Back to Main Page Professor Vincent L. Pecoraro Group Information Lectures and Conferences
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Publication List of Dr. Vincent L. Pecoraro

1. Raymond, K.N.; Pecoraro, V.L. "Coordination Chemistry: Ferric ion Sequestering Agents", McGraw-Hill Yearbook of Science and Technology, 1981, McGraw-Hill, New York, 150.

2. Harris, W.R.; Carrano,C.J.; Pecoraro, V.L.; Raymond, K.N. "Siderophilin Metal Coordination. 1. Complexation of Thorium by Transferin: Structure-Function Implications", J. Amer. Chem. Soc., 1981, 103, 2231.

3. Tufano, T.P.; Pecoraro, V.L.; Raymond, K.N. "Ferric Ion Sequestering Agents. 8. Kinetics of Iron Release From Ferritin to Catechoylamides", Biochim. Biophys. Acta 1981, 668, 420.

4. Pecoraro, V.L.; Weitl, F.L.; Raymond, K.N. "Ferric Iron Sequestering Agents. 7. Synthesis, Iron-Exchange Kinetics and Stability Constants of N-Substituted, Sulfonated Catechoylamide Analogues of Enterobactin", J. Amer. Chem. Soc. 1981, 103, 5133.

5. Pecoraro, V.L.; Harris, W.R.; Carrano, C.J.; Raymond, K.N. "Siderophilin Metal Coordination. 2. Difference Ultraviolet Spectroscopy of Di-, Tri- and Tetravalent Metal Ions With Ethylene-bis-(o-hydroxyphenylglycine)", Biochemistry 1981, 20, 7033.

6. Raymond, K.N.; Pecoraro, V.L.; Weitl, F.L. "Development of Iron Chelators for Clinical Use", Martell, A.E.; Anderson, W.F.; Badman, D.G., eds., 1981, Elsevier/North Holland, New York, 165.

7., Pecoraro, V.L.; Wong, G.B.; Raymond, K.N. "Stability Constants of Catechoylamide Sequestering Agents with Ga(III) and In(III)", Inorg. Chem. 1982, 21, 2209.

8. Raymond, K.N.; Pecoraro, V.L.; Harris, W.R.; Carrano, C.J. "Actinide Coordination and Discrimination by Human Transferrin", Environmental Migration of Long-Lived Radionuclides, 1982, International Atomic Energy Agency, Vienna, 571.

9. Raymond, K.N.; Pecoraro, V.L.; Kappel, M.J.; Harris, W.R.; Carrano, C.J. "Specific Sequestering Agents for the Actinides", Actinides in Perspective, 1982, N.E. Edelstein, ed., Pergamon Press, Oxford, 491.

10. Pecoraro, V.L.; Rawlings, J.; Cleland, W.W. "The Use of M3+(NH3)3H2 OATP Complexes as Inhibitors of Hexokinase", Fed. Proc., Fed. Am. Soc. Exp. Biol., 1982, 41, 907.

11. Raymond, K.N.; Chung, T.D.Y.; Pecoraro, V.L.; Carrano, C.J. "Metal Binding Sites of Transferrin", The Biochemistry and Physiology of Iron, 1982, P. Saltman and J. Hegenauer, eds. Elsevier/North Holland, New York, 649.

12. Harris, W.R.; Pecoraro, V.L. "Thermodynamic Binding Constants for Gallium Transferrin", Biochemistry, 1983, 22, 292.

13. Heidinger, S.; Braun, V.; Pecoraro, V.L.; Raymond, K.N. "Iron Supply of Escherichia coli with Synthetic Analogues of Enterochelin", J. Bactiol., 1983, 153, 109.

14. Pecoraro, V.L.; Wong, G.B.; Kent, T.A.; Raymond, K.N. "Coordination Chemistry of Microbial Iron Transport Compounds. 22. pH Dependent Mössbauer Spectroscopy of Ferric Enterobactin and Synthetic Analogues", J. Amer. Chem. Soc., 1983, 105, 4617.

15. Pecoraro; Harris, W.R.; Wong, G.B.; Carrano, C.J.; Raymond, K.N. "Coordination Chemistry of Microbial Iron Transport Compounds. 23. Fourier Transform Infrared Spectroscopy of Ferric Enterobactin and Synthetic Analogues", J. Amer. Chem. Soc., 1983, 105, 4623.

16. Pecoraro, V.L.; Rawlings, J.; Cleland, W.W. "The Use of Chromium (III) and Cobalt(III) Complexes of ADP to Elucidate the Catalytic Mechanism of Creatine Kinase", Inorg. Chim. Acta, Bioinorg. Let., 1983, 79, 241.

17. Riley, P.E.; Pecoraro, V.L.; Carrano, C.J.; Raymond, K.N. "Siderophilin Metal Coordination. 3. Crystal Structures of Co(III), Ga(III) and Cu(II) Ethylene-bis-(o-hydroxyphenylglycine)", Inorg. Chem., 1983, 22, 3096.

18. Pecoraro, V.L.; Rawlings, J.; Cleland, W.W. "Investigation of the Substrate Specificity of Creatine Kinase using Co(III) and Cr(III) Complexes of ADP", Biochemistry, 1984, 23, 153.

19. Pecoraro, V.L.; Bonadies, J.; Marese, C.A.; Carrano, C.J. "The Stepwise Metal-Assisted Oxidative Decarboxylation of Vanadium(V) EHPG: Isolation of a Possible Intermediate", J. Amer. Chem. Soc., 1984, 106, 3360.

20. Pecoraro, V.L.; Hermes, J.D.; Cleland, W.W. "Stability Constants of Mg(II) and Cd(II) Adenine Nucleotides and Thionucleotides and Rate Constants for Formation and Dissociation of MgATP and MgADP", Biochemistry, 1984, 23, 5202.

21. Carrano, C.J.; Spartalian, K.; Appa Rao, G.V.N.; Pecoraro, V.L.; Sundaralingham, M. "The Fe(III) Complex of N-[2-((o-hydroxyphenyl)glycino)ethyl] salicylidenim-ine. A Model Complex for the Fe(III) Binding Site in Transferrins", J. Amer. Chem. Soc., 1985, 107, 1651.

22. Pecoraro, V.L.; Rendina, A.R.; Cleland, W.W. "Determination of the Screw Sense Specificity of Bovine Liver Fructokinase", Biochemistry, 1985, 24, 1619.

23. Pecoraro, V.L.; Zylstra, G.; Olsen, R.H. "Isolation of the DNA Sequence Coding for Pseudomonas aeruginosa Azurin", Rev. Port. Quimica, 1985, 27, 170.

24. Kappel, M.J.; Pecoraro, V.L.; Raymond, K.N. "Lipophilic Enterobactin Analogues. Iron Exchange Kinetics and Complexation of Ga(III) and Fe(III) by Terminally N-Substituted Catechoylamide Ligands", Inorg. Chem., 1985, 24, 2447.

25. Riley, P.E.; Pecoraro, V.L.; Carrano, C.J.; Bonadies, J.A.; Raymond, K.N. "Crystal Structures of Vanadyl Ethylene-bis-(o-hydroxyphenyglycine) Complexes", Inorg. Chem., 1986, 25, 154.

26. Pecoraro, V.L.; Butler, W.M. "Structure of N,N'-Ethylene-bis-(Salicylideniminato) Manganese(III) Chloride", Acta Cryst., 1986, C42, 1151.

27. Speckhard, D.; Pecoraro, V.L.; Knight, W.B.; Cleland, W.W. "Synthesis, Purification and Characterization of the Four Screw Sense Diastereomers of Co(III)(NH3)3 ATP", J. Amer. Chem. Soc., 1986, 108, 4167.

28. Bonadies, J. ; Pecoraro, V.L.; Carrano, C.J. "The Acid Promoted Disproportionation of a Vanadium(IV) Phenolate: Implications for Vanadium Uptake in Tunicates", J. Chem. Soc., Chem. Comm., 1986, 1218.

