1. Scott, P.J.H; Sanford, M.S.; Ichiishi, N.; Brooks, A.F.; Rodnick, M.; Topczewski, J.T. "Copper Catalyzed [18F]Fluorination of Iodonium Salts, " U.S. Patent WO2015157597 A1, October 15, 2015.

  2. Schimler, S.D.; Ryan, S.J.; Bland, D.C; Anderson, J.E.; Sanford, M.S. "Anhydrous Tetramethylammonium Fluoride for Room-Temperature SNAr Fluorination, " J. Org. Chem. 2015, 80, 12137-12145.

  3. 120
  4. Mossine, A.V.; Brooks, A.F.; Makaravage, K.J.; Miller, J.M.; Ichiishi, N.; Sanford, M.S.; Scott, P.J.H. "Synthesis of [18F]Arenes via the Copper-Mediated [18F]Fluorination of Boronic Acids, " Org. Let. 2015, 17, 5780-5783.

  5. 119
  6. Sevov, C.S.; Brooner, R.E.M.; Chénard, E.; Assary, R.S.; Moore, J.S.; Rodríguez-López, J.; Sanford, M.S. "Evolutionary Design of Low Molecular Weight Organic Anolyte Materials for Applications in Nonaqueous Redox Flow Batteries, " J. Am. Chem. Soc. 2015, 137, 14465-14472.

  7. 118
  8. Cabrera, P.J.; Yang, X.; Suttil, J.A.; Brooner, R.E.M.; Thompson, L.T.; Sanford, M.S. "Evaluation of Tris-Bipyridine Chromium Complexes for Flow Battery Applications: Impact of Bipyridine Ligand Structure on Solubility and Electrochemistry, " Inorg. Chem. 2015, 54, 10214-10223.

  9. 117
  10. Cook, A.; Sanford, M.S. "C-Hal Bond Formation by Arene C-H Activation," In Catalytic Transformations via C-H Activation, Vol. 2; Science of Synthesis, Yu, J.-Q., 2015, 183-219.

  11. Lee, M.; Sanford, M.S. "Platinum-Catalyzed, Terminal-Selective C(sp3)–H Oxidation of Aliphatic Amines, " J. Am. Chem. Soc. 2015, 137, 12796-12799.

  12. 115
  13. Bour, J. R.; Camasso, N.M.; Sanford, M.S."Oxidation of Ni(II) to Ni(IV) with Aryl Electrophiles Enables Ni-Mediated Aryl–CF3 Coupling, " J. Am. Chem. Soc. 2015, 137, 8034-8037.

  14. 114
  15. Cabrera, P. J.; Yang, X.; Suttil, J. A.; Hawthorne, K. L.' Brooner, R. E. M.; Sanford, M. S.; Thompson, L. T. "Complexes Containing Redox Noninnocent Ligands for Symmetric, Multielectron Transfer Nonaqueous Redox Flow Batteries, " J. Phys. Chem. C 2015, 119, 15882-15889.

  16. 113
  17. Ryan, S. J.; Schimler, S. D.; Bland, D. C.; Sanford, M. S."Acyl Azolium Fluorides for Room Temperature Nucleophilic Aromatic Fluorination of Chloro- and Nitroarenes, " Org. Lett. 2015, 17, 1866-1869.

  18. Suttil, J. A.; Kucharyson, J. F.; Escalante-Garcia, I. L.; Cabrera, P. J.; James, B. R.; Savinell, R. F.; Sanford, M. S.; Thompson, L. T. "Metal acetylacetonate complexes for high energy density non-aqueous redox flow batteries, " J. Mater. Chem. A 2015, 3, 7929-7938.

  19. Canty, A. J.; Ariafard, A.; Yates, B. F.; Sanford, M. S." Computational Study of Intramolecular Arene Palladation at a Palladium(IV) Center, " Organometallics, 2015, 34, 1085-1090.

  20. Cook, A. K.; Sanford, M. S." Mechanism of the Palladium-Catalyzed Arene C-H Acetoxylation: A Comparison of Catalysis and Ligand Effects, " J. Am. Chem. Soc. 2015, 137, 3109-3118.

