Lett. 2012, 14, 1760–1763.

  180. 113

  181. Hickman, A. J.; Cismesia, M. A.; Sanford, M. S. "Structure-Activity Relationship Study of Diimine PtII Catalysts for H/D Exchange" Organometallics 2012, 31, 1761–1766.

  182. 113

  183. Racowski, J. M.; Gary, B. G.; Sanford, M. S. "Carbon(sp3)–Fluorine Bond-Forming Reductive Elimination from Palladium (IV)" Angew. Chem. Int. Ed 2012, 51, 3414–3417

  184. 113

  185. Park, T.-H.; Hickman, A. J.; Koh, K.; Martin, S.; Wong-Foy, A. G.; Sanford, M. S.; Matzger, A. J. "Highly Dispersed Palladium (II) in a Defective MOF: Application to C–H Activation and Functionalization," J. Am. Chem. Soc. 2011, 133, 20138–20141.

  186. 113

  187. Maleckis, A; Sanford, M. S. "Facial Tridentate Ligands for Stabilizing Palladium (IV) Complexes," Organometallics 2011, 30, 6617–6627.

  188. 113

  189. Kalyani, D.; McMurtrey, K. B.; Neufeldt, S. R.; Sanford, M. S. "Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis," J. Am. Chem. Soc. 2011, 133, 18566–18569.

  190. 113

  191. Huff, C. A.; Sanford, M. S. "Cascade Catalysis for the Homogeneous Hydrogenation of CO2 to Methanol," J. Am. Chem. Soc. 2011, 133, 18122–18125.

  192. 113

  193. Gary, J. B.; Sanford, M. S. "Participation of Carbonyl Oxygen in Carbon-Carboxylate Bond-Forming Reductive Elimination from Palladium," Organometallics 2011, 30, 6143–6149.

  194. 113

  195. Racowski, J. M.; Ball, N. D.; Sanford, M. S. "C–H Bond Activation at Palladium (IV) Centers," J. Am. Chem. Soc. 2011, 133, 18022–18025.

  196. 113

  197. Ye, Y.; Lee, S.; Sanford, M. S. "Silver-Mediated Trifluoromethylation of Arenes Using TMSCF3," Org. Lett. 2011, 13, 5464–5467.

  198. 113

  199. Emmert, M. H.; Cook, A. K.; Xie, Y. J.; Sanford, M. S. "Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected C–H Oxygenation of Arenes," Angew. Chem. Int. Ed. 2011, 50, 9409–9412.

  200. 113

  201. Lanci, M. P.; Remy, M. S.; Lao, D. B.; Sanford, M. S.; Mayer, J. M. "Modulating Sterics in Trimethylplatinum (IV) Diimine Complexes to Achieve C–C Bond-Forming Reductive Elimination," Organometallics 2011, 30, 3704–3707.

  202. 113

  203. Kubota, A; Sanford, M. S. "Palladium-Catalyzed Ligand-Directed Oxidative Functionalization of Cyclopropanes," Synthesis 2011, 16, 2579–2589.

  204. Loy, R. N.; Sanford, M. S. "Palladium-Catalyzed C–H Perfluoroalkylation of Arenes," Org. Lett. 2011, 13, 2548–2551.

  205. 113

  206. Ball, N. D.; Gary, J. B.; Ye, Y.; Sanford, M. S. "Mechanistic and Computational Studies of Oxidatively-Induced Aryl–CF3 Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation," J. Am. Chem. Soc. 2011, 133, 7577–7584.

  207. 113

  208. Stowers, K. J.; Fortner, K. C.; Sanford, M. S. "Aerobic Pd-Catalyzed sp3 C–H Olefination: A Route to Both N-Heterocyclic Scaffolds and Alkenes," J. Am. Chem. Soc. 2011, 133, 6541–6544.

  209. 113

  210. Racowski, J.; Sanford, M. S. "Carbon-Heteroatom Bond Forming Reductive Elimination from Palladium (IV) Complexes," In Topics in Organometallic Chemistry, Vol. 53, Allan Canty, Ed., Springer, 2011, 61-84.