29. Kessissoglou, D.P.; Butler, W.M.; Pecoraro, V.L. "Structural and Spectroscopic Characterization of the Mn(IV) Schiff's Base Complex Mn(SALADHP)2", J. Chem. Soc., Chem. Comm., 1986, 1253.

30. Pecoraro, V.L.; Kessissoglou, D.P.; Li, X.; Butler, W.M. "Models for the Active Sites of Manganoenzymes", Prog. Photosyn. Res., 1987, 1, 795.

31. Kessissoglou, D.P.; Butler, W.M.; Pecoraro, V.L. "Characterization of Mono- and Binuclear Manganese(II) Schiff's Base Complexes With Metal Disulfide Bonds", Inorg. Chem., 1987, 26, 495.

32. Bonadies, J.; Butler, W.M.; Pecoraro, V.L.; Carrano, C.J. "Novel Reactivity Patterns of N,N'-Ethylene-bis-(salicylideniminato)oxovanadium(IV) in Strongly Acidic Media", Inorg. Chem., 1987, 26, 1218.

33. Kessissoglou, D.P.; Li., X.; Butler, W.M.; Pecoraro, V.L. "Mononuclear Mn(IV) Complexes of Hydroxyl Rich Schiff Base Ligands", Inorg. Chem., 1987, 26, 2487.

34. Cusky, S.; Pecoraro, V.L.; Olsen, R.H. "Initial Catabolism of Biogenic Amines by Pseudomonas aeruginosa PAO: Pathway Description, Mapping of Mutations and Cloning of the Essential Genes", J. Bact., 1987, 169, 2398.

35. Pecoraro, V.L.; Li, X.; Baker, M.J.; Butler, W.M.; Bonadies, J.A. "Manganese Complexes of Relevance to Enzymes Containing Multinuclear Manganese Centers", Recueil Trav. Chim., 1987, 106, 221.

36. Kessissoglou, D.P.; Li., X.; Kirk, M.; Bender, C.J.; Pecoraro, V.L. "Isolation of a Mixed Valence Trinuclear Manganese Complex Potentially Relevant to Photosynthetic Oxygen Evolution", Inorg. Chem., 1988, 27, 1

37. Pecoraro, V.L. "Structural Proposals for the Manganese Centers of the Oxygen Evolving Complex: An Inorganic Chemist's Perspective", Photochem. Photobiol., 1988, 48, 249.

38. Li, X.; Lah, M.S.; Pecoraro, V.L. "Vanadium Complexes of the Tridentate Schiff Base Ligand N-(salicylideneaminato)-N'-(2-hydroxyethyl)ethylenediamine: Acid-Base and Redox Conversion Between Vanadium(IV) and Vanadium(V) Iminophenolates", Inorg. Chem., 1988, 27, 4657.

39. Kessissoglou, D.P.; Bender, C.; Kirk, M.L.; Lah, M.S.; Pecoraro, V.L. "A Bent Mixed Valence Mn(III/II/III) Complex: A New Class of Trinuclear, Acetate Bridged Schiff Base Compounds Exhibiting a g=2 Multiline ESR Signal", J. Chem. Soc., Chem. Comm., 1989, 84.

40. Pecoraro, V.L. "Structural Characterization of [VO(salicylhydroximate)(CH3OH)]3: Applications to the Biological Chemistry of Vanadium(V)", Inorg. Chim. Acta., 1989, 155, 171.

41. Waggoner, C.; Pecoraro, V.L.; Yocum, C.F. "Monovalent Cations (Na+, K+, Cs+) Inhibit Calcium Activation of Photosynthetic Oxygen Evolution", FEBS Lett., 1989, 244, 237.

42. Bonadies, J.A.; Lah, M.S.; Kirk, M.L.; Kessissoglou, D.P.; Hatfield, W.; Pecoraro, V.L. "Structurally Diverse Manganese(III) Schiff Base Complexes: Chains, Dimers and Cages", Inorg. Chem., 1989, 28, 2037.

43. Bonadies, J.A.; Maroney, M.L.; Pecoraro, V.L. "Structurally Diverse Manganese(III) Schiff Base Complexes: Solution Speciation via 1H NMR Spectroscopy and Electrochemistry", Inorg. Chem., 1989, 28, 2044.

44. Penner-Hahn, J.E.; Fronko, R.; Pecoraro, V.L.; Bowlby, N.F.; Betts, S.D.; Yocum, C.F. "XAS of Mn in the Photosynthetic Oxygen Evolving Complex", Physica B, 1989, 158, 107.

45. Pichersky, E.; Detlefsen, D.; Pecoraro, V.L. "Pre-plastocyanin from Lycopersicon esculentum", Nucl. Acids Res., 1989, 17, 6414.

46. Li, X.; Lah, M.S.; Pecoraro, V.L. "Structural Characterization of the Manganese(IV) Schiff-Base Complex MnIV(5-Cl-SALAHP)2", Acta Cryst, 1989, C45, 1517.

47. Lah, M.S.; Pecoraro, V.L. "Isolation and Characterization of Mn(II)[Mn(III)4 (salicyl-hydroximate)4(Acetate)2 (DMF)6]: An Inorganic Analogue of M2+(12-Crown-4)", J. Amer. Chem. Soc., 1989, 111, 7258.

48. Li, X.; Pecoraro, V.L. "Stepwise, Metal Assisted Decarboxylation Promoted by Manganese: Reactivity Relationship Between Manganese and Vanadium", Inorg. Chem., 1989, 28, 3403.

49. Lah, M.S.; Kirk, M.L.; Hatfield, W.; Pecoraro, V.L. "The Tetranuclear Cluster Fe(III)-[Fe(III)(Salicylhydroximate)(Acetate)(CH3OH)]3 is an Analogue of vM3+(9-Crown-3)", J. Chem. Soc., Chem. Comm., 1989, 1606.

50. Pecoraro, V.L.; Kessissoglou, D.P.; Li, X.; Lah, M. S.; Saadeh, S.; Bender, C.; Bonadies, J. A.; Larson, E. "Evaluation of Structural Possibilities for the Mn Centers of the OEC", Curr Resrch. Photosyn., M. Baltscheffsky, ed., Klueer Academia Publishers, Dordercht, 1990, 1, 709.

51. Penner-Hahn, J.E.; Fronko, R.; Pecoraro, V.L.; Bowlby, N.F.; Betts, S.D.; Yocum, C.F. "Structural Characterization of the Manganese Sites in the Photosynthetic Oxygen-Evolving Complex Using X-ray Absorption Spectroscopy", J. Amer. Chem. Soc., 1990, 112, 2549.

52. Carrano, C.J.; Nunn, C.; Quan, R.; Bonadies, J.A.; Pecoraro, V.L. "Monomeric and Dimeric Vanadium(IV) and (V) Complexes of N-(hydroxyalkyl)salicylidene-amines: Structures, Magnetochemistry and Reactivity", Inorg. Chem, 1990, 29, 944.

53. Lah, M.S.; Pecoraro, V.L.; Kirk, M.L.; Hatfield, W. "Transition Metal Encapsulation by "Metallocrown" Ethers," Biosensor Technology, R. Buck, W. Hatfield, E. Bowden, M. Umana, eds. Marcel-Dekker, New York, 1990, 201.

54. Detlefsen, D.; Thanabal, V.; Pecoraro, V.L.; Wagner, G. "Sequential 1H NMR Assignments of Iron(II) Cytochrome c551 from Pseudomonas aeruginosa", Biochemistry, 1990, 29, 9377.

55. Pecoraro, V.L. "Photosynthesis" The 1991 McGraw-Hill Yearbook of Science and Technology, Sybyl Parker, Ed. McGraw-Hill, New York, 340, 1990.