  21. Camasso, N. M.; Sanford, M. S." Design, Synthesis, and Carbon-Heteroatom Coupling Reactions of Organometallic Nickel(IV) Complexes, " Science 2015, 347, 1218-1220.

  22. Rezayee, N. M.; Huff, C. A.; Sanford, M. S." Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol, " J. Am. Chem. Soc. 2015, 137, 1028-1031.

  23. Topczewski, J. J.; Sanford, M. S." Carbon–hydrogen (C–H) bond activation at PdIV: a Frontier in C–H functionalization catalysis, " Chem. Sci. 2014, 6, 70-76.

  24. Ichiishi, N.; Canty, A. J.; Yates, B. F.; Sanford, M. S." Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the CuI/CuIII Manifold in Copper Catalysis, " Organometallics. 2014, 33, 5525–5534.

  25. Brooks, A. F.; Topczewski, J. J.; Ichiishi, N.; Sanford, M. S.; Scott, P. J. H. " Late-Stage [18F]Fluorination: New Solutions to Old Problems, " Chem. Sci. 2014, 5, 4545-4553.

  26. Camasso, N. M.; Pérez-Temprano, M. H.; Sanford, M. S. " C(sp3)–O Bond-Forming Reductive Elimination from PdIV with Diverse Oxygen Nucleophiles, " J. Am. Chem. Soc. 2014, 136, 12771-12775.

  27. Allen, L. J.; Lee, S. H.; Cheng, Y.; Hanley, P. S.; Muhuhi, J. M.; Kane, E.; Powers, S. L.; Anderson, J. E.; Bell, B. M.; Roth, G. A.; Sanford, M. S.; Bland, D. C. " Developing Efficient Nucleophilic Fluorination Methods and Application to Substituted Picolinate Esters, " Org. Process Res. Dev. 2014, 18, 1045-1054.

  28. Maleckis, A.; Sanford, M. S. " Synthesis of Fluoroalkyl Palladium and Nickel Complexes via Decarbonylation of Acylmetal Species " Organometallics. 2014, 33, 3831-3839.

  29. Ichiishi, N.; Brooks, A. F.; Topczewski, J. J.; Rodnick, M. E.; Sanford, M. S.; Scott, P. J. H. " Copper-Catalyzed [18F]Fluorination of (Mesityl)(aryl)iodonium Salts," Org. Lett. 2014, 16, 3224–3227.

  30. Lotz, M. D.; Remy, M. S.; Lao, D. B.; Ariafard, A.; Yates, B. F.; Canty, A. J.; Mayer, J. M.; Sanford, M. S."Formation of Ethane from Mono-Methyl Palladium(II) Complexes, " J. Am. Chem. Soc. 2014, 136, 8237–8242.

  31. Allen, L. J.; Muhuhi, J. M.; Bland, D. C.; Merzel, R.; Sanford, M. S. "Mild Fluorination of Chloropyridines with in Situ Generated Anhydrous Tetrabutylammonium Fluoride, " J. Org. Chem. 2014, 79, 5827–5833.

  32. Maleckis, A.; Sanford, M. S. "Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source, " Organometallics 2014, 33, 2653-2660.

  33. Allen, L. J.; Cabrera, P. J.; Lee, M.; Sanford, M. S. "N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes, " J. Am. Chem. Soc. 2014, 136, 5607-5610.

  34. Pérez-Temprano, M. H.; Racowski, J. M.; Kampf, J. W.; Sanford, M. S. "Competition between sp 3-C–N vs sp 3-C–F Reductive Elimination from PdIV Complexes, " J. Am. Chem. Soc. 2014, 136, 4097–4100.

  35. Wagner, A. M.; Sanford, M. S. " Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers, " J. Org. Chem. 2014, 79, 2263-2267.

  36. Ye, Y.; Schimler, S. D.; Hanley, P. S.; Sanford, M. S. " Cu(OTf)2-Mediated Fluorination of Aryltrifluoroborates with Potassium Fluoride, " J. Am. Chem. Soc. 2013, 135, 16292-16295.

  37. Wagner, A. M. ; Hickman, A. J. ; Sanford, M. S. " Platinum-Catalyzed C–H Arylation of Simple Arenes, " J. Am. Chem. Soc. 2013, 135, 15710-15713.