  211. Satterfield, A. D.; Kubota, A.; Sanford, M. S. "Palladium-Catalyzed 1,1-Aryloxygenation of Terminal Olefins," Org. Lett. 2011, 13, 1076–1079.

  212. 113

  213. Lyons, T. W.; Hull, K. L.; Sanford M. S. "Controlling Site Selectivity in Palladium-Catalyzed C–H Oxidative Cross-Coupling," J. Am. Chem. Soc. 2011, 133, 4455–4464.

  214. 113

  215. Hickman, A. J.; Sanford, M. S. "Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene," ACS Catal. 2011, 1, 170–174.

  216. 113

  217. Wagner, A. M.; Sanford, M. S. "Palladium-Catalyzed C–H Arylation of 2,5-Disubstituted Pyrroles," Org. Lett. 2011, 13, 288–291.

  218. 113

  219. Ye, Y.; Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Oxidation of Catalytically Relevant Palladium Dimer with "CF3+": Formation and Reactivity of a Monomeric Palladium (IV) Aquo Product," J. Am. Chem. Soc. 2010, 132, 14682–14687.

  220. 113

  221. Higgs, A. T.; Zinn, P. J.; Sanford, M. S. "Synthesis and Reactivity of (Phpy)2Ni (Phpy = 2-Phenylpyridine)," Organometallics 2010, 29, 5446–5449.

  222. 113

  223. Emmert, M. H.; Villalobos, J. M.; Gary, J. B.; Sanford, M. S. "Pt and Pd Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation," Angew. Chem. Int. Ed. 2010, 49, 5884–5886.

  224. 113

  225. Kalyani, D.; Satterfield, A. D.; Sanford, M. S. "Palladium-Catalyzed Oxidative Arylhalogenation of Alkenes: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2010, 132, 8419–8427.

  226. 113

  227. Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Aryl-CF3 Bond-Forming Reductive Elimination from Palladium (IV)," J. Am. Chem. Soc. 2010, 132, 2878–2879.

  228. 113

  229. Remy, M. S.; Cundari, T.; Sanford, M. S. "Computational and Experimental Studies of Methyl Group Exchange Between Group 10 Metal Centers," Organometallics 2010, 29, 1522–1525.

  230. 113

  231. Neufeldt, S. R.; Sanford, M. S. "O-Acetyl Oximes as Transformable Directing Groups for Pd-Catalyzed C–H Functionalization," Org. Lett. 2010, 12, 532–535.

  232. 113

  233. Villalobos, J. M.; Hickman, A. J.; Sanford, M. S. "Platinum (II) Complexes Containing Quaternized Nitrogen Ligands: Synthesis, Stability, and Evaluation as Catalysts for Methane and Benzene H/D Exchange," Organometallics 2010, 29, 257–262.

  234. 113

  235. Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Synthesis and Reactivity of Palladium (II) Fluoride Complexes Containing Nitrogen Donor Ligands," Dalton Trans. 2010, 39, 632–640.

  236. 113

  237. Lyons, T. W.; Sanford, M. S. "Palladium-Catalyzed Ligand-Directed C–H Functionalization Reactions," Chem. Rev. 2010, 110, 1147–1169.

  238. Higgs, A. T.; Zinn, P. J.; Simmons, S. J.; Sanford, M. S. "Oxidatively Induced Carbon-Halogen Bond-Forming Reactions at Nickel," Organometallics 2009, 28, 6142–6144.

  239. 113

  240. Lanci, M. P.; Remy, M. S.; Kaminsky, W.; Mayer, J. M.; Sanford, M. S. "Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium (IV) Intermediates in a One Electron Oxidation Reaction," J. Am. Chem. Soc. 2009, 131, 15618–15620.