56. Briggs, L.M.; Pecoraro, V.L.; McIntosh, L. "Copper-Induced Expression, Cloning and Regulatory Studies of the Plastocyanin Gene from the Cyanobacterium Synechocystis sp. PCC 6803", Plant Mol. Biol., 1990, 15, 633.

57. Pecoraro, V.L.; Lah, M.S. "Development of Metallacrown Ethers: A New Class of Metal Clusters", Comments Inorg. Chem., 1990, 11, 59.

58. Saadeh, S.; Lah, M.S.; Pecoraro, V.L. "Manganese Complexes of a-Hydroxy Acids", Inorg. Chem., 1991, 30, 9.

59. Speckhard, D.C.; Rawlings, J.; Pecoraro, V.L.; Cleland, W.W. "Triammine-chromium(III) Complexes of Tripolyphosphate and Adenosine Tri- and Diphosphate,", J. Inorg. Biochem., 1991, 41, 105.

60. Detlefsen, D.; Thanabal, V.; Pecoraro, V.L.; Wagner, G. "Solution Structure of Fe(II) Cytochrome c551 from Pseudomonas aeruginosa as Determined by 2D3. Weng, T.C., Hsieh, W-Y., Uffelman, E. S., Gordon-Wylie, S.W., Collins, T., Pecoraro, V.L. and Penner-Hahn, J.E., "XANES Evidence Against a Manganyl Species in the S3 Sta 1H-NMR", Biochemistry, 1991, 30, 9040.

61. Lah, M.S.; Pecoraro, V. L. "A Functional Analogy Between Crown and Metallacrown Ethers", Inorg. Chem, 1991, 30, 878.

62. Larson, E.; Pecoraro, V.L. "The Peroxide Dependent m2-O Bond Formation of [Mn(IV)SALPN(O)]2", J. Amer. Chem. Soc., 1991, 113, 3810.

63. Kirk, M.L.; Lah, M.S.; Kessissoglou, D.P.; Rapodopolou, C.; Hatfield, W.; Pecoraro, V.L. "Cationic Control of Spin Dimensionality in Infinite Chains of (Cation)2[Mn(III)(Salicylate)2][Mn(III)(Salicylate)2(CH3OH)2]", Inorg. Chem., 1991, 30, 3900.

64. Larson, E.; Pecoraro, V.L. "Catalytic Disproportionation of Hydrogen Peroxide by a bis-m2-O-Mn(IV) Dimer", J. Amer. Chem. Soc, 1991, 113, 7809.

65. Kirk, M.L.; Hatfield, W.; Lah, M.S.; Kessissoglou, D.P.; Pecoraro, V.L.; Morgan, L.W.; Pedersen, J.D. "Effects of Alternation in Some Quasi-One Dimensional Magnetic Materials", J. Appl. Phys., 1991, 69, 6013.

66. Pecoraro, V.L. "Vanadium", The McGraw-Hill Encyclopedia of Science and Technology, 1991, Sybyl Parker, Ed. McGraw-Hill, New York, Vol. 19, 149.

67. Larson, E.; Lah, M. S.; Li, X.; Bonadies, J. A.; Pecoraro, V. L. "Manganese-Manganese Separations in Oxide and Alkoxide Bridged Complexes: Correlation of Structure With Ligand Type and Number", Inorg. Chem., 1992, 31, 373.

68. Larson, E.; Pecoraro, V.L. "Introduction to Manganese Enzymes," Chapter 1 in Manganese Redox Enzymes, V.L. Pecoraro, ed, Verlag-Chemie, 1992, 1.

69. Pecoraro, V.L. "Structurally Diverse Manganese Complexes: From Voodoo to Oxygenic Photosynthesis," Chapter 10 in Manganese Redox Enzymes, V.L. Pecoraro, ed, Verlag-Chemie, 1992, 197.

70. Pecoraro, V.L., ed. Manganese Redox Enzymes, Verlag-Chemie, New York, 1992.

71. Larson, E.L.; Riggs, P.; Penner-Hahn, J.E.; Pecoraro, V.L. "Structural Characterization of Protonated [Mn(IV)(m2-O)]2 Cores", J. Chem. Soc., Chem. Comm., 1992, 102.

72. Cornman, C.R.; Kampf, J.; Pecoraro, V.L. "Structural and Spectroscopic Char-acterization of Vanadium(V)O-Imidazole Complexes", Inorg. Chem., 1992, 31, 1981.

73. Cornman, C.R.; Kampf, J.; Lah, M.S.; Pecoraro, V.L. "Modelling Vanadium Bromoperoxidase: Synthesis, Structure and Reactivity of Vanadium(IV)-Imidazole Complexes", Inorg. Chem., 1992, 31, 2035.

74. Larson, E.L.; Haddy, A.; Kirk, M.L.; Sands, R.; Hatfield, W.; Pecoraro, V.L. "The Asymmetric Mixed Valent Dimer {[Mn(2-OH-SALPN)]2(THF)}ClO4 Shows a Temperature Dependent Interconversion Between g=2 Multiline and Low Field EPR Signals", J. Amer. Chem. Soc., 1992, 114, 6263.

75. Kessissoglou, D.P.; Kirk, M.; Lah, M.S.; Li, X. Raptopoulou, C.; Hatfield, W.M.; Pecoraro, V.L. "Structural and Magnetic Characterization of Trinuclear Mixed Valence, Manganese Acetates", Inorg. Chem., 1992, 31, 5424.

76. Cornman, C.R.; Colpas, G.J.; Hoeschele, J.D.; Kampf, J.; Pecoraro, V.L. "Implications for the Spectroscopic Assignment of Vanadium Biomolecules: Structural and Spectroscopic Characterization of Monooxovanadium(V) Complexes Containing Catecholate and Hydroximate Based Non-Innocent Ligands", J. Amer. Chem. Soc.. 1992, 114, 9925.

77. Saadeh, S. M.; Trojan, K. L.; Kampf, J.; Hatfield, W. E.; Pecoraro, V. L. "Magnetic Characterization of S=2 Chains of Composition [(Cat)2{[Mn(III)-(Malonate)2(CH3OH)2][Mn(III)(Malonate)2]}]n and {(Cat)2[Mn(III)(Malonate)2-(CH3OH)][Mn(III)(Malonate)2]}n", Inorg. Chem., 1993, 32, 3034.

78. Lah, M.S.; Gibney, B.; Tierney, D.; Penner-Hahn, J.E.; Pecoraro, V.L. "The Fused Metallacrown Anion Na2{[Na0.5[Ga(salicylhydroximate)]4]2(m2-OH)4}- is An Inorganic Analogue of a Cryptate", J. Amer. Chem. Soc., 1993, 115, 5857.

79. Root, C.; Hoeschele, J.D.; Cornman, C.R.; Kampf, J.; Pecoraro, V.L. "Structural and Spectroscopic Characterization of Dioxovanadium(V) Complexes With Asymmetric Schiff Base Ligands", Inorg. Chem., 1993, 32, 3855.

80. Gelasco, A.; Pecoraro, V.L. "[Mn(III)(2-OHSalpn)]2 Is An Efficient Functional Model For the Manganese Catalases", J. Amer. Chem. Soc., 1993, 115, 7928.

81. Gibney, B.; Stemmler, A.J.; Pilotek, S.; Kampf, J.; Pecoraro, V.L. "Generalizing the Metallacrown Analogy: Ligand Variation and Solution Stability of the V(V)O 9-Metallacrown-3 Structure Type," Inorg. Chem., 1993, 32, 6008.

82. Baldwin, M.J.; Gelasco, A.; Pecoraro, V. L. "The Effect of Protonation on [Mn(IV)(m2-O)]2 Complexes", Photosyn. Resrch., 1993, 38, 303.

83. Baldwin, M.; Kampf, J.; Pecoraro, V.L. "The Linear Mn(II) Complex Mn3(5-NO2-SALIMH)2(OAc)4 Provides an Alternative Structure Type for the Carboxylate Shift in Proteins", J. Chem. Soc., Chem. Comm., 1993, 1741.