  38. Cook, A. K.; Emmert, M. H.; Sanford, M. S. " Steric Control of Site Selectivity in the Pd-Catalyzed C–H Acetoxylation of Simple Arenes, " Org. Lett. 2013, 15, 5428-5431.

  39. Lehman, M. C.; Gary, J. B.; Boyle, P. D.; Sanford, M. S.; Ison, E. A. " Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*IrIII(L) Complexes, " ACS Catalysis. 2013, 3, 2304–2310.

  40. Huff, C. A.; Sanford, M. S. "Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex, " ACS Catalysis. 2013, 3, 2412-2416.

  41. Ichiishi, N.; Canty, A. J.; Yates, B. F.; Sanford, M. S. " Cu-Catalyzed Fluorination of Diaryliodonium Salts with KF, " Org. Lett. 2013, 15, 5134–5137.

  42. Genna, D. T.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. " Heterogenization of Homogeneous Catalysts in Metal–Organic Frameworks via Cation Exchange, " J. Am. Chem. Soc. 2013, 135, 10586–10589.

  43. Huff, C. A.; Kampf, J. W.; Sanford, M. S. " Reversible Carbon-Carbon Bond Formation Between Carbonyl Compounds and a Ruthenium Pincer Complex, " Chem. Commun. 2013, 49, 7147-7149.

  44. Sanhueza, I. A.; Wagner, A. M.; Sanford, M. S.; Schoenebeck, F. "On the role of anionic ligands in the site-selectivity of oxidative C–H functionalization reactions of arenes. " Chem. Sci. 2013, 4, 2767-2775.

  45. Gary, J. B.; Cook, A. K.; Sanford, M. S. " Palladium Catalysts Containing Pyridinium-Substituted Pyridine Ligands for the C–H Oxygenation of Benzene with K2S2O8, " ACS Catalysis. 2013, 3, 700-703.

  46. Seigerman, C. K.; Micyus, T. M.; Neufeldt, S. R.; Sanford, M. S. " Palladium-Catalyzed C–H Arylation Using Aryltrifluoroborates in Conjunction with a Mn(III) Oxidant under Mild Conditions, " Tetrahedron. 2013, 69, 5580-5587.

  47. Maleckis, A.; Kampf, J. W.; Sanford, M. S. " A Detailed Study of Acetate-Assisted C–H Activation at Palladium(IV) Centers," J. Am. Chem. Soc. 2013, 135, 6618-6625.

  48. Neufeldt, S. R.; Seigerman, C. K.; Sanford, M. S. " Mild Palladium-Catalyzed C–H Alkylation Using Potassium Alkyltrifluoroborates in Combination with MnF3," Org. Lett. 2013, 15, 2302-2305.

  49. Ye, Y.; Sanford, M. S."Mild Copper-Mediated Fluorination of Aryl Stannanes and Aryl Trifluoroborates, " J. Am. Chem. Soc., 2013, 135, 4648–4651.

  50. Canty, A. J.; Ariafard, A.; Sanford, M. S.; Yates, B. F. "Mechanism of Pd-Catalyzed Ar-Ar Bond Formation Involving Ligand-Directed C-H Arylation and Diaryliodonium Oxidants: Computational Studies of Orthopalladation at Binuclear Pd(II) Centers, Oxidation To Form Binuclear Palladium(III) Species, and Ar···Ar Reductive Coupling, " Organometallics, 2013, 32, 544-555.

  51. Neufeldt, S. R.; Sanford, M. S. "Asymmetric Chiral Ligand-Directed Alkene Dioxygenation, " Org. Lett. 2013, 15, 46-49.

  52. McMurtrey, K. B.; Sanford, M. S. "C-F Bond-Forming Reactions, "In Cross-Coupling and Heck-Type Reactions from the Science of Synthesis Reference Library. Vol. 2, John P. Wolfe, Ed., Thieme, 2012.

  53. Neufeldt, S. R.; Sanford, M. S. "Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed C–H Arylation with Diaryliodonium Salts, " Adv. Synth. Catal. 2012, 354, 3517-3522.

  54. Ye,Y.; Kuenzi, S. A.; Sanford, M. S. "Practical Method for the Cu-Mediated Trifluoromethylation of Arylboronic Acids with CF3 Radicals Derived from NaSO2CF3 and tert-Butyl Hydroperoxide (TBHP)," Org. Lett. 2012, 14, 4979-4981.