  241. 113

  242. Stowers, K. J.; Sanford, M. S. "Mechanistic Comparison Between Palladium-Catalyzed C–H Acetoxylation and C–H Chlorination," Org. Lett. 2009, 11, 4584–4587.

  243. 113

  244. Arnold, P. L.; Sanford, M. S.; Pearson, S. M. "Chelating N-Heterocyclic Carbene-Alkoxide as a Supporting Ligand for PdII/IV C–H Bond Functionalization Catalysis," J. Am. Chem. Soc. 2009, 131, 13912–13913.

  245. 113

  246. Hickman, A. J.; Villalobos, J. M.; Sanford, M. S. "A Quantitative Method to Assay Platinum Catalysts for Benzene H/D Exchange," Organometallics 2009, 28, 5316–5322.

  247. 113

  248. Deprez, N. R.; Sanford, M. S. "Synthetic and Mechanistic Studies of Pd-Catalyzed C–H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate," J. Am. Chem. Soc. 2009, 131, 11234–11241.

  249. 113

  250. Racowski, J. M.; Dick, A. R.; Sanford, M. S. "Detailed Study of C–O and C–C Bond-Forming Reductive Elimination from Stable C2N2O2 Palladium (IV) Complexes," J. Am. Chem. Soc. 2009, 131, 10974–10983.

  251. 113

  252. Hull, K. L.; Sanford, M. S. "Mechanism of Benzoquinone-Promoted Palladium-Catalyzed Oxidative Cross Coupling Reactions," J. Am. Chem. Soc. 2009, 131, 9651–9653.

  253. 113

  254. Ball, N. D.; Sanford, M. S. "Synthesis and Reactivity of a Mono-σ-Aryl Palladium (IV) Fluoride Complex," J. Am. Chem. Soc. 2009, 131, 3796–3797.

  255. 113

  256. Lyons, T. W.; Sanford, M. S. "PdII/IV-Catalyzed Cyclopropanation Reactions: Scope and Mechanism," Tetrahedron 2009, 65, 3211–3221.

  257. 113

  258. Desai, L. V.; Stowers, K. J.; Sanford, M. S. "Insights into Directing Group Ability in Palladium-Catalyzed C–H Bond Functionalization," J. Am. Chem. Soc. 2008, 130, 13285–13293.

  259. 113

  260. Whitfield, S. R.; Sanford, M. S. "Reactions of Platinum (II) Complexes with Chloride-Based Oxidants: Routes to PtIV and PtIII Products," Organometallics 2008, 27, 1683–1689.

  261. 113

  262. Kalyani, D.; Sanford, M. S. "Oxidatively Intercepting Heck Intermediates: Pd-Catalyzed 1,2- and 1,1-Arylhalogenation of Alkenes," J. Am. Chem. Soc. 2008, 130, 2150–2151.

  263. 113

  264. Whitfield, S. L.; Sanford, M. S. "Reactivity of PdII Complexes with Electrophilic Chlorinating Reagents: Isolation of PdIV Intermediates and Observation of C–Cl Bond-Forming Reductive Elimination," J. Am. Chem. Soc. 2007, 129, 15142–15143.

  265. 113

  266. Hull, K. L.; Sanford, M. S. "Catalytic and Highly Regioselective Cross-Coupling of Aromatic C–H Substrates," J. Am. Chem. Soc. 2007, 129, 11904–11905.

  267. 113

  268. Deprez, N. R.; Sanford, M. S. "Reactions of Hypervalent Iodine Reagents with Palladium: Mechanisms and Applications in Organic Synthesis," Inorg. Chem. 2007, 46, 1924–1935.

  269. 113

  270. Desai, L. V.; Sanford, M. S. "Construction of Tetrahydrofurans via PdII/IV-Catalyzed Aminooxygenation of Alkenes," Angew. Chem., Int. Ed. 2007, 46, 5737–5740.

  271. 113

  272. Welbes, L. L.; Lyons, T. W.; Cychosz, K. A.; Sanford, M. S. "Synthesis of Cyclopropanes via PdII/IV-Catalyzed Reactions of Enynes," J. Am. Chem. Soc. 2007, 129, 5836–5837.