84. Hoeschele, J.D.; Roy, A.; Pecoraro, V.L.; Carver, P.L. "In Vitro Analysis of the Interaction Between Sucralfate and Ketoconazole", Antimicrob. Agents Chemother., 1994, 38, 319.

85. Kessissoglou, D.P.; Kampf, J.; Pecoraro, V.L. "Compositional and Geometrical Isomers of 15-Metallacrown-5 Complexes," Polyhedron, 1994, 13, 1379.

86. Colpas, G. J.; Hamstra, B.; Pecoraro, V.L. "VO(O2)(HEIDA) is an Efficient Mimic for the Vanadium Bromoperoxidases", J. Amer. Chem. Soc., 1994, 116, 3627.

87. Pecoraro, V.L.; Baldwin, M.J.; Gelasco, A. "Manganese Complexes with Dioxygen and its Reduced Forms", Chem Reviews, 1994, 94, 807.

88.. Colpas, G. J.; Hamstra, B.; Kampf, J.; Pecoraro, V.L. "The Preparation of VO3+ and VO2+ Complexes Using Hydrolytically Stable, Asymmetric Ligands Derived from Schiff Base Precursors", Inorg. Chem., 1994, 33, 4669.

89. Gibney, B.P.; Kampf, J.; Kessissoglou, D.P.; Pecoraro, V.L. "Copper 12-Metallacrown-4 Complexes", Inorg. Chem., 1994, 33, 4840.

90. Baldwin, M.J.; Stemmler, T.; Riggs-Gelasco, P.J.; Kirk, M.J.; Penner-Hahn, J.E.; Pecoraro, V.L. " Structural and Magnetic Effects of Succesive Protonations of Oxo Bridges in High Valent Manganese Dimers", J. Amer. Chem. Soc., 1994, 116, 11349.

91. Stemmler, A.J.; Kampf, J.W.; Pecoraro, V.L. "Preparation of the First Inverse 12-Metallacrown-4", Inorg. Chem., 1995, 34, 2271.

92. Utschig, L.M.; Wright, J.G.; Dieckmann, G.; Pecoraro, V.L.; O'Halloran, T.V. "199Hg NMR Spectroscopy of Mercury Substituted Blue Copper Proteins", Inorg. Chem., 1995, 34, 2497.

93. Dieckmann, G.; Heilman, S.; DeGrado, W.; Pecoraro, V.L. "DeNovo Design of Metallopeptides", in An Inorganic Perspective of Life, D.P. Kessissoglou, D. Coucouvanis and M. Kanatzidas, eds., Elsevier, Amsterdam, 1995, 275.

94. Baldwin, M.; Gelasco, A.; Pecoraro, V.L. "Modeling the Reactivity of the Oxygen Evolving Complex" in An Inorganic Perspective of Life, D.P. Kessissoglou, D. Coucouvanis and M. Kanatzidas, eds., Elsevier, Amsterdam, 1995, 287.

95. Stemmler, A.J.; Kampf, J.W.; Kirk, M.L.; Pecoraro, V.L. "Characterization of a Nickel Hydroxamate That Serves As a Model for the Stemmler, A.J.; Kampf, J.W.; Kirk, M.L.; Pecoraro, V.L.J. Amer. Chem. Soc. , 1995, 117, 6368.

96. Gibney, B.; Pecoraro, V.L."Theoretical Considerations for the Binding of Metals in Biological Fluids", in Handbook on Metal-Ligand Interactions in Biological Fluids, Volume 1, G. Berthon, Ed., Amsterdam, 1995, 62.

97. Pecoraro, V.L.; Gibney, B. "Structural Aspects of Metal Ion Interactions with Synthetic Carrier Ligands", in Handbook on Metal-Ligand Interactions in Biological Fluids, Volume 1, G. Berthon, Ed., Amsterdam 1995, 597.

98. Gelasco, A.; Baldwin, M.; Pecoraro, V.L. "A Modelling Approach For Understanding the Mechanism of Manganese Enzymes", in Mechanistic Bioinorganic Chemistry, H.H. Thorp and V.L. Pecoraro, eds., Adv. Chem Series, ACS Books, Washington, D.C. 1995, 265.

99. Baldwin, M.J.; Kampf, J.W.; Kirk, M.L.; Pecoraro, V.L. "Structural and Magnetic Studies of Mn(II) Complexes of the Imidazole Containing Ligand 5-NO2-salimH [5-NO2-salimH2= 4-(2-(5-nitrosalicylideneamino)ethyl)imidazole] With Varying Nuclearity", Inorg. Chem, 1995, 34, 5252.

100. Law, N.A.; Machonkin, T.E.; McGorman, J.P.; Larson, E.J.; Kampf, J.W.; Pecoraro, V.L. "A Structurally Characterized DiChloro-Mn(IV) Complex Capable of Chlorinating Alkenes", J. Chem. Soc., Chem. Comm., 1995, 2015.

101. Gelasco, A.; Ascenas, A.; Pecoraro,V.L. "The Tetranuclear Complex [Mn(II)(picpn)]4 Efficiently Disproportionates Hydrogen Peroxide", Inorg. Chem., 1996, 35, 1419.

102. Colpas, G.C.; Hamstra, B.J.; Kampf, J.W.; Pecoraro, V.L. "Functional Models for Vanadium Haloperoxidase", J. Amer. Chem. Soc., 1996, 118, 3469.

103. Caudle, M. T.; Riggs-Gelasco; P.; Gelasco,, A.K.; Penner-Hahn, J.E.; Pecoraro, V.L. "Homolytic Cleavage of tert-butyl hydroperoxide by Mn2(2-OHsalpn)2 to Form the One-Electron Oxidized Compound Mn2(2-OHsalpn)2 OH having a Terminal Hydroxo Ligand", Inorg. Chem., 1996, 35, 3577.

104. Pecoraro, V.L.; Stemmler, A.J.; Gibney, B.P.; Bodwin, J.; Kampf, J.W.; Wang, H. "Metallacrowns: A New Class of Molecular Recognition Agents", in Prog. Inorg. Chem. Vol. 45, Chapter 2, K. Karlin, ed. Pergamon Press, 1996, 83.

105. Gibney, B.; Wang, H.; Kampf, J. W.; Pecoraro,V.L. "Structural Evaluation and Solution Integrity of Alkali Halide Salts of Manganese 12-Metallacrown-4", Inorg. Chem., 1996 35, 6184.

106. Baldwin, M.J.; Pecoraro, V.L. "Energetics of the Proton-Coupled Electron Transfer in High-Valent Systems: Models for Water Oxidation by the Oxygen Evolving Complex of Photosystem II", J. Amer. Chem. Soc., 1996, 118, 11325.

107. Stemmler, A.J.; Barwinski, A.; Baldwin, M.J.; Young, Jr., V.; Pecoraro, V.L. "Facile Preparation of a Chiral, Face Differentiated 15-Metallacrown-5", J. Amer. Chem. Soc, 1996, 118, 11962.

108. Stemmler, A.J.; Kampf, J.W.; Pecoraro, V.L. "A Planar 15-Metallacrown-5 that Selectively Binds the Uranyl Cation," Agnew. Chem., 1996, 35, (23), 2841.

109. Pecoraro, V.L.; Baldwin, M.J.; Caudle, M.T.; Law, N.A.; Kampf, J.W.; Rasmussen, P.G. "A Modelling Approach for Understanding Water Oxidation in Photosynthesis", Photosynthesis: From Light to vBiosphere, Vol. II, Proceedings of the Xth International Photosynthesis Congress, Paul Mathis, ed., Dordrecht: Kluwer Academic Publishers, 1995, 377.

110. Slebodnick, C.; Hamstra, B.J.; Pecoraro, V.L. "Modelling the Biological Chemistry of Vanadium: Structural and Reactivity Studies Elucidating Biological Function," Structure and Bonding, P. Sadler, Ed., 1997, 51.