  55. Stowers, K. J.; Kubota, A.; Sanford, M. S. "Nitrate as a redox co-catalyst for the aerobic Pd-catalyzed oxidation of unactivated sp3-C–H bonds, " Chem. Sci. 2012, 3, 3192-3195.

  56. McMurtrey, K. B.; Racowski, J. M.; Sanford, M. S. "Pd-Catalyzed C-H Fluorination with Nucleophilic Fluoride, " Org. Lett. 2012, 14, 4094-4097.

  57. Powers, D. C.; Lee, E.; Ariafard, A.; Sanford, M. S.; Yates, B. F.; Canty, A. J.; Ritter, T. "Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd-Pd Bond Cleavage," J. Am. Chem. Soc. 2012, 134, 12002-12009.

  58. Ye, Y.; Sanford, M. S. "Investigations into Transition-Metal-Catalyzed Arene Trifluoromethylation Reactions," Synlett. 2012, 23, 2005-2013.

  59. Gary, J. B; Carter, T. J.; Sanford, M. S. "Rh(III) Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange, " Top. Catal. 2012, 55, 565-570.

  60. Huff, C. A.; Kampf, J. W.; Sanford, M. S."Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO)," Organometallics 2012, 31, 4643-4635.

  61. Hickman, A. J.; Sanford, M. S."High-Valent Organometallic Copper and Palladium in Catalysis," Nature 2012, 484, 177-185.

  62. Ye, Y.; Sanford, M. S. "Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I," J. Am. Chem. Soc. 2012, 134, 9034-9037.

  63. Neufeldt, S. R.; Sanford, M. S."Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization" Acc. Chem. Res. 2012, 45, 936-946.

  64. Kubota, A.; Emmert, M. H.; Sanford, M. S."Pyridine Ligands as Promoters in PdII/0-Catalyzed C–H Olefination Reactions" Org. Lett. 2012, 14, 1760-1763.

  65. Hickman, A. J.; Cismesia, M. A.; Sanford, M. S."Structure-Activity Relationship Study of Diimine PtII Catalysts for H/D Exchange" Organometallics 2012, 31, 1761-1766.

  66. Racowski, J. M.; Gary, B. G.; Sanford, M. S."Carbon(sp3)–Fluorine Bond-Forming Reductive Elimination from Palladium(IV)" Angew. Chem. Int. Ed 2012, 51, 3414-3417

  67. Park, T.-H.; Hickman, A. J.; Koh, K.; Martin, S.; Wong-Foy, A. G.; Sanford, M. S.; Matzger, A. J. "Highly Dispersed Palladium(II) in a Defective MOF: Application to C–H Activation and Functionalization" J. Am. Chem. Soc. 2011, 133, 20138-20141.

  68. Maleckis, A; Sanford, M. S. "Facial Tridentate Ligands for Stabilizing Palladium(IV) Complexes" Organometallics 2011, 30, 6617-6627.

  69. Kalyani, D.; McMurtrey, K. B.; Neufeldt, S. R.; Sanford, M. S. "Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis" J. Am. Chem. Soc. 2011, 133, 18566-18569.

  70. Huff, C. A.; Sanford, M. S. "Cascade Catalysis for the Homogeneous Hydrogenation of CO2 to Methanol" J. Am. Chem. Soc. 2011, 133, 18122-18125.

  71. Gary, J. B.; Sanford, M. S. "Participation of Carbonyl Oxygen in Carbon-Carboxylate Bond-Forming Reductive Elimination from Palladium" Organometallics 2011, 30, 6143-6149.

  72. Racowski, J. M.; Ball, N. D.; Sanford, M. S. "C–H Bond Activation at Palladium(IV) Centers" J. Am. Chem. Soc. 2011, 133, 18022-18025.

  73. Ye, Y.; Lee, S.; Sanford, M. S. "Silver-Mediated Trifluoromethylation of Arenes Using TMSCF3" Org. Lett. 2011, 13, 5464-5467.

  74. Emmert, M. H.; Cook, A. K.; Xie, Y. J.; Sanford, M. S. "Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected C–H Oxygenation of Arenes" Angew. Chem. Int. Ed. 2011, 50, 9409-9412.