  273. 113

  274. Dick, A. R.; Remy, M. S.; Kampf, J. W.; Sanford, M. S. "Carbon-Nitrogen Bond-Forming Reactions Between Palladacycles and Hypervalent Iodine Reagents," Organometallics 2007, 26, 1365–1370.

  275. 113

  276. Kalyani, D.; Sanford, M. S. "Chelate-Directed Oxidative Functionalization of Carbon-Hydrogen Bonds: Synthetic Applications and Mechanistic Insights," In Topics in Organometallic Chemistry, Vol. 24, Naoto Chatani, Ed., Springer, 2007, 85–116.

  277. Hull, K. L.; Lanni, E. L.; Sanford, M. S. "Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2006, 128, 14047-14049.

  278. 113

  279. Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. "Scope and Selectivity in Palladium-Catalyzed Directed C–H Bond Halogenation Reactions," Tetrahedron 2006, 62, 11483–11498.

  280. 113

  281. Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. "A Simple Catalytic Method for the Regioselective Halogenation of Arenes," Org. Lett. 2006, 8, 2523–2526.

  282. 113

  283. Hull, K. L.; Anani, W. Q.; Sanford, M. S. "Palladium-Catalyzed Fluorination of Carbon-Hydrogen Bonds," J. Am. Chem. Soc. 2006, 128, 7134–7135.

  284. 113

  285. Deprez, N. R.; Kalyani, D.; Krause, A.; Sanford, M. S. "Room Temperature Palladium-Catalyzed 2-Arylation of Indoles," J. Am. Chem. Soc. 2006, 128, 4972–4973.

  286. 113

  287. Desai, L. V.; Malik, H. A.; Sanford, M. S. "Oxone as an Inexpensive Safe and Environmentally Benign Oxidant for C–H Bond Oxygenation," Org. Lett. 2006, 8, 1141–1144.

  288. 113

  289. Kalberer, E. W.; Whitfield, S. R.; Sanford, M. S. "Application of Recyclable, Polymer-Immobilized IodineIII Oxidants in Catalytic C–H Bond Functionalization," J. Mol. Catal. A. 2006, 251, 108–113.

  290. 113

  291. Dick, A. R.; Sanford, M. S. "Transition Metal Catalyzed Catalyzed Oxidative Functionalization of Carbon-Hydrogen Bonds," Tetrahedron 200662, 2439–2463.

  292. 113

  293. Dick, A. R.; Kampf, J. W.; Sanford, M. S. "Unusually Stable Palladium (IV) Complexes: Detailed Mechanistic Investigation of C–O Bond-Forming Reductive Elimination," J. Am. Chem. Soc. 2005, 127, 12790–12791.

  294. 113

  295. Kalyani, D.; Sanford, M. S. "Regioselectivity in Palladium-Catalyzed C–H Activation/Oxygenation Reactions," Org. Lett. 2005, 7, 4149–4152.

  296. 113

  297. Kalyani, D.; Deprez, N. R.; Desai, L. V.; Sanford, M. S. "Oxidative C–H Activation/C–C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2005, 127, 7330–7331.

  298. 113

  299. Dick, A. R.; Kampf, J. W.; Sanford, M. S. "Platinum Model Studies for Palladium-Catalyzed Oxidative Functionalization of C–H Bonds," Organometallics 2005, 24, 482–485.

  300. 113

  301. Desai, L. V.; Hull , K. L.; Sanford, M. S. "Palladium-Catalyzed Oxygenation of Unactivated sp3 C–H Bonds," J. Am. Chem. Soc. 2004, 126, 9542–9543.

  302. 113

  303. Dick, A. R.; Hull, K. L.; Sanford, M. S. "A Highly Selective Catalytic Method for the Oxidative Functionalization of C–H Bonds," J. Am. Chem. Soc. 2004, 126, 2300–2301.

  304. 113