111. Rompel, A.; Andrews, J.C.; Cinco, R.M.; Wemple, M.W.; Christou, G.; Law, N.A.; Pecoraro, V.L.; Sauer, K. Yachandra, V.K.; Klein, M.P. "Chlorine K-Edge X-ray Absorption Spectroscopy as a Probe of Chlorine-Metal Bonding: Manganese-Chloride Model Systems with Relevance to the Oxygen Evolving Complex in Photosystem II", J. Amer. Chem. Soc., 1997, 119, 4465.

112. Caudle, M.T.; Pecoraro, V.L. "Hydrogen Atom Abstraction of Bound Substrate is a Viable Mechanism for Cluster Oxidation in the Oxygen Evolving Complex of Photosystem II", J. Amer. Chem. Soc., 1997, 119, 3415.

113. Gelasco, A.; Kirk, M.L.; Kampf, J.W.; Pecoraro, V.L. "The [Mn2(2-OHsalpn)2]2-,1-,0,1+ System: Synthesis, Structure, Spectroscopy and Magnetic Characterization of the First Dinuclear Manganese Series Containing Four Distinct Oxidation States", Inorg. Chem., 1997, 36, 1829.

114. Hamstra, B.J.; Houseman A.L.P.; LoBruto, R.; Colpas, G.C.; Kampf, J.W.; Frasch, W.D.; Pecoraro, V.L. "Structural and Solution Characterization of Mononuclear V(IV) Complexes that Help to Elucidate the Active Site Structures of Vanadium Haloperoxidases", Inorg. Chem., 1997, 36, 4866.

115. Randall, D.W.; Gelasco, A.; Caudle, M.T.; Pecoraro, V.L.; Britt, R.D. "1H ESE-ENDOR and ESEEM Characterization of Water and Methanol Ligation to a Dinuclear Mn(III)Mn(IV) Cluster", J. Amer. Chem. Soc., 1997, 119, 4481.

116. Dieckmann, G.; McCrory, D.; Tierney, D.; Utschig, L. M.; Singer, C.P.; O’Halloran, T.V.; Penner-Hahn, J.E.; DeGrado, W.; Pecoraro, V.L.; "Conversion of a Three Helix Bundle to a Two Helix Bundle Initiated by the Complexation of Hg(II)", J. Amer. Chem. Soc., 1997, 119, 6195.

117. Caudle, M.T.; Kampf, J. W.; Rasmussen, P. G.; Pecoraro, V. L. "The First Binuclear Mn(IV) Complex Containing a Bridging Imidazolate Ligand Exhibits Unique EPR Spectral Features", J. Amer. Chem. Soc., 1997, 119, 9297.

118. Priuska, E. M.; Clark-Baldwin, K.; Pecoraro, V.L. , Schacht, J. "1H NMR studies of Iron-Gentamicin Complexes and the Implications for Aminoglycoside Toxicity." Inorg. Chim. Acta. (Special Issue dedicated to Ivano Bertini), 1998, 273, 85.

119. Gelasco, A.; Pecoraro, V.L. "The [Mn2(2-OHsalpn)2]2-,1-,0 System: An Efficient Functional Model for the Reactivity and Inactivation of the Manganese Catalases", Inorg. Chem., 1998, 37, 3301.

120. Slebodnick, C.; Pecoraro, V.L., "Solvent Effects on 51V NMR Chemical Shifts: Characterization of Vanadate and Peroxovanadate Complexes in Mixed Water Acetonitrile Solvent", Inorg. Chim. Acta., 1998, 283, 37 (Special Issue dedicated to Osamu Yamauchi).

121. LoBruto, R.; Hamstra, B.J.; Colpas, G.C.; Frasch, W.D.; Pecoraro, V.L. "ESEEM Spectroscopy Reveals and Distinguishes Equatorial and Axial Nitrogen Ligands Bound to VO in Proteins Containing the Vanadyl Ion", J. Amer. Chem. Soc., 1998, 120, 4410-4416.

122. Pecoraro, V.L.; Baldwin, M.J.; Caudle, M.T.; Hsieh, W.-Y.; Law, N.A. "A Proposal for Water Oxidation in Photosystem II", Pure & Appl. Chem., 1998, 70, 925.

123. Halfen, J.A.; Bodwin, J.J.; Pecoraro, V.L. "Preparation and Characterization of Chiral Copper 12-Metallacrown-4 Complexes: Inorganic Analogues of Tetraphenylporphyrinatocopper(II)", Inorg. Chem., 1998, 37, 5416.

124. Law, N.A.; Caudle, M.T.; Pecoraro, V.L. "Manganese Redox Enzymes and Model Systems: Properties , Structures, and Reactivity", Adv. Inorg. Chem., Geoffery B. Sykes, ed., 1998, 46 305-440.

125. Pecoraro, V.L. "A Modeling Approach for Understanding Photosynthetic Water Oxidation"; Photosyn. Resch., in Photosynthesis: Mechanisms and Effects,G. Garab (ed.), Kluwer Academic Publishers, Dordrecht, 1998, 1247-52.

126. Dieckmann, G.; McRorie, D.; Lear, J.D.; Sharp, K.A.; DeGrado, W.; Pecoraro, V.L."The Role of Protonation and Chelation Preferences in Defining the Properties of Mercury Binding Coiled-Coils", J. Mol. Biol., 1998, 280, 897.

127. Grant, C.V.; Ball, J.A.; Hamstra, B. J. ; Pecoraro, V.L.; Britt, R. D. "51V ESE-ENDOR Studies of Oxovanadium(IV) Complexes: Investigation of the Nuclear Quadrupole Interaction", J. Phys. Chem. B, 1998, 102, 8145-8150.

128. Pecoraro, V.L.; slebodnick, C.; Hamstra, B.J. "Synthetic Models for Vanadium Haloperoxidases", in Vanadium Compounds: Chemistry, Biochemistry, and Therapeutic Applications, A.S. Tracey & D.C. Crans, eds, 1998, 157.

129. Yocum, C.F.; Pecoraro, V.L. "Recent Advances in the Understanding of the Biological Chemistry of Manganese", Current Opinions in Biology, 1999, 3, 182-187.

130. Stemmler, A.J.; Kampf, J.W.; Kirk, M.L.; Atasi, B.H.; Pecoraro, V.L. "The Preparation, Characterization and Magnetism of Copper 15-Metallacrown-5 Lanthanide Complexes", Inorg. Chem., 1999, 38, 2807.

131. Baldwin, M.; Law, N.A.; Stemmler, T.L.; Kampf, J.W.; Penner-Hahn, J.E.; Pecoraro, V.L. "Reactivity of [MnIV(salpn)]2(m-O,m-OCH3)+ and [MnIV(salpn)]2(m-O,m-OCH3)+: Effects of Proton Lability and Hydrogen Bonding", Inorg. Chem., 1999, 38, 4801-4809.

132. Pecoraro, V.L.; Hsieh, W-Y "The Use of Model Complexes to Elucidate the Structure and Function of Manganese Redox Enzymes"; Chapter 14 in Metals in Biological Systems, Astrid Sigel and Helmut Sigel (eds.) Marcel-Dekker, Inc., Basel, Switzerland 2000, 37, 429-504

133. Slebodnick, C.A.; Law, N.A.; Pecoraro, V.L. "A Comparison of Manganese and Vanadium Peroxidase, Haloperoxidase and Catalase Activities"; B. Meunier (ed.) (Imperial College Press: London), 2000, 215-67

134. Law, N.A.; Kampf, J.W.; Pecoraro, V.L. "Correlation of Mn-O-Mn Bridging Angle and the Heisenberg Exchange Parameter, J, For an Isostructural Series of MnIV2(m2-O)2 dimers", Inorg. Chim. Acta., 2000, 297, 252-64 (a special volume in honor of Prof. Srephen J. Lippard).