  75. Lanci, M. P.; Remy, M. S.; Lao, D. B.; Sanford, M. S.; Mayer, J. M. "Modulating Sterics in Trimethylplatinum(IV) Diimine Complexes to Achieve C–C Bond-Forming Reductive Elimination," Organometallics 2011, 30, 3704-3707.

  76. Kubota, A; Sanford, M. S. "Palladium-Catalyzed Ligand-Directed Oxidative Functionalization of Cyclopropanes" Synthesis 2011, 16, 2579-2589.

  77. Loy, R. N.; Sanford, M. S. "Palladium-Catalyzed C–H Perfluoroalkylation of Arenes," Org. Lett. 2011, 13, 2548-2551.

  78. Ball, N. D.; Gary, J. B.; Ye, Y.; Sanford, M. S. "Mechanistic and Computational Studies of Oxidatively-Induced Aryl–CF3 Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation," J. Am. Chem. Soc. 2011, 133, 7577-7584.

  79. Stowers, K. J.; Fortner, K. C.; Sanford, M. S. "Aerobic Pd-Catalyzed sp3 C–H Olefination: A Route to Both N-Heterocyclic Scaffolds and Alkenes," J. Am. Chem. Soc. 2011, 133, 6541-6544.

  80. Racowski, J.; Sanford, M. S. "Carbon-Heteroatom Bond Forming Reductive Elimination from Palladium(IV) Complexes," In Topics in Organometallic Chemistry, Vol. 53, Allan Canty, Ed., Springer, 2011, 61-84.

  81. Satterfield, A. D.; Kubota, A.; Sanford, M. S. "Palladium-Catalyzed 1,1-Aryloxygenation of Terminal Olefins," Org. Lett. 2011, 13, 1076-1079.

  82. Lyons, T. W.; Hull, K. L.; Sanford M. S. "Controlling Site Selectivity in Palladium-Catalyzed C–H Oxidative Cross-Coupling," J. Am. Chem. Soc. 2011, 133, 4455-4464.

  83. Hickman, A. J.; Sanford, M. S. "Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene," ACS Catal. 2011, 1, 170-174.

  84. Wagner, A. M.; Sanford, M. S. "Palladium-Catalyzed C–H Arylation of 2,5-Disubstituted Pyrroles," Org. Lett. 2011, 13, 288-291.

  85. Ye, Y.; Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Oxidation of Catalytically Relevant Palladium Dimer with "CF3+": Formation and Reactivity of a Monomeric Palladium(IV) Aquo Product," J. Am. Chem. Soc. 2010, 132, 14682-14687.

  86. Higgs, A. T.; Zinn, P. J.; Sanford, M. S. "Synthesis and Reactivity of (Phpy)2Ni (Phpy = 2-Phenylpyridine)," Organometallics 2010, 29, 5446-5449.

  87. Emmert, M. H.; Villalobos, J. M.; Gary, J. B.; Sanford, M. S. "Pt and Pd Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation," Angew. Chem. Int. Ed. 2010, 49, 5884-5886.

  88. Kalyani, D.; Satterfield, A. D.; Sanford, M. S. "Palladium-Catalyzed Oxidative Arylhalogenation of Alkenes: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2010, 132, 8419-8427.

  89. Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Aryl-CF3 Bond-Forming Reductive Elimination from Palladium(IV)," J. Am. Chem. Soc. 2010, 132, 2878-2879.

  90. Remy, M. S.; Cundari, T.; Sanford, M. S. "Computational and Experimental Studies of Methyl Group Exchange Between Group 10 Metal Centers," Organometallics 2010, 29, 1522-1525.

  91. Neufeldt, S. R.; Sanford, M. S. "O-Acetyl Oximes as Transformable Directing Groups for Pd-Catalyzed C–H Functionalization," Org. Lett. 2010, 12, 532-535.

  92. Villalobos, J. M.; Hickman, A. J.; Sanford, M. S. "Platinum(II) Complexes Containing Quaternized Nitrogen Ligands: Synthesis, Stability, and Evaluation as Catalysts for Methane and Benzene H/D Exchange," Organometallics 2010, 29, 257-262.

  93. Ball, N. D.; Kampf, J. W.; Sanford, M. S. "Synthesis and Reactivity of Palladium(II) Fluoride Complexes Containing Nitrogen Donor Ligands," Dalton Trans. 2010, 39, 632-640.

  94. Lyons, T. W.; Sanford, M. S. "Palladium-Catalyzed Ligand-Directed C–H Functionalization Reactions," Chem. Rev. 2010, 110, 1147-1169.

  95. Higgs, A. T.; Zinn, P. J.; Simmons, S. J.; Sanford, M. S. "Oxidatively Induced Carbon-Halogen Bond-Forming Reactions at Nickel," Organometallics 2009, 28, 6142-6144.

  96. Lanci, M. P.; Remy, M. S.; Kaminsky, W.; Mayer, J. M.; Sanford, M. S. "Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium(IV) Intermediates in a One Electron Oxidation Reaction," J. Am. Chem. Soc. 2009, 131, 15618-15620.

  97. Stowers, K. J.; Sanford, M. S. "Mechanistic Comparison Between Palladium-Catalyzed C–H Acetoxylation and C–H Chlorination," Org. Lett. 2009, 11, 4584-4587.

  98. Arnold, P. L.; Sanford, M. S.; Pearson, S. M. "Chelating N-Heterocyclic Carbene-Alkoxide as a Supporting Ligand for PdII/IV C–H Bond Functionalization Catalysis," J. Am. Chem. Soc. 2009, 131, 13912-13913.

  99. Hickman, A. J.; Villalobos, J. M.; Sanford, M. S. "A Quantitative Method to Assay Platinum Catalysts for Benzene H/D Exchange," Organometallics 2009, 28, 5316-5322.

  100. Deprez, N. R.; Sanford, M. S. "Synthetic and Mechanistic Studies of Pd-Catalyzed C–H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate," J. Am. Chem. Soc. 2009, 131, 11234-11241.

  101. Racowski, J. M.; Dick, A. R.; Sanford, M. S. "Detailed Study of C–O and C–C Bond-Forming Reductive Elimination from Stable C2N2O2 Palladium(IV) Complexes," J. Am. Chem. Soc. 2009, 131, 10974-10983.

  102. Hull, K. L.; Sanford, M. S. "Mechanism of Benzoquinone-Promoted Palladium-Catalyzed Oxidative Cross Coupling Reactions," J. Am. Chem. Soc. 2009, 131, 9651-9653.

  103. Ball, N. D.; Sanford, M. S. "Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex," J. Am. Chem. Soc. 2009, 131, 3796-3797.

  104. Lyons, T. W.; Sanford, M. S. "Pd(II/IV)-Catalyzed Cyclopropanation Reactions: Scope and Mechanism," Tetrahedron 2009, 65, 3211-3221.

  105. Desai, L. V.; Stowers, K. J.; Sanford, M. S. "Insights into Directing Group Ability in Palladium-Catalyzed C–H Bond Functionalization," J. Am. Chem. Soc. 2008, 130, 13285-13293.

  106. Whitfield, S. R.; Sanford, M. S. "Reactions of Platinum(II) Complexes with Chloride-Based Oxidants: Routes to Pt(IV) and Pt(III) Products," Organometallics 2008, 27, 1683-1689.

  107. Kalyani, D.; Sanford, M. S. "Oxidatively Intercepting Heck Intermediates: Pd-Catalyzed 1,2- and 1,1-Arylhalogenation of Alkenes," J. Am. Chem. Soc. 2008, 130, 2150-2151.

  108. Whitfield, S. L.; Sanford, M. S. "Reactivity of Pd(II) Complexes with Electrophilic Chlorinating Reagents: Isolation of Pd(IV) Intermediates and Observation of C–Cl Bond-Forming Reductive Elimination," J. Am. Chem. Soc. 2007, 129, 15142-15143.

  109. Hull, K. L.; Sanford, M. S. "Catalytic and Highly Regioselective Cross-Coupling of Aromatic C–H Substrates," J. Am. Chem. Soc. 2007, 129, 11904-11905.

  110. Deprez, N. R.; Sanford, M. S. "Reactions of Hypervalent Iodine Reagents with Palladium: Mechanisms and Applications in Organic Synthesis," Inorg. Chem. 2007, 46, 1924-1935.