135. Thomas S. Smith, II, Charles A. Root, Jeff W. Kampf, Paul G. Rasmussen, and Vincent L. Pecoraro, "Reevaluation of the Additivity Relationship for Vanadyl-Imidazole Complexes: Correlation of the EPR Hyperfine Constant with Ring Orientation", J. Am. Chem. Soc., 2000, 122,, 767-75.

136. Bodwin. J.J.; Pecoraro, V.L.; "Preparation of a Chiral, 2-Dimensional Network Using Metallacrown and Copper Benzoate Building Blocks"; Inorg. Chem., 2000, 39, 3434-5.

137. Pecoraro, V. L.; Bodwin, J. J.; Cutland, A. D.; "Formation of Chiral Solids Via a Molecular Building Block Approach"; J. Solid State Chem., 2000, 152, 68-77.

138. Cutland, A.D.; Malkani, R.G.; Kampf, J.W.; Pecoraro, V.L. "Lanthanide 15-MC-5 Complexes Form Nitrate Selective Cavities"; Angew. Chemie, 2000, 39, 2689-91.

139. Farrer, B.T.; McClure, C.; Penner-Hahn, J.E.; Pecoraro, V.L. "Arsenic(III)-Thiol Interactions Stabilize Three-Helix Bundles in Aqueous Solution"; Inorg. Chem., 2000, 39, 5422-5423.

140. Peloquin, J.M.; Campbell, K.A.; Randall, D.W.; Evanchik, M.A.; Pecoraro, V.L.; Armstrong, W.A.; Britt, R.W. "55Mn ENDOR of the S2-state Multiline EPR Signal of Photosystem II: Implications on the Structure of the Tetranuclear Cluster"; J. Amer. Chem. Soc. 2000, 122,, 10926-10942.

141. Caudle, M.T.; Pecoraro, V.L, "Mechanism for the Reduction of the Mixed-Valent Mn(III)Mn(IV)[2-Ohsalpn]+ Complex by Tertiary Amines"; Inorg. Chem., 2000, 39, 5831-5837.

142. Psomas, G. Stemmler, A.J.; Dendrinou-Samara, C.; Bodwin, J.J.; Schneider, M.; Alexiou, M.; Kampf, J.J.; Kessissoglou, D. P.; Pecoraro, V.L. "The Preparation of Site Differentiated Mixed Ligand and Mixed Ligand/Mixed Metal Metallacrowns"; Inorg. Chem., 2001, 40, 1562.

143. Cutland, A.; Halfen, J.A.; Kampf, J.; Pecoraro, V.L. "Chiral 15-Metallacrown-5 Complexes Differentially Bind Carboxylate Anions"; J. Amer. Chem. Soc., 2001, 123, 6211-6212.

144. Bodwin, J.J.; Cutland, A. D. ; Malkani, R.; Pecoraro, V.L. "The Development of Chiral Metallacrowns Into Anion Recognition Agents and Porous Materials"; Coord. Chem. Rev., 2001, 216-217, 489-512.

145. Farrer, B. T.; Pecoraro, V.L. "Thermodynamic Model for the Stabilization of Trigonal Hg(II) in a Designed Three Helix Bundle"; Biochemistry, 2001, 40, 14696-14705.

146. Stemmler, A.J.; Pecoraro, V.L. "Use of Picolinehydroximate Complexes in Preparation of Uranyl and Lanthanide 15-Metallacrown-5: UO2(NO3)3[Cu(II)(picolinate)]5 and Eu(NO3)3[Cu(II)(picolinate)]5"; Inorg. Synth.; 2002, 33, 67-70.

147. Gibney, B.R.; Pecoraro, V.L. "Use of Salicyl- and Napthoylhydroxymate Complexes in Preparation of Manganese and Copper 12-Metallacrown-4 Complexes: Mn(II)(Acetate)2[Mn(III)(salicylhydroximate)]4 and (Tetramemthylammonium)2[Cu(II)5(napthoylhydroximate) 4]"; Inorg. Synth.; 2002, 33, 70-74.

148. Farrer, B.T.; Pecoraro, V.L. "Bioinorganic Chemistry" in The Academic Press Encyclopedia of Science and Technology, 3rd Edition, Academic Press, New York, 2002, 117-139.

149. Smith II, T.S.; LoBrutto, R.; Pecoraro, V.L. "Paramagnetic Spectroscopy of Vanadyl Complexes: Applications to Biological Systems"; Coord. Chem. Reviews, 2002, 228, 1-18

150. Matzapetakis, M.; Farrer, B. T.; Weng, T.-C.; Hemmingsen, L.; Penner-Hahn, J. E.; Pecoraro, V. L.; "Comparison of the Binding of Cadmium(II), Mercury(II), and Arsenic(III) to the de Novo Designed Peptides TRI L12C and TRI L16C"; J. Am. Chem. Soc., 2002, 124(27), 8042-8054.

151. Rajendiran, T.M.; Kampf, J. W.; Pecoraro, V.L. "A Structurally Characterized Monomeric Mn(IV) Complex in a Discrete N2O4 Coordination Environment," Inorg. Chem., 2002, 339, 497-502 (Issue in honor of Helmut Sigel).

152. A. D. Cutland-Van Noord; Jeff W. Kampf, V. L. Pecoraro, "Preparation of Resolved Four-Fold Symmetric Amphiphilic Helices Using Chiral Metallacrown Building Blocks," Angew. Chem., 2002, 41, 4667-4670.

153. Smith II, T.S.; Pecoraro, V.L. "Oxidation of Organic Sulfides By Vanadium Haloperoxidase Model Complexes," Inorg. Chem., 2002, 41, 6754-6760.

154. Triller, M.U.; Hsieh, W.-Y.; Pecoraro, V.L.; Rompel, A.; Krebs, B. "Preparation of Highly Efficiently Manganese Catalase Mimics," Inorg. Chem., 2002, 41, 5544-5554.

155. Hsieh, W.-Y.; Pecoraro, V.L. "Oxidation of m-Chlorobenzoic acid by Mn(V)=O complexes," Inorg. Chim Acta, 2002, 341, 113-117 (Special issue honoring K.N. Raymond).

156. Kessissoglou, D.P.; Bodwin, J.J.; Kampf, J.J.; Dendrinou-Samarab, C.; Pecoraro, V.L. "Pseudohalide complexation by manganese 12-metallacrowns-4 complexes" Inorg. Chim. Acta, 2002, 331, 73-80 (Special issue in honor of Geoffrey Sykes).

157. Farrer, Brian T.; Pecoraro, Vincent L. "Heavy Metal Complexation by de Novo Peptide Design," Curr. Opin. Drug Discovery & Development, 2002, 5, 937-943.

158. Rajendiran, T.M.; Kirk M.L.; Setyawati, I.; Caudle, M.T.; Kampf, J. W.; Pecoraro, V.L. "The First Ferromagnetically Coupled Mn(III/IV) Complex," Chem. Comm., 2003 7, 824-825.

159. Rajendiran, T.M.; Caudle, M.T.; Setyawati, I.; Kampf, J.W.; Pecoraro, V.L. "Evaluating Hydrogen Bond Interactions in Enzymes Containing Mn(III)-Histidine Complexation Using Manganese Imidazole Complexes," JBIC, 2003 8(3) 283-293 Feb.

160. J. A. Johnson, J. W. Kampf; Vincent L. Pecoraro, "The Preparation of a New Type of Helicate: A Double-Metallahelicate Containing 28 Copper Atoms," Angew. Chem., 2003, 42(5), 546-549.