  111. Desai, L. V.; Sanford, M. S. "Construction of Tetrahydrofurans via Pd(II/IV)-Catalyzed Aminooxygenation of Alkenes," Angew. Chem., Int. Ed. 2007, 46, 5737-5740.

  112. Welbes, L. L.; Lyons, T. W.; Cychosz, K. A.; Sanford, M. S. "Synthesis of Cyclopropanes via Pd(II/IV)-Catalyzed Reactions of Enynes," J. Am. Chem. Soc. 2007, 129, 5836-5837.

  113. Dick, A. R.; Remy, M. S.; Kampf, J. W.; Sanford, M. S. "Carbon-Nitrogen Bond-Forming Reactions Between Palladacycles and Hypervalent Iodine Reagents," Organometallics 2007, 26, 1365-1370.

  114. Kalyani, D.; Sanford, M. S. "Chelate-Directed Oxidative Functionalization of Carbon-Hydrogen Bonds: Synthetic Applications and Mechanistic Insights," In Topics in Organometallic Chemistry, Vol. 24, Naoto Chatani, Ed., Springer, 2007, 85-116.

  115. Hull, K. L.; Lanni, E. L.; Sanford, M. S. "Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2006, 128, 14047-14049.

  116. Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. "Scope and Selectivity in Palladium-Catalyzed Directed C–H Bond Halogenation Reactions," Tetrahedron 2006, 62, 11483-11498.

  117. Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. "A Simple Catalytic Method for the Regioselective Halogenation of Arenes," Org. Lett. 2006, 8, 2523-2526.

  118. Hull, K. L.; Anani, W. Q.; Sanford, M. S. "Palladium-Catalyzed Fluorination of Carbon-Hydrogen Bonds," J. Am. Chem. Soc. 2006, 128, 7134-7135.

  119. Deprez, N. R.; Kalyani, D.; Krause, A.; Sanford, M. S. "Room Temperature Palladium-Catalyzed 2-Arylation of Indoles," J. Am. Chem. Soc. 2006, 128, 4972-4973.

  120. Desai, L. V.; Malik, H. A.; Sanford, M. S. "Oxone as an Inexpensive Safe and Environmentally Benign Oxidant for C–H Bond Oxygenation," Org. Lett. 2006, 8, 1141-1144.

  121. Kalberer, E. W.; Whitfield, S. R.; Sanford, M. S. "Application of Recyclable, Polymer-Immobilized Iodine(III) Oxidants in Catalytic C–H Bond Functionalization," J. Mol. Catal. A. 2006, 251, 108-113.

  122. Dick, A. R.; Sanford, M. S. "Transition Metal Catalyzed Catalyzed Oxidative Functionalization of Carbon-Hydrogen Bonds," Tetrahedron 200662, 2439-2463.

  123. Dick, A. R.; Kampf, J. W.; Sanford, M. S. "Unusually Stable Palladium(IV) Complexes: Detailed Mechanistic Investigation of C–O Bond-Forming Reductive Elimination," J. Am. Chem. Soc. 2005, 127, 12790-12791.

  124. Kalyani, D.; Sanford, M. S. "Regioselectivity in Palladium-Catalyzed C–H Activation/Oxygenation Reactions," Org. Lett. 2005, 7, 4149-4152.

  125. Kalyani, D.; Deprez, N. R.; Desai, L. V.; Sanford, M. S. "Oxidative C–H Activation/C–C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights," J. Am. Chem. Soc. 2005, 127, 7330-7331.

  126. Dick, A. R.; Kampf, J. W.; Sanford, M. S. "Platinum Model Studies for Palladium-Catalyzed Oxidative Functionalization of C–H Bonds," Organometallics 2005, 24, 482-485.

  127. Desai, L. V.; Hull , K. L.; Sanford, M. S. "Palladium-Catalyzed Oxygenation of Unactivated sp3 C–H Bonds," J. Am. Chem. Soc. 2004, 126, 9542-9543.

  128. Dick, A. R.; Hull, K. L.; Sanford, M. S. "A Highly Selective Catalytic Method for the Oxidative Functionalization of C–H Bonds," J. Am. Chem. Soc. 2004, 126, 2300-2301.