161. Farrer, Brian T.; Pecoraro, Vincent L. "Hg(II) binding to a weakly associated coiled coil nucleates an encoded metalloprotein fold: A Kinetic analysis" Proc. Natl. Acad. Sci., 2003, 3760-3765

162. Alexiou, M.; Dendrinou-Samara, C.; Karagianni, A.; Biswas, S; Zaleski, C.; Yoder, D.; Kampf, J.W.; Penner-Hahn, J.E.; Pecoraro, V.L.; Kessissoglou, D.P. "Models For the Lower S States of Photosystem II: A Trinuclear Mixed-Valent MnII/MnIV/MnII Complex," Inorg. Chem, 2003, 2185-2187.

163. Lesniak, W.; Harris, W.R.; Yudenfreund Kravitz, J.; Schacht, J.; Pecoraro, V.L. "The Solution Chemistry of Copper(II)-Gentamicin Complexes: Relevance to Metal," Inorg. Chem., 2003, 42, 1420-1429.

164. C. Dendrinou-Samara, M. Alexiou, C. M. Zaleski, J. W. Kampf, M. L. Kirk, D. P. Kessissoglou, V. L. Pecoraro; "Synthesis and Magnetic Properties of a Metallacryptate that behaves as a Single Molecule Magnet" Angew. Chem. Int. Ed. 2003, 42, 3763-3766.

165. C. Dendrinou-Samara, C. M. Zaleski, A. Evagorou, J. W. Kampf, D. P. Kessissoglou, V. L. Pecoraro; "A Cationic 24-MC-8 Manganese Cluster with Ring Metals Possessing Three Oxidation States [MnII4MnIII6MnIV 24-O)23-O)43-OH)43-OCH3) 2(pko)12](OH)(ClO4)3" Chem. Comm. 2003, 2668 - 2669.

166. Maria Alexiou, Curtis M. Zaleski, Catherine Dendrinou-Samara, Jeff Kampf, Dimitris P. Kessissoglou, Vincent L. Pecoraro "Trinuclear Mixed-Valent MnII/MnIV/MnII Complexes - Structure and Magnetic Behavior" Zeitschrift f|r anorganische und allgemeine Chemie,2003, 629(12-13),2348-2355.

167. Triller M.U; Pursche D.; Hsieh W.Y.; Pecoraro V.L.; Rompel A.; Krebs B.; "Catalytic oxidation of 3,5-di-tert-butylcatechol by a series of Mononuclear Manganese Complexes: Synthesis, structure, and kinetic investigation " Inorg. Chem. , 2003 , 42(20)6274-6283.

168. Zampella, G; Kravitz, J.Y.; Webster,C. E.; Fantucci, P.; Hall, M. B.; Carlson, H. A.; Pecoraro, Vincent L.; Gioia, L. D.; "Quantum Mechanical Models of the Resting State of the Vanadium-Dependent Haloperoxidase" Inorg. Chem., 2004, 43, 4127-4136.

169. Lee, K.H.; Matzapetakis, M.; Mitra, S.; Marsh, E.Neil.G.; Pecoraro, Vincent L."Control of Metal Coordination Number in de Novo Designed Peptides through Subtle Sequence Modifications" J. Am. Chem. Soc.,2004, 126(30), 9178-9179.

170. Zaleski,C.Z.; Depperman,E.C.; Kampf,J.W.; Kirk,M.L.; Pecoraro, V.L.; "Synthesis, Structure, and Magnetic Properties of a Large Lanthanide-Transition Metal Single-Molecule Magnet" Angew. Chem. Int. Ed.2004, 43, 3912-3914

171. Ghosh, D.; Pecoraro, V.L.; "Understanding Metalloprotein Folding Using a De Novo Design Strategy" Inorg. Chem.2004, 43, 7902-7915.

172. Weng, T.C., Hsieh, W-Y., Uffelman, E. S., Gordon-Wylie, S.W., Collins, T., Pecoraro, V.L. and Penner-Hahn, J.E., "XANES Evidence Against a Manganyl Species in the S3 State of the Oxygen Evolving Complex", J. Am. Chem. Soc., 2004, 126, 8070.

173. Hsieh, W-Y., Campbell, K., Britt, R.D., Yoder, D., Penner-Hahn, J.E. and Pecoraro, V.L., "The First Spectroscopic Model for the S1 State Multiline Signal of the OEC", Biochim. Biophys. Acta: Bioenergetics, 2004, 1655, 149.

174. Zampella, G.; Fantucci, P.; Pecoraro,V.L.;, and Gioia, L. D.;; "Reactivity of Peroxo Forms of the Vanadium Haloperoxidase Cofactor. A DFT Investigation" J. Am. Chem. Soc. 2005, 127, 953-960

175. Ghosh, D.; Pecoraro, V.L.; "Probing Metal-Peptide Interactions Using a De Novo Design Approach", Curr. Opin. Chem. Biol., 2005, 9, 1-7.

176. Lesniak, W.; Pecoraro, V. L.; Schacht, J.; "Ternary Complexes of Gentamicin with Iron and Lipid Catalyze Formation of Reactive Oxygen Species" Chem. Res. Toxicol., 2005, 18(2), 357-364.

177. Angaridis, P.; Kampf, J. W.; Pecoraro, V. L.; "Multinuclear Fe(III) Complexes with Polydentate Ligands of the Family of Dicarboxyimidazoles: Nuclearity- and Topology-Controlled Syntheses and Magneto-Structural Correlations" Inorg. Chem. , 2005, 44(10), 3626-3635. 2

178. Scarpellini, M.; Wu, A. J.; Kampf, J. W.; Pecoraro, V. L.; "Corroborative Models of the Cobalt(II) Inhibited Fe/Mn Superoxide Dismutases" Inorg. Chem. , 2005, 44(14), 5001-5010.

179. Kravitz, J.Y. and Pecoraro, V. L.; " Synthetic and computational modeling of the vanadium-dependent haloperoxidases", Pure Appl. Chem. 2005 , 77(9), 1595-1605.

180. Ghosh, D.; Lee, K.H.; Demeler, B.; Pecoraro, V. L.; "Linear Free Energy Analysis of Mercury(II) and Cadmium(II) Binding to Three Stranded Coiled Coils", Biochemistry , 2005, 44, 10732-10740.

181. Kravitz, J. Y.; Pecoraro, V. L.; Carlson, H. A.; "Quantum mechanics/molecular mechanics calculations of the vanadium dependent chloroperoxidase", J. Chem. Theory Comput., 2005, 1(6): 1265-1274.

182. Lesniak, W.; Pecoraro, V. L.; Schacht, J.; "Ternary complexes of gentamicin with iron and lipid catalyze formation of reactive oxygen species", Chem. Res. Toxicol., 2005, 18(2): 357-364.

183. Matzapetakis, M.; Pecoraro, V. L.; "Site-selective metal binding by designed alpha-helical peptides", J. Am. Chem. Soc., 2005, 127(51): 18229-18233.

184. Zaleski, C. M.; Depperman, E. C.; Dendrinou-Samara, C.; Alexiou, M.; Kampf, J. W.; Kessissoglou, D. P.; Kirk, M. L.; Pecoraro, V. L. "Metallacryptate single-molecule magnets: Effect of lower molecular symmetry on blocking temperature", J. Am. Chem. Soc., 2005, 127, 12862-12872.

185. Zampella, G.; Fantucci, P.; Pecoraro, V. L.; De Gioia, L.; "Reactivity of peroxo forms of the vanadium haloperoxidase cofactor. A DFT investigation", J. Am. Chem. Soc., 2005, 127, 953-960.

186. Hsieh, W. Y.; Zaleski, C. M.; Pecoraro, V. L.; Fanwick, P. E.; Liu, S. A.; "Mn(II) complexes of monoanionic bidentate chelators: X-ray crystal structures of Mn(dha)2(CH3OH)2 (Hdha = dehydroacetic acid) and Mn(ema)2(H2O) 2*2H2O (Hema=2-ethyl-3-hydroxy-4-pyrone)", Inorg. Chim.Acta, 2006, 359, 228-236.

187. Lee, K. H.; Cabello, C.; Hemmingsen, L.; Marsh, E. N. G.; Pecoraro, V. L.; "Using nonnatural amino acids to control metal-coordination number in three-stranded coiled coils", Angew. Chem.-Intl. Ed., 2006, 45, 2864-2868.

188. Matzapetakis, M; Ghosh, D; Weng, T-C.; Penner-Hahn, J. E.; Pecoraro, V. L.; "Peptidic models for the binding of Pb(II), Bi(III) and Cd(II) to mononuclear thiolate binding sites", J. Biol. Inorg. Chem., , 2006, 11, 876-890.

189. Zampella, G.; Fantucci, P.; Pecoraro, V.L.; De Gioia, L. "Insight into the Catalytic Mechanism of Vanadium Haloperoxidases. DFT Investigation of Vanadium Cofactor Reactivity," Inorg. Chem.,2006, 45, 7133-7143.

190. Zaleski, C.J.; Depperman, E.; Kampf, J.W.; Kirk, M.L.; Pecoraro, V.L. "Using LnIII[15-MCCuII(N)S-pheHA-5] 3+ Complexes to Construct Chiral Single-Molecule Magnets and Chains of Single-Molecule Magnets" Inorg. Chem.,2006, 45, 10022-10024.

191. Iranzo, O.; Ghosh, D.; Pecoraro, V. L. "Assessing the integrity of designed homomeric parallel 3-stranded coiled coils in the presence of metal ions," Inorg. Chem., 2006, 45, 9959-9973.

192. Schneider, C.J.; Zampella, G.; Greco, C.; Pecoraro, V. L.; De Gioia, L. "Mechanistic Analysis of Nucleophilic Substrate Oxidation by Functional Models of Vanadium Dependent Haloperoxidases: A Density Functional Theory Study" Eur. J. Inorg. Chem., 2007, 515-523 [Cover Article].

193. Mezei, G.; Kampf, J.W.; Pan, S.; Poeppelmeier, K.; Watkins, B.; Pecoraro, V.L. "Metallacrown-Based Molecular Capsules: Selective Encapsulation of Three Isonicotinate Anions," Chem. Comm., 2007, 1148-1150.

194. Mezei, G.; Kampf, J.W.; Pecoraro, V. L., "Temperature-, molar ratio- and counterion-effect on the crystal growth of bipyridinium-bis-alkylcarboxylic acid/crown ether pseudorotaxanes" New Journal of Chemistry, 2007, 31, 439-446.

195. Zaleski, C.J.; Cutland-Van Noord, A.D.; Kampf, J.W.; Pecoraro, V.L. "Controlling the Polymorph of LnIII(NO3)3-x(OH)x[15-MCCuII(N)S-pheHA-5] Complexes Through Solvent Type and LnIII Ion Choice" Crystal Growth and Design 2007, 7, 1098-1105.

196. Zaleski, C.J.; Kampf, J.W.; Mallah, T.; Kirk, M.L.; Pecoraro, V.L. "Using the Metallacrown Analogy to Prepare Mixed d-f Element Clusters: LnIII4MnIII6" Inorg. Chem., 2007, 46, 1954-1956.

197. Afrati, T.; Zaleski, C.; Dendrinou-Samara, C.; Mezei, G.; Kampf, J. W.; Pecoraro, V. L.; Kessissoglou, D. P. "Di-2-Pyridyl Ketone Oxime in Copper Chemistry: di-, tri-, penta- and hexanuclear Clusters" Dalton.Trans., 2007, 2658-2668

198. Lim, C.S.; Van Noord, A.C.; Kampf, J.W.; Pecoraro, V.L. "Assessing Guest Selectivity Within Metallacrown Host Capsules" Eur. J Inorg. Chem., 2007, 1347-1350.

199. Iranzo, O.; Cabello, C.; Pecoraro, V.L. "Heterochromia in Designed Metallopeptides: Geometry-Selective Binding of Cd(II) in a De Novo Peptide" Angew. Chem., 2007, 46, 6688-6691 [Cover Article].

200. Touw, D.S. ; Stuckey, J.A.; Nordman, C.E.; Pecoraro, V.L. "Identifying important structural characteristics of arsenic resistance proteins by using designed three-stranded coiled coils" Proc. Natl. Acad. Sci.(USA), 2007, 104, 11969-11974.

201. Schneider, C.J.; Pecoraro, V.L. "Understanding the Mechanism of Vanadium Dependent Haloperoxidases and Related Biomimetic Catalysis," ACS Symposium Series, 2007, 974, Chapter 12, 148-162.

202. Gatjens, J.; Sjodin, M.; Pecoraro, V.L.; Un. S. "The relationship between the manganese(II) zero-field interaction and Mn(II)/Mn(III) redox potential of Mn(4'-X-terpy)2 complexes" J. Amer. Chem. Soc., 2007, 129, 13825-13827

203. Iranzo, O.; Thulstrup, P.W.; Ryu, S.-B.; Hemmingsen, L.; Pecoraro, V.L. "The Application of 199Hg NMR and 199mHg PAC Spectroscopies to Define the Biological Chemistry of Hg(II): A Case Study Using Designed Two and Three Stranded Coiled Coils," Chem: Eur. J. 2007, 13, 9178-9190 [Frontispiece].

204. Signorella, S.; Buldt-Karentzopoulos, K.; Rompel, A.; Krebs, B.; Pecoraro, V.L.; Tuchagues, J.-P. "Reevaluation of the Rates of Mn Catalase Mimics" Inorg. Chem., 2007, 46, 10864-10868.

205. Scarpellini, M.; Gatjens, J.; Karylowski, O.; Kampf, J.W.; Sherman, S.E.; Pecoraro, V.L. "Modeling the Resting State of Oxalate Oxidase and Oxalate Decarboxylase Enzymes," Inorg. Chem.,2008, 47, 3584-3593.

206. Mullins, C.S.; Pecoraro, V.L. "Reflections on Small Molecule Manganese Models that Seek to Mimic Photosynthetic Water Oxidation Chemistry," Coord. Chem. Reviews, 2008, 252, 416-443.

207. Sjodin, M.; Gatjens, J.; Tabares, L.C.; Thuery, P.; Pecoraro, V.L.; Un, S. "Tuning the Redox Properties of Manganese(II) and its Implications to the Electrochemistry of Manganese/Iron Superoxide Dismutases," Inorg. Chem., 2008, 47, 2897-2908.

208. Pecoraro, V.L.; Hseih, W.Y. "In Search of High Valent Intermediates in Schiff Base Containing Manganese Dimers," Inorg. Chem., 2008, 47, 1765-1778.

209. Meelich, K.; Zaleski, C.; Pecoraro, V.L. "Using Small Molecule Complexes to Elucidate Features of Photosynthetic Water oxidation" Phil. Trans. Royal Soc., 2008, 363, 1271-1281.

210. Schneider, C.J.; Penner-Hahn, J.E.; Pecoraro, V.L. "Elucidating the Protonation Site of Vanadium Peroxide Complexes and the Implications for Biomimetic Catalysis" J. Amer. Chem. Soc., 2008, 130, 2712-2713.

211. Zaleski, C.J.; Weng, T-C; Dendrinou-Samara, C.; Alexiou, M.; Kanakaraki, P.; Hsieh, W.-Y.; Kampf, J.W.; Penner-Hahn, J.E.; Pecoraro, V.L; Kessissoglou, D.P. "Structural and Physical Characterization of Tetranuclear [MnII3MnIV] and [MnII2MnIII2] Valence-Isomers Manganese Clusters" Inorg. Chem.. in press [Cover Article]

212. Gatjens, J.; Kampf, J.W.; Pecoraro, V.L "Preparation of a new 16-MC-4 Structure Type That Captures Mn(II) in the Central Cavity" Inorg. Chim. Acta, in press [special issue in honor of Bernhard Lippert].


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Metallopeptide Project Manganese Project Vanadium Project Metallacrown Project